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Unexpected conversions of selected heteroorganic compounds

Unexpected conversions of selected heteroorganic compounds A few unexpected conversions of selected heteroorganic compounds are described, including the formation of N‐sulfonyl sulfenamide derivatives and the mixed phosphinyl‐sulfenyl anhydrides in the reactions of sulfinyl chlorides with α‐phenylethylamine or t‐butyl‐phenylphosphine oxide, respectively. Unexpected reactions of the ortho hydroxyalkyl‐substituted diaryl sulfoxides and hypervalent sulfur and selenium derivatives, induced by triphenylphosphine, are also presented. Attempts to rationalize the observed reaction courses are briefly discussed. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:437–442, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10077 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Unexpected conversions of selected heteroorganic compounds

Heteroatom Chemistry , Volume 13 (5) – Jan 1, 2002

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References (11)

Publisher
Wiley
Copyright
Copyright © 2002 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.10077
Publisher site
See Article on Publisher Site

Abstract

A few unexpected conversions of selected heteroorganic compounds are described, including the formation of N‐sulfonyl sulfenamide derivatives and the mixed phosphinyl‐sulfenyl anhydrides in the reactions of sulfinyl chlorides with α‐phenylethylamine or t‐butyl‐phenylphosphine oxide, respectively. Unexpected reactions of the ortho hydroxyalkyl‐substituted diaryl sulfoxides and hypervalent sulfur and selenium derivatives, induced by triphenylphosphine, are also presented. Attempts to rationalize the observed reaction courses are briefly discussed. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:437–442, 2002; Published online in Wiley Interscience (www.interscience.wiley.com). DOI 10.1002/hc.10077

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2002

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