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I. Colquhoun, W. Mcfarlane (1977)
Nuclear magnetic double resonance studies of isotopically labelled bis-(dichlorophosphino)methylamine partially oriented in a nematic liquid crystal
H. Sisler, N. Smith (1961)
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Chemistry of bis(dialkoxyphosphino)methylamines. Mono- and bimetallic complexes of chromium(0), molybdenum(0), tungsten(0), rhodium(I), and ruthenium(II)Organometallics, 9
G. Leeuw, J. Field, R. Haines (1989)
[Co2(CO)4μ-(CH2O)2PN(Et)P(OCH2)22]: A molecule with a symmetrical formula but an unsymmetrical structureJournal of Organometallic Chemistry, 359
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Alkylaminobis(difluorophosphines): novel bidentate ligands for stabilizing low metal oxidation states and metal-metal bonded systemsAccounts of Chemical Research, 13
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Synthesis and structural characterization of the primary-amine-substituted phosphines (C6H5NH)3P and [(C6H5NH)2P]2NC6H5Inorganic Chemistry, 21
Two new diphosphazane ligands, PriN(PPh2)(PO2C6H4) (1) and PriN{P(O2C6H4)}2 (3), have been synthesized and characterized by spectroscopic data. The structure of 1 has been confirmed by single crystal X‐ray diffraction. Crystal data: Monoclinic, C2/c, Z = 16, a = 34.149(5) Å, b = 9.717(6) Å, c = 29.439(5) Å, β = 125.11(2)°, V = 7991 Å3, R = 0.058, Rw = 0.061. This compound shows two different P–N bond lengths (1.654 (4) and 1.743(4) Å) and a P–N–P angle of 120.7(2)°. Variable temperature 31P NMR measurements for 1 and 3 throw light on the nature of the conformers present in solution.
Heteroatom Chemistry – Wiley
Published: Jan 1, 1991
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