Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/water-soluble-organic-dyes-as-molecular-photocatalysts-for-h2o2-IIHp4qXLXQ
References (26)
-
Shu Hu (2019)
Membrane-less photoelectrochemical devices for H2O2 production: efficiency limit and operational constraintSustainable Energy & Fuels
-
Emily Cole, Prasad Lakkaraju, D. Rampulla, A. Morris, E. Abelev, A. Bocarsly (2010)
Using a one-electron shuttle for the multielectron reduction of CO2 to methanol: kinetic, mechanistic, and structural insights.Journal of the American Chemical Society, 132 33
-
E. Mitraka, Maciej Gryszel, M. Vagin, M. Jafari, Amritpal Singh, M. Warczak, M. Mitrakas, M. Berggren, T. Ederth, I. Zozoulenko, X. Crispin, E. Głowacki (2018)
Electrocatalytic Production of Hydrogen Peroxide with Poly(3,4‐ethylenedioxythiophene) ElectrodesAdvanced Sustainable Systems, 3
-
R. Eisenberg (2009)
Rethinking Water SplittingScience, 324
-
C. Cardona, W. Li, A. Kaifer, D. Stockdale, G. Bazan (2011)
Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell ApplicationsAdvanced Materials, 23
-
Maciej Gryszel, M. Sytnyk, M. Jakešová, G. Romanazzi, R. Gabrielsson, W. Heiss, E. Głowacki (2018)
General Observation of Photocatalytic Oxygen Reduction to Hydrogen Peroxide by Organic Semiconductor Thin Films and Colloidal Crystals.ACS applied materials & interfaces, 10 16
-
Yasuhiro Shiraishi, Shunsuke Kanazawa, Yusuke Kofuji, Hirokatsu Sakamoto, S. Ichikawa, S. Tanaka, T. Hirai (2014)
Sunlight-driven hydrogen peroxide production from water and molecular oxygen by metal-free photocatalysts.Angewandte Chemie, 53 49
-
Shen Zhao, Xu Zhao, Hui Zhang, Jiangxu Li, Yongfa Zhu (2017)
Covalent combination of polyoxometalate and graphitic carbon nitride for light-driven hydrogen peroxide productionNano Energy, 35
-
Zhiyi Lu, Guangxu Chen, Samira Siahrostami, Zhihua Chen, Kai Liu, Jin Xie, Lei Liao, Tong Wu, Dingchang Lin, Yayuan Liu, Thomas Jaramillo, J. Nørskov, Yi Cui (2018)
High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materialsNature Catalysis, 1
-
T. Rubin, J. Calvert, G. Rankin, W. MacNevin (1953)
Photochemical Synthesis of Hydrogen Peroxide at Zinc Oxide Surfaces1Journal of the American Chemical Society, 75
-
Marek Węcławski, M. Jakešová, Martyna Charyton, N. Demitri, Beata Koszarna, Kerstin Oppelt, S. Sariciftci, D. Gryko, E. Głowacki (2017)
Biscoumarin-containing acenes as stable organic semiconductors for photocatalytic oxygen reduction to hydrogen peroxideJournal of Materials Chemistry, 5
-
Satoshi Kato, Jieun Jung, T. Suenobu, S. Fukuzumi (2013)
Production of hydrogen peroxide as a sustainable solar fuel from water and dioxygenEnergy and Environmental Science, 6
-
Ludovico Migliaccio, Maciej Gryszel, Vedran Đerek, A. Pezzella, E. Głowacki (2018)
Aqueous photo(electro)catalysis with eumelanin thin filmsMaterials horizons, 5
-
Kentaro Mase, Masaki Yoneda, Yusuke Yamada, S. Fukuzumi (2016)
Seawater usable for production and consumption of hydrogen peroxide as a solar fuelNature Communications, 7
-
S. Habisreutinger, L. Schmidt‐Mende, Jacek Stolarczyk (2013)
Photocatalytic reduction of CO2 on TiO2 and other semiconductors.Angewandte Chemie, 52 29
-
M. Warczak, Maciej Gryszel, M. Jakešová, Vedran Đerek, E. Głowacki (2018)
Organic semiconductor perylenetetracarboxylic diimide (PTCDI) electrodes for electrocatalytic reduction of oxygen to hydrogen peroxide.Chemical communications, 54 16
