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Versatile and Direct Transformation of Secondary Amides into Ketones by Deaminative Alkylation with Organocerium Reagents

Versatile and Direct Transformation of Secondary Amides into Ketones by Deaminative Alkylation... Cerium makes it simple: A simple, efficient, and versatile CC bond‐forming method for the direct transformation of secondary amides into ketones by Tf2O‐mediated deaminative alkylation with organocerium reagents is described. A wide variety of ketones, including α,β‐unsaturated ketones, β‐chloroenones, diaryl ketones, and ynones, were synthesized by using this method. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Versatile and Direct Transformation of Secondary Amides into Ketones by Deaminative Alkylation with Organocerium Reagents

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References (34)

Publisher
Wiley
Copyright
Copyright © 2012 Wiley Subscription Services, Inc., A Wiley Company
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201200066
Publisher site
See Article on Publisher Site

Abstract

Cerium makes it simple: A simple, efficient, and versatile CC bond‐forming method for the direct transformation of secondary amides into ketones by Tf2O‐mediated deaminative alkylation with organocerium reagents is described. A wide variety of ketones, including α,β‐unsaturated ketones, β‐chloroenones, diaryl ketones, and ynones, were synthesized by using this method.

Journal

Asian Journal of Organic ChemistryWiley

Published: Oct 1, 2012

Keywords: ; ; ; ;

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