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Zhengyuan Tu, Y. Kambe, Yingying Lu, L. Archer (2014)
Nanoporous Polymer‐Ceramic Composite Electrolytes for Lithium Metal BatteriesAdvanced Energy Materials, 4
M. Armand, J. Tarascon (2008)
Building better batteriesNature, 451
Xiaokun Zhang, Jin Xie, Feifei Shi, Dingchang Lin, Yayuan Liu, Wei Liu, Allen Pei, Y. Gong, Hongxia Wang, Kai Liu, Y. Xiang, Yi Cui (2018)
Vertically Aligned and Continuous Nanoscale Ceramic-Polymer Interfaces in Composite Solid Polymer Electrolytes for Enhanced Ionic Conductivity.Nano letters, 18 6
Sen Xin, Ya You, Shaofei Wang, Hongcai Gao, Ya‐Xia Yin, Yu‐Guo Guo (2017)
Solid-State Lithium Metal Batteries Promoted by Nanotechnology: Progress and ProspectsACS energy letters, 2
Yanyan Cui, Xinmiao Liang, J. Chai, Z. Cui, Qinglei Wang, Weisheng He, Xiaochen Liu, Zhihong Liu, G. Cui, Jiwen Feng (2017)
High Performance Solid Polymer Electrolytes for Rechargeable Batteries: A Self‐Catalyzed Strategy toward Facile SynthesisAdvanced Science, 4
H. Duan, Ya‐Xia Yin, Yang Shi, Peng-fei Wang, Xu-Dong Zhang, Chunpeng Yang, Ji-Lei Shi, R. Wen, Yu‐Guo Guo, L. Wan (2018)
Dendrite-Free Li-Metal Battery Enabled by a Thin Asymmetric Solid Electrolyte with Engineered Layers.Journal of the American Chemical Society, 140 1
Sarah Gerssen-Gondelach, A. Faaij (2012)
Performance of batteries for electric vehicles on short and longer termJournal of Power Sources, 212
Quan Li, Hongyi Pan, Wenjun Li, Yi Wang, Junyang Wang, Jieyun Zheng, Xiqian Yu, Hong Li, Liquan Chen (2018)
Homogeneous Interface Conductivity for Lithium Dendrite-Free AnodeACS Energy Letters
J. Janek, W. Zeier (2016)
A solid future for battery developmentNature Energy, 1
W. Luo, Yunhui Gong, Yizhou Zhu, Yiju Li, Yonggang Yao, Ying Zhang, Kun Fu, Glenn Pastel, Chuan-Fu Lin, Yifei Mo, E. Wachsman, Liangbing Hu (2017)
Reducing Interfacial Resistance between Garnet‐Structured Solid‐State Electrolyte and Li‐Metal Anode by a Germanium LayerAdvanced Materials, 29
Nianwu Li, Ya‐Xia Yin, Jin‐Yi Li, Chang-Huan Zhang, Yu‐Guo Guo (2016)
Passivation of Lithium Metal Anode via Hybrid Ionic Liquid Electrolyte toward Stable Li Plating/StrippingAdvanced Science, 4
Yutao Li, Xi Chen, A. Dolocan, Zhiming Cui, Sen Xin, Leigang Xue, Henghui Xu, Kyusung Park, J. Goodenough (2018)
Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries.Journal of the American Chemical Society, 140 20
Yingying Lu, Mukul Tikekar, R. Mohanty, Kenville Hendrickson, Lingjie Ma, L. Archer (2015)
Stable Cycling of Lithium Metal Batteries Using High Transference Number ElectrolytesAdvanced Energy Materials, 5
Xunliang Cheng, Jian Pan, Yang Zhao, M. Liao, Huisheng Peng (2018)
Gel Polymer Electrolytes for Electrochemical Energy StorageAdvanced Energy Materials, 8
Hanjun Ryu, Ju-Hyuck Lee, Tae‐Yun Kim, U. Khan, Jong-Seop Lee, S. Kwak, Hong‐Joon Yoon, Sang‐Woo Kim (2017)
High‐Performance Triboelectric Nanogenerators Based on Solid Polymer Electrolytes with Asymmetric Pairing of IonsAdvanced Energy Materials, 7
Shuya Wei, Zhu Cheng, Pooja Nath, Mukul Tikekar, Gaojin Li, L. Archer (2018)
Stabilizing electrochemical interfaces in viscoelastic liquid electrolytesScience Advances, 4
Nianwu Li, Yang Shi, Ya‐Xia Yin, Xian‐Xiang Zeng, Jin‐Yi Li, Congju Li, L. Wan, R. Wen, Yu‐Guo Guo (2018)
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes.Angewandte Chemie, 57 6
Jan Broek, Semih Afyon, J. Rupp (2016)
Interface‐Engineered All‐Solid‐State Li‐Ion Batteries Based on Garnet‐Type Fast Li+ ConductorsAdvanced Energy Materials, 6
M. Monchak, T. Hupfer, A. Senyshyn, H. Boysen, D. Chernyshov, T. Hansen, K. Schell, E. Bucharsky, Michael Hoffmann, H. Ehrenberg (2016)
Lithium Diffusion Pathway in Li(1.3)Al(0.3)Ti(1.7)(PO4)3 (LATP) Superionic Conductor.Inorganic chemistry, 55 6
D. Aurbach (2000)
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteriesJournal of Power Sources, 89
J. Choi, Jae-won Lee (2016)
Improved electrochemical properties of Li(Ni 0.6 Mn 0.2 Co 0.2 )O 2 by surface coating with Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3Journal of Power Sources, 307
A. D’Angelo, M. Panzer (2018)
Decoupling the Ionic Conductivity and Elastic Modulus of Gel Electrolytes: Fully Zwitterionic Copolymer Scaffolds in Lithium Salt/Ionic Liquid SolutionsAdvanced Energy Materials, 8
Xian‐Xiang Zeng, Ya‐Xia Yin, Nianwu Li, W. Du, Yu‐Guo Guo, L. Wan (2016)
Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries.Journal of the American Chemical Society, 138 49
Shuang‐Jie Tan, Xian‐Xiang Zeng, Q. Ma, Xiongwei Wu, Yu‐Guo Guo (2018)
Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium BatteriesElectrochemical Energy Reviews, 1
Jia‐Yan Liang, Xian‐Xiang Zeng, Xu-Dong Zhang, Peng-fei Wang, Jing Ma, Ya‐Xia Yin, Xiongwei Wu, Yu‐Guo Guo, L. Wan (2018)
Mitigating Interfacial Potential Drop of Cathode-Solid Electrolyte via Ionic Conductor Layer To Enhance Interface Dynamics for Solid Batteries.Journal of the American Chemical Society, 140 22
Nan Chen, Haiqin Zhang, Li Li, Renjie Chen, Shaojun Guo (2018)
Ionogel Electrolytes for High‐Performance Lithium Batteries: A ReviewAdvanced Energy Materials, 8
Tong‐Tong Zuo, Xiongwei Wu, Chunpeng Yang, Ya‐Xia Yin, Huan Ye, Nianwu Li, Yu‐Guo Guo (2017)
Graphitized Carbon Fibers as Multifunctional 3D Current Collectors for High Areal Capacity Li AnodesAdvanced Materials, 29
Irene Osada, Henrik Vries, B. Scrosati, S. Passerini (2016)
Ionic-Liquid-Based Polymer Electrolytes for Battery Applications.Angewandte Chemie, 55 2
Wei Dong, Xian‐Xiang Zeng, Xu-Dong Zhang, Jin‐Yi Li, Ji-Lei Shi, Yaonan Xiao, Yang Shi, R. Wen, Ya‐Xia Yin, Taishan Wang, Chun-Ru Wang, Yu‐Guo Guo (2018)
Gradiently Polymerized Solid Electrolyte Meets with Micro-/Nanostructured Cathode Array.ACS applied materials & interfaces, 10 21
Shuangyan Lang, Yang Shi, Yu‐Guo Guo, Dong Wang, R. Wen, L. Wan (2016)
Insight into the Interfacial Process and Mechanism in Lithium-Sulfur Batteries: An In Situ AFM Study.Angewandte Chemie, 55 51
A. Stephan (2006)
Review on gel polymer electrolytes for lithium batteriesEuropean Polymer Journal, 42
Chen‐Zi Zhao, Xue‐Qiang Zhang, Xin‐Bing Cheng, Rui Zhang, Rui Xu, Peng Chen, Hong‐Jie Peng, Jiaqi Huang, Qiang Zhang (2017)
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodesProceedings of the National Academy of Sciences, 114
Xiaogang Han, Yunhui Gong, Kun Fu, Xingfeng He, Greg Hitz, J. Dai, A. Pearse, Boyang Liu, Howard Wang, G. Rubloff, Yifei Mo, V. Thangadurai, E. Wachsman, Liangbing Hu (2017)
Negating interfacial impedance in garnet-based solid-state Li metal batteries.Nature materials, 16 5
Hua Xie, Chunpeng Yang, Kun Fu, Yonggang Yao, Feng Jiang, Emily Hitz, Boyang Liu, Sha Wang, Liangbing Hu (2018)
Flexible, Scalable, and Highly Conductive Garnet‐Polymer Solid Electrolyte Templated by Bacterial CelluloseAdvanced Energy Materials, 8
Mun Kim, Jin Ryu, Deepika, Young Lim, I. Nah, Kwang-Ryeol Lee, L. Archer, W. Cho (2018)
Langmuir–Blodgett artificial solid-electrolyte interphases for practical lithium metal batteriesNature Energy, 3
Junpei Yue, Min Yan, Ya‐Xia Yin, Yu‐Guo Guo (2018)
Progress of the Interface Design in All‐Solid‐State Li–S BatteriesAdvanced Functional Materials, 28
A. Best, M. Forsyth, D. Macfarlane (2000)
Stoichiometric changes in lithium conducting materials based on Li1+xAlxTi2−x(PO4)3: impedance, X-ray and NMR studiesSolid State Ionics, 136
Chunpeng Yang, Ya‐Xia Yin, Shuai-Feng Zhang, Nianwu Li, Yu‐Guo Guo (2015)
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodesNature Communications, 6
P. Bruce, C. Vincent (1987)
Steady state current flow in solid binary electrolyte cellsJournal of Electroanalytical Chemistry, 225
Xian‐Xiang Zeng, Ya‐Xia Yin, Yang Shi, Xu-Dong Zhang, H. Yao, R. Wen, Xiongwei Wu, Yu‐Guo Guo (2018)
Lithiation-Derived Repellent toward Lithium Anode Safeguard in Quasi-solid BatteriesChem, 4
Research Program of the Chinese Academy of Sciences (Grant No. XDA 21070300)
Wu Xu, Jiulin Wang, F. Ding, Xilin Chen, E. Nasybulin, Yaohui Zhang, Ji‐Guang Zhang (2014)
Lithium metal anodes for rechargeable batteriesEnergy and Environmental Science, 7
Jiwoong Bae, Yutao Li, Jun Zhang, Xingyi Zhou, Fei Zhao, Ye Shi, J. Goodenough, Guihua Yu (2018)
A 3D Nanostructured Hydrogel-Framework-Derived High-Performance Composite Polymer Lithium-Ion Electrolyte.Angewandte Chemie, 57 8
F. Croce, G. Appetecchi, L. Persi, B. Scrosati (1998)
Nanocomposite polymer electrolytes for lithium batteriesNature, 394
Raimund Koerver, Isabel Aygün, Thomas Leichtweiss, C. Dietrich, Wenbo Zhang, J. Binder, P. Hartmann, W. Zeier, J. Janek (2017)
Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid ElectrolytesChemistry of Materials, 29
Herein, a composite polymer electrolyte with a viscoelastic and nonflammable interface is designed to handle the contact issue and preclude Li dendrite formation. The composite polymer electrolyte (cellulose acetate/polyethylene glycol/Li1.4Al0.4Ti1.6P3O12) exhibits a wide electrochemical window of 5 V (vs Li+/Li), a high Li+ transference number of 0.61, and an excellent ionic conductivity of above 10−4 S cm−1 at 60 °C. In particular, the intimate contact, low interfacial impedance, and fast ion‐transport process between the electrodes and solid electrolytes can be simultaneously achieved by the viscoelastic and nonflammable layer. Benefiting from this novel design, solid lithium metal batteries with either LiFePO4 or LiCoO2 as cathode exhibit superior cyclability and rate capability, such as a discharge capacity of 157 mA h g−1 after 100 cycles at C/2 and 97 mA h g−1 at 5C for LiFePO4 cathode. Moreover, the smooth and uniform Li surface after long‐term cycling confirms the successful suppression of dendrite formation. The viscoelastic and nonflammable interface modification of solid electrolytes provides a promising and general strategy to handle the interfacial issues and improves the operative safety of solid lithium metal batteries.
Advanced Energy Materials – Wiley
Published: Apr 1, 2019
Keywords: ; ; ;
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