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Lu Wang, Guoran Li, Shengqi Liu, Xueping Gao (2021)
Hollow Molybdate Microspheres as Catalytic Hosts for Enhancing the Electrochemical Performance of Sulfur Cathode under High Sulfur Loading and Lean ElectrolyteAdvanced Functional Materials, 31
L. Gerber, Peter Frischmann, Frank Fan, Sean Doris, X. Qu, A. Scheuermann, K. Persson, Y. Chiang, B. Helms (2016)
Three-Dimensional Growth of Li2S in Lithium-Sulfur Batteries Promoted by a Redox Mediator.Nano letters, 16 1
V. Kolosnitsyn, E. Kuzmina, E. Karaseva (2015)
On the reasons for low sulphur utilization in the lithium-sulphur batteriesJournal of Power Sources, 274
Yu‐Xing Yao, Xue‐Qiang Zhang, Bo‐Quan Li, Chong Yan, Peng Chen, Jiaqi Huang, Qiang Zhang (2020)
A compact inorganic layer for robust anode protection in lithium‐sulfur batteries, 2
Weijia Zhou, J. Lu, Kai Zhou, Linjing Yang, Yunting Ke, Zhenghua Tang, Shaowei Chen (2016)
CoSe2 nanoparticles embedded defective carbon nanotubes derived from MOFs as efficient electrocatalyst for hydrogen evolution reactionNano Energy, 28
Long Zhang, Yicheng Liu, Zedong Zhao, Peilu Jiang, Teng Zhang, Mengxiong Li, Shaoxue Pan, Tianyu Tang, Tianqi Wu, Peiying Liu, Yanglong Hou, Hongbing Lu (2020)
Enhanced Polysulfide Regulation via Porous Catalytic V2O3/V8C7 Heterostructures Derived from Metal-Organic Frameworks towards High-Performance Li-S Batteries.ACS nano
Jiaye Yang, Lihong Yu, Bangbei Zheng, Narui Li, Jingyu Xi, X. Qiu (2020)
Carbon Microtube Textile with MoS2 Nanosheets Grown on Both Outer and Inner Walls as Multifunctional Interlayer for Lithium–Sulfur BatteriesAdvanced Science, 7
Chaoqi Zhang, Ruifeng Du, J. Biendicho, Mingjie Yi, Ke Xiao, Dawei Yang, Ting Zhang, Xiang Wang, J. Arbiol, J. Llorca, Yingtang Zhou, J. Morante, A. Cabot (2021)
Tubular CoFeP@CN as a Mott–Schottky Catalyst with Multiple Adsorption Sites for Robust Lithium−Sulfur BatteriesAdvanced Energy Materials, 11
V. Do, Deepika, Mun Kim, Min Kim, Kwang-Ryeol Lee, W. Cho (2019)
Carbon Nitride Phosphorus as an Effective Lithium Polysulfide Adsorbent for Lithium-Sulfur Batteries.ACS applied materials & interfaces, 11 12
Zhonglin Li, Pengyue Li, X. Meng, Zhang Lin, Ruihu Wang (2021)
The Interfacial Electronic Engineering in Binary Sulfiphilic Cobalt Boride Heterostructure Nanosheets for Upgrading Energy Density and Longevity of Lithium‐Sulfur BatteriesAdvanced Materials, 33
Jun Zhang, Ye Shi, Yu Ding, Lele Peng, Wenkui Zhang, Guihua Yu (2017)
A Conductive Molecular Framework Derived Li2S/N,P‐Codoped Carbon Cathode for Advanced Lithium–Sulfur BatteriesAdvanced Energy Materials, 7
Jing Tang, R. Salunkhe, Jian Liu, Nagy Torad, M. Imura, S. Furukawa, Y. Yamauchi (2015)
Thermal conversion of core-shell metal-organic frameworks: a new method for selectively functionalized nanoporous hybrid carbon.Journal of the American Chemical Society, 137 4
Zhaohuan Wei, Yaqi Ren, Joshua Sokolowski, Xiaodong Zhu, Gang Wu (2020)
Mechanistic understanding of the role separators playing in advanced lithium‐sulfur batteriesInfoMat
Zhifu Liang, Dawei Yang, Pengyi Tang, Chaoqi Zhang, Jordi Biendicho, Yi Zhang, J. Llorca, Xiang Wang, Junshan Li, M. Heggen, J. David, R. Dunin‐Borkowski, Yingtang Zhou, J. Morante, A. Cabot, J. Arbiol (2020)
