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Trifluoromethylsulfonylmethanides functionalized by a CN group

Trifluoromethylsulfonylmethanides functionