Access the full text.
Sign up today, get DeepDyve free for 14 days.
Woo‐Jin Yoo, Chao‐Jun Li (2006)
Highly efficient oxidative amidation of aldehydes with amine hydrochloride salts.Journal of the American Chemical Society, 128 40
Chunyan Xu, Zhen-Hua Xiao, B. Zhuo, Yu-huang Wang, Pei‐Qiang Huang (2010)
Efficient and chemoselective alkylation of amines/amino acids using alcohols as alkylating reagents under mild conditions.Chemical communications, 46 41
Kai-Jiong Xiao, Jie Luo, Keyin Ye, Yu Wang, Pei‐Qiang Huang (2010)
Direct, one-pot sequential reductive alkylation of lactams/amides with Grignard and organolithium reagents through lactam/amide activation.Angewandte Chemie, 49 17
P. Knochel, W. Dohle, N. Gommermann, F. Kneisel, F. Kopp, Tobias Korn, Ioannis Sapountzis, V. Vu (2003)
Highly functionalized organomagnesium reagents prepared through halogen-metal exchange.Angewandte Chemie, 42 36
Xisheng Wang, D. Leow, jin-quan yu (2011)
Pd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes.Journal of the American Chemical Society, 133 35
M. Movassaghi, M. Hill, O. Ahmad (2007)
Direct synthesis of pyridine derivatives.Journal of the American Chemical Society, 129 33
Rui-feng Yang, Pei‐Qiang Huang (2010)
Studies towards an enantioselective total synthesis of sarain A: a concise asymmetric construction of the diazatricyclic core.Chemistry, 16 34
Jason Schmink, Shane Krska (2011)
Reversed-polarity synthesis of diaryl ketones via palladium-catalyzed cross-coupling of acylsilanes.Journal of the American Chemical Society, 133 49
J. March (1977)
Advanced Organic Chemistry: Reactions, Mechanisms, and Structure
P. Wender, Vishal Verma, Thomas Paxton, Thomas Pillow (2008)
Function-oriented synthesis, step economy, and drug design.Accounts of chemical research, 41 1
Carine Guérot, Boris Tchitchanov, H. Knust, E. Carreira (2011)
Synthesis of novel angular spirocyclic azetidines.Organic letters, 13 4
Hsing‐Jang Liu, Kak‐Shan Shia, X. Shang, B. Zhu (1999)
Organocerium compounds in synthesisTetrahedron, 55
Shi-Chuan Tuo, Jian-Liang Ye, Ai-E Wang, Su-Yu Huang, Pei‐Qiang Huang (2011)
Concise asymmetric total synthesis of 9-epi-sessilifoliamide J.Organic letters, 13 19
I. Baraznenok, V. Nenajdenko, E. Balenkova (2000)
Chemical Transformations Induced by Triflic AnhydrideChemInform, 31
S. Nahm, S. Weinreb (1982)
N-methoxy-n-methylamides as effective acylating agentsTetrahedron Letters, 22
Laure Boymond, M. Rottländer, G. Cahiez, P. Knochel (1998)
Preparation of Highly Functionalized Grignard Reagents by an Iodine-Magnesium Exchange Reaction and its Application in Solid-Phase Synthesis.Angewandte Chemie, 37 12
Tomohiro Iwai, Tetsuaki Fujihara, J. Terao, Y. Tsuji (2012)
Iridium-catalyzed addition of aroyl chlorides and aliphatic acid chlorides to terminal alkynes.Journal of the American Chemical Society, 134 2
T. Imamoto, Yasushi Sugiura, Nobuyuki Takiyama (1985)
Organocerium reagents. Nucleophilic addition to easily enolizable ketonesTetrahedron Letters, 25
G. Barbe, A. Charette (2008)
Highly chemoselective metal-free reduction of tertiary amides.Journal of the American Chemical Society, 130 1
Kai-Jiong Xiao, Yu Wang, Keyin Ye, Pei‐Qiang Huang (2010)
Versatile one-pot reductive alkylation of lactams/amides via amide activation: application to the concise syntheses of bioactive alkaloids (±)-bgugaine, (±)-coniine, (+)-preussin, and (-)-cassine.Chemistry, 16 43
A. Charette, M. Grenon (2001)
Spectroscopic studies of the electrophilic activation of amides with triflic anhydride and pyridineCanadian Journal of Chemistry, 79
Laure Boymond, Mario Rottländer, G. Cahiez, P. Knochel (1998)
DARSTELLUNG HOCHFUNKTIONALISIERTER GRIGNARD-REAGENTIEN DURCH EINE IOD-MAGNESIUM-AUSTAUSCHREAKTION UND IHRE ANWENDUNG IN DER FESTPHASENSYNTHESEAngewandte Chemie, 110
G. Bartoli, E. Marcantoni, M. Marcolini, L. Sambri (2010)
Applications of CeCl(3) as an environmental friendly promoter in organic chemistry.Chemical reviews, 110 10
William Bechara, G. Pelletier, A. Charette (2012)
Chemoselective synthesis of ketones and ketimines by addition of organometallic reagents to secondary amides.Nature chemistry, 4 3
M. Wasa, K. Engle, David Lin, E. Yoo, jin-quan yu (2011)
Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.Journal of the American Chemical Society, 133 49
A. Charette, M. Grenon, Alexandre Lemire, Mehrnaz Pourashraf, J. Martel (2001)
Practical and highly regio- and stereoselective synthesis of 2-substituted dihydropyridines and piperidines: application to the synthesis of (-)-coniine.Journal of the American Chemical Society, 123 47
A. Pohland, W. Benson (1966)
β-Chlorovinyl KetonesChemical Reviews, 66
Quan Chen, L. Ilies, E. Nakamura (2011)
Cobalt-catalyzed ortho-alkylation of secondary benzamide with alkyl chloride through directed C-H bond activation.Journal of the American Chemical Society, 133 3
P. Knochel, W. Dohle, Nina Gommermann, Florian Kneisel, Felix Kopp, Tobias Korn, Ioannis Sapountzis, Viet Vu (2003)
Synthese hoch funktionalisierter Organomagnesiumreagentien durch Halogen-Metall-AustauschAngewandte Chemie, 115
T. Imamoto, Nobuyuki Takiyama, Kazuki Nakamura, Toshihiko Hatajima, Y. Kamiya (1989)
Reactions of carbonyl compounds with Grignard reagents in the presence of cerium chlorideJournal of the American Chemical Society, 111
Jiaying Xiao, Bo Wang, Guangyin Lu, Ziqiang Zhu, Yujiao Huang (2012)
Imaging of oocyte development using ultrahigh-resolution full-field optical coherence tomography.Applied optics, 51 16
S. Zultanski, G. Fu (2011)
Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplings.Journal of the American Chemical Society, 133 39
J. Medley, M. Movassaghi (2009)
Direct dehydrative N-pyridinylation of amides.The Journal of organic chemistry, 74 3
Sunliang Cui, Jing Wang, Yanguang Wang (2008)
Synthesis of indoles via domino reaction of N-aryl amides and ethyl diazoacetate.Journal of the American Chemical Society, 130 41
Cerium makes it simple: A simple, efficient, and versatile CC bond‐forming method for the direct transformation of secondary amides into ketones by Tf2O‐mediated deaminative alkylation with organocerium reagents is described. A wide variety of ketones, including α,β‐unsaturated ketones, β‐chloroenones, diaryl ketones, and ynones, were synthesized by using this method.
Asian Journal of Organic Chemistry – Wiley
Published: Oct 1, 2012
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.