Atomically dispersed Fe in a C2N Based Catalyst as a Sulfur Host for Efficient Lithium–Sulfur BatteriesAdvanced Energy Materials, 11
Rongrong Li, Xuejun Zhou, Hangjia Shen, Minghui Yang, Chilin Li (2019)
Conductive Holey MoO2-Mo3N2 Heterojunctions as Job-Synergistic Cathode Host with Low Surface Area for High Loading Li-S Batteries.ACS nano
Zhejun Li, Yucun Zhou, Y. Wang, Yi‐Chun Lu (2018)
Solvent‐Mediated Li2S Electrodeposition: A Critical Manipulator in Lithium–Sulfur BatteriesAdvanced Energy Materials, 9
Yongsheng Fu, Zhen Wu, Yifei Yuan, Peng Chen, Lei Yu, Lei Yuan, Qiurui Han, Ying-jie Lan, W. Bai, E. Kan, Chengxi Huang, X. Ouyang, Xin Wang, Junwu Zhu, Jun Lu (2020)
Switchable encapsulation of polysulfides in the transition between sulfur and lithium sulfideNature Communications, 11
T. Nguyen, Jayaraman Balamurugan, Hyun Go, Q. Ngo, N. Kim, J. Lee (2022)
Dual-functional Co5.47N/Fe3N heterostructure interconnected 3D N-doped carbon nanotube-graphene hybrids for accelerating polysulfide conversion in Li-S batteriesChemical Engineering Journal, 427
Shixia Chen, Junhui Luo, Nuoyan Li, Xinxin Han, Jun Wang, Q. Deng, Zheling Zeng, S. Deng (2020)
Multifunctional LDH/Co9S8 heterostructure nanocages as high-performance lithium–sulfur battery cathodes with ultralong lifespanEnergy Storage Materials, 30
Zhen-yu Wang, Hui-min Wang, Shengqi Liu, Guoran Li, Xueping Gao (2021)
To Promote the Catalytic Conversion of Polysulfides Using Ni-B Alloy Nanoparticles on Carbon Nanotube Microspheres under High Sulfur Loading and a Lean Electrolyte.ACS applied materials & interfaces
Hyunwon Chu, Jinkwan Jung, Hyungjun Noh, Seongmin Yuk, Jinhong Lee, Ju-Hyuk Lee, J. Baek, Young-Soo Roh, Hyeokjin Kwon, DongWoong Choi, Kwonnam Sohn, YunKyoung Kim, Hee‐Tak Kim (2020)
Unraveling the Dual Functionality of High‐Donor‐Number Anion in Lean‐Electrolyte Lithium‐Sulfur BatteriesAdvanced Energy Materials, 10
Frank Fan, W. Carter, Y. Chiang (2015)
Mechanism and Kinetics of Li2S Precipitation in Lithium–Sulfur BatteriesAdvanced Materials, 27
Won-Gwang Lim, C. Jo, A. Cho, Jongkook Hwang, Seongseop Kim, J. Han, Jinwoo Lee (2018)
Approaching Ultrastable High‐Rate Li–S Batteries through Hierarchically Porous Titanium Nitride Synthesized by Multiscale Phase SeparationAdvanced Materials, 31
Chaoqi Zhang, J. Biendicho, Ting Zhang, Ruifeng Du, Junshan Li, Xuhui Yang, J. Arbiol, Yingtang Zhou, J. Morante, A. Cabot (2019)
Combined High Catalytic Activity and Efficient Polar Tubular Nanostructure in Urchin‐Like Metallic NiCo2Se4 for High‐Performance Lithium–Sulfur BatteriesAdvanced Functional Materials, 29
Zihan Shen, Zili Zhang, Matthew Li, Yifei Yuan, Yue Zhao, Shuo Zhang, Chenglin Zhong, Jia Zhu, Jun Lu, Huigang Zhang (2020)
Rational Design of a Ni3N0.85 Electrocatalyst to Accelerate Polysulfide Conversion in Lithium-Sulfur Batteries.ACS nano
Rongrong Chu, Hewei Song, Z. Ullah, Zhixing Guan, Yingfei Zhang, Liyi Zhao, Mingliang Chen, Weiwei Li, Qi Li, Liwei Liu (2020)
ZIF-8 derived nitrogen-doped carbon composites boost the rate performance of organic cathodes for sodium ion batteriesElectrochimica Acta, 362
Jiarui He, A. Manthiram (2020)
3D CoSe@C Aerogel as a Host for Dendrite‐Free Lithium‐Metal Anode and Efficient Sulfur Cathode in Li–S Full CellsAdvanced Energy Materials, 10