-
Yusuke Kofuji, Yuki Isobe, Yasuhiro Shiraishi, Hirokatsu Sakamoto, S. Tanaka, S. Ichikawa, T. Hirai (2016)
Carbon Nitride-Aromatic Diimide-Graphene Nanohybrids: Metal-Free Photocatalysts for Solar-to-Hydrogen Peroxide Energy Conversion with 0.2% Efficiency.Journal of the American Chemical Society, 138 31
-
S. Shaegh, N. Nguyen, S. Ehteshami, Siew Hwa, Chan (2013)
Membraneless hydrogen peroxide fuel cell using Prussian Blue as cathode material † -
Maciej Gryszel, A. Markov, M. Vagin, E. Głowacki (2018)
Organic heterojunction photocathodes for optimized photoelectrochemical hydrogen peroxide productionJournal of Materials Chemistry, 6
-
R. Disselkamp (2008)
Energy Storage using Aqueous Hydrogen PeroxideEnergy & Fuels, 22
-
M. Jakešová, D. Apaydin, M. Sytnyk, Kerstin Oppelt, W. Heiss, N. Sariciftci, E. Głowacki (2016)
Hydrogen‐Bonded Organic Semiconductors as Stable Photoelectrocatalysts for Efficient Hydrogen Peroxide PhotosynthesisAdvanced Functional Materials, 26
-
V. Vyas, V. Lau, B. Lotsch (2016)
Soft Photocatalysis: Organic Polymers for Solar Fuel ProductionChemistry of Materials, 28
-
Eva Miglbauer, P. Wójcik, E. Głowacki (2018)
Single-compartment hydrogen peroxide fuel cells with poly(3,4-ethylenedioxythiophene) cathodes.Chemical communications, 54 84
-
Yanming Liu, X. Quan, Xinfei Fan, Hua Wang, Shuo Chen (2015)
High-yield electrosynthesis of hydrogen peroxide from oxygen reduction by hierarchically porous carbon.Angewandte Chemie, 54 23
-
A. Morris, G. Meyer, E. Fujita (2009)
Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels.Accounts of chemical research, 42 12
-
G. Suppes, P. Fortin, S. Holdcroft (2015)
Photoelectrochemical Hydrogen Evolution: Single-Layer, Conjugated Polymer Films Bearing Surface-Deposited Pt NanoparticlesJournal of The Electrochemical Society, 162
- Publisher
- Wiley
- Copyright
- © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- eISSN
- 2366-7486
- DOI
- 10.1002/adsu.201900027
- Publisher site
- See Article on Publisher Site
Abstract
Photochemical generation of hydrogen peroxide via oxygen reduction is a critical component of emerging sustainable energy conversion concepts. Light‐absorbing semiconductors as well as electrodes modified with sensitizers typically catalyze oxygen photoreduction to hydrogen peroxide. Here, it is reported that, in contrast to these heterogeneous systems, a homogeneous solution of a metal‐free organic dye can perform the whole catalytic cycle of hydrogen peroxide photoevolution itself. This cycle can proceed with simultaneous oxidation of various organic molecules as electron donors, or even water. In the three water‐soluble dyes that are experimented with, photoevolution of peroxide occurs favorably at neutral to basic pH. The reaction is first order with respect to dye concentration, and evidence implicates a single‐electron reduction pathway with superoxide as an intermediate. Photostability of the dyes over time correlates with increased oxidation potential of the molecule. The finding that hydrogen peroxide can be produced in aqueous solution with single fully organic molecules performing the entire photocatalytic cycle creates a new avenue for the peroxide carbon free energy cycle.
Journal
Advanced Sustainable Systems – Wiley
Published: Aug 1, 2019
Keywords: ; ; ;