Yongshang Zhang, Peng Zhang, Shijie Zhang, Zheng Wang, Neng Li, S. Silva, G. Shao (2021)
A flexible metallic TiC nanofiber/vertical graphene 1D / 2D heterostructured as active electrocatalyst for advanced Li–S batteriesInfoMat
Jiarui He, A. Manthiram (2019)
A review on the status and challenges of electrocatalysts in lithium-sulfur batteriesEnergy Storage Materials
Zhengqing Ye, Ying Jiang, Li Li, Feng Wu, Renjie Chen (2020)
A High‐Efficiency CoSe Electrocatalyst with Hierarchical Porous Polyhedron Nanoarchitecture for Accelerating Polysulfides Conversion in Li–S BatteriesAdvanced Materials, 32
Nguyen T. T. (2021)
9092J. Mater. Chem. A, 9
T. Nguyen, Jayaraman Balamurugan, Do Kim, N. Kim, J. Lee (2020)
Hierarchical 3D Oxygenated Cobalt Vanadium Selenide Nanosheets as Advanced Electrode for Flexible Zinc-Cobalt and Zinc-Air Batteries.Small
Zhonghao Gu, Chen Cheng, Tianran Yan, Genlin Liu, Jinsen Jiang, Jing Mao, Kehua Dai, Jiong Li, Jinpeng Wu, Liang Zhang (2021)
Synergistic effect of Co3Fe7 alloy and N-doped hollow carbon spheres with high activity and stability for high-performance lithium-sulfur batteriesNano Energy, 86
Xin Wang, L. Zhuang, Tianwei He, Y. Jia, Longzhou Zhang, Xuecheng Yan, Minrui Gao, A. Du, Zhonghua Zhu, X. Yao, Shuhong Yu (2018)
Grafting Cobalt Diselenide on Defective Graphene for Enhanced Oxygen Evolution ReactioniScience, 7
Bin Zhang, C. Luo, Yaqian Deng, Zhijia Huang, Guangmin Zhou, Wei Lv, Yan‐Bing He, Y. Wan, F. Kang, Quan-hong Yang (2020)
Optimized Catalytic WS2–WO3 Heterostructure Design for Accelerated Polysulfide Conversion in Lithium–Sulfur BatteriesAdvanced Energy Materials, 10
Guangmin Zhou, Hongzhen Tian, Yang Jin, X. Tao, Bofei Liu, Rufan Zhang, Z. Seh, Denys Zhuo, Yayuan Liu, Jie Sun, Jie Zhao, Chenxi Zu, David Wu, Qianfan Zhang, Yi Cui (2017)
Catalytic oxidation of Li2S on the surface of metal sulfides for Li−S batteriesProceedings of the National Academy of Sciences, 114
Tao Wang, Qiusheng Zhang, Jiang Zhong, Maoxin Chen, Hongli Deng, Jinhui Cao, Lei Wang, Lele Peng, Jian Zhu, Bingan Lu (2021)
3D Holey Graphene/Polyacrylonitrile Sulfur Composite Architecture for High Loading Lithium Sulfur BatteriesAdvanced Energy Materials, 11
Yanjie Cui, A. Abouimrane, Jun Lu, T. Bolin, Yang Ren, Wei Weng, Chengjun Sun, V. Maroni, S. Heald, K. Amine (2013)
(De)lithiation mechanism of Li/SeS(x) (x = 0-7) batteries determined by in situ synchrotron X-ray diffraction and X-ray absorption spectroscopy.Journal of the American Chemical Society, 135 21
H. Wu, Shuya Wei, Lei Zhang, R. Xu, H. Hng, X. Lou (2013)
Embedding sulfur in MOF-derived microporous carbon polyhedrons for lithium-sulfur batteries.Chemistry, 19 33
Jiawei Li, Zhao Kong, Xiaoxi Liu, B. Zheng, Qiufeng Fan, E. Garratt, T. Schuelke, Keliang Wang, Hui Xu, Hong Jin (2021)
Strategies to anode protection in lithium metal battery: A reviewInfoMat
Zhao‐Qing Liu, Huiyuan Cheng, Nan Li, Tian-Yi Ma, Yu-zhi Su (2016)
ZnCo2O4 Quantum Dots Anchored on Nitrogen‐Doped Carbon Nanotubes as Reversible Oxygen Reduction/Evolution ElectrocatalystsAdvanced Materials, 28
(1920)
Energy Storage Mater
Hao Li, Dan Liu, Xinxin Zhu, D. Qu, Zhizhong Xie, Junsheng Li, Haolin Tang, D. Zheng, D. Qu (2020)
Integrated 3D electrodes based on metal-nitrogen-doped graphitic ordered mesoporous carbon and carbon paper for high-loading lithium-sulfur batteriesNano Energy, 73
Dong Cai, Bingke Liu, Dehua Zhu, Duo Chen, Mengjie Lu, Junming Cao, Yanhu Wang, Wenhao Huang, Yong Shao, Haoran Tu, W. Han (2020)
Ultrafine Co3Se4 Nanoparticles in Nitrogen‐Doped 3D Carbon Matrix for High‐Stable and Long‐Cycle‐Life Lithium Sulfur BatteriesAdvanced Energy Materials, 10
D. Su, M. Cortie, H. Fan, Guoxiu Wang (2017)
Prussian Blue Nanocubes with an Open Framework Structure Coated with PEDOT as High‐Capacity Cathodes for Lithium–Sulfur BatteriesAdvanced Materials, 29
A. Cabot, M. Ibáñez, P. Guardia, A. Alivisatos (2009)
Reaction regimes on the synthesis of hollow particles by the Kirkendall effect.Journal of the American Chemical Society, 131 32
Meng-ting Liu, Samik Jhulki, Zifei Sun, A. Magasinski, Charles Hendrix, G. Yushin (2021)
Atom-economic synthesis of Magnéli phase Ti4O7 microspheres for improved sulfur cathodes for Li–S batteriesNano Energy, 79
Wei M. (2021)
7397Angew. Chem., Int. Ed., 60
Mingjie Wei, Dacheng Liang, X. Cao, Wenjun Luo, Guojian Ma, Zeyuan Liu, Le Li (2020)
A Broad-Spectrum, Catalytic Amidation of Sulfonyl Fluorides and Fluorosulfates.Angewandte Chemie
Lin H. (2017)
1476Energy Environ. Sci., 10
Huilin Pan, K. Han, M. Engelhard, R. Cao, Junzheng Chen, Ji‐Guang Zhang, K. Mueller, Yuyan Shao, Jun Liu (2018)
Addressing Passivation in Lithium–Sulfur Battery Under Lean Electrolyte ConditionAdvanced Functional Materials, 28
Maoxu Wang, Lishuang Fan, Xun Sun, Bin Guan, Bo Jiang, Xian Wu, Da Tian, Kening Sun, Y. Qiu, X. Yin, Yu Zhang, Naiqing Zhang (2020)
Nitrogen-Doped CoSe2 as a Bifunctional Catalyst for High Areal Capacity and Lean Electrolyte of Li–S BatteryACS energy letters, 5
X. Tao, Jianguo Wang, Chong Liu, Haotian Wang, Hongbin Yao, G. Zheng, Z. Seh, Q. Cai, Weiyang Li, Guangmin Zhou, Chenxi Zu, Yi Cui (2016)
Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium–sulfur battery designNature Communications, 7
Xiangcun Li, Yue Zhang, Shuting Wang, Yang Liu, Yu Ding, G. He, Xiaobin Jiang, W. Xiao, Guihua Yu (2020)
Scalable High-Areal-Capacity Li-S Batteries Enabled by Sandwich-Structured Hierarchically Porous Membranes with Intrinsic Polysulfide Adsorption.Nano letters
M. Jafarian, M. Mahjani, F. Gobal, I. Danaee (2006)
Effect of potential on the early stage of nucleation and growth during aluminum electrocrystallization from molten salt (AlCl3–NaCl–KCl)Journal of Electroanalytical Chemistry, 588
Zhou J. (2014)
2715Energy Environ. Sci., 7
density functional theory, heterostructures, lithium-sulfur batteries, metal-organic frameworks Received
Wenzhi Tian, Baojuan Xi, Zhenyu Feng, Haibo Li, Jinkui Feng, S. Xiong (2019)
Sulfiphilic Few‐Layered MoSe2 Nanoflakes Decorated rGO as a Highly Efficient Sulfur Host for Lithium‐Sulfur BatteriesAdvanced Energy Materials, 9
P. Ge, Sijie Li, Laiqiang Xu, Kangyu Zou, X. Gao, Xiaoyu Cao, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji (2018)
Hierarchical Hollow‐Microsphere Metal–Selenide@Carbon Composites with Rational Surface Engineering for Advanced Sodium StorageAdvanced Energy Materials, 9
M. Ibáñez, Jiandong Fan, Wenhua Li, D. Cadavid, Raquel Nafria, Alex Carrete, A. Cabot (2011)
Means and Limits of Control of the Shell Parameters in Hollow Nanoparticles Obtained by the Kirkendall EffectChemistry of Materials, 23
Dawei Yang, Chaoqi Zhang, J. Biendicho, Xu Han, Zhifu Liang, Ruifeng Du, Mengyao Li, Junshan Li, J. Arbiol, J. Llorca, Yingtang Zhou, J. Morante, A. Cabot (2020)
ZnSe/N-Doped Carbon Nanoreactor with Multiple Adsorption Sites for Stable Lithium-Sulfur Batteries.ACS nano
Zhenzhen Du, Xingjia Chen, Wei Hu, Chenghao Chuang, Shuai-Lei Xie, Ajuan Hu, Wensheng Yan, X. Kong, Xiaojun Wu, Hengxing Ji, L. Wan (2019)
Cobalt in Nitrogen-Doped Graphene as Single-Atom Catalyst for High-Sulfur Content Lithium-Sulfur Batteries.Journal of the American Chemical Society, 141 9
Zhe Yuan, Hong‐Jie Peng, Tingzheng Hou, Jiaqi Huang, Chengmeng Chen, Dai‐Wei Wang, Xin‐Bing Cheng, F. Wei, Qiang Zhang (2016)
Powering Lithium-Sulfur Battery Performance by Propelling Polysulfide Redox at Sulfiphilic Hosts.Nano letters, 16 1
Haoran Xu, Lanling Zhao, Xiaomeng Liu, Qishun Huang, Yueqing Wang, Chuan-xin Hou, Yuyang Hou, Jun Wang, Feng Dang, Jintao Zhang (2020)
Metal‐Organic‐Framework Derived Core‐Shell N‐Doped Carbon Nanocages Embedded with Cobalt Nanoparticles as High‐Performance Anode Materials for Lithium‐Ion BatteriesAdvanced Functional Materials, 30
M. Nabar, S. Paralkar (1975)
Thermal decomposition of some divalent metal selenatesThermochimica Acta, 11
Donghee Gueon, Minghui Ju, J. Moon (2020)
Complete encapsulation of sulfur through interfacial energy control of sulfur solutions for high-performance Li−S batteriesProceedings of the National Academy of Sciences of the United States of America, 117
Rechargeable lithium–sulfur batteries (LSBs) are recognized as a promising candidate for next‐generation energy storage devices because of their high theoretical specific capacity and energy density. However, the insulating of sulfur, Li2S2/Li2S, and the shuttling effect of high order lithium polysulfides (LiPSs) hinder its practical applications. Herein, a heterostructure is explored to enhance the conversion reaction kinetics and adsorption ability of LiPSs. By rationally designing a conductive carbon framework and polar metal sites, both experimental and theoretical results show strong adsorption abilities for dissolved LiPSs and promote the conversion reaction rate. A CoSe2/Co3O4@NC‐CNT/S cathode shows an excellent rate performance (≈1457 mAh g−1 at 0.1 C and still retains ≈688 mAh g−1 at a high rate of 5 C). When performing charge–discharge in long‐term stability at 2 C, the CoSe2/Co3O4@NC‐CNT/S cathode delivers a high initial specific capacity of ≈780 mAh g−1 and retains ≈602 mAh g−1 after 500 cycles with an excellent Coulombic efficiency of ≈95.4%. Remarkably, the battery can entirely operate even at a very high sulfur loading of ≈10.1 mg cm−2 and lean electrolyte condition. This work emphasizes a new strategy to rationally design heterostructures that can encourage the industrial application of LSBs.
Advanced Energy Materials – Wiley
Published: Mar 1, 2022
Keywords: accelerated conversion; density functional theory; heterostructures; lithium–sulfur batteries; metal‐organic frameworks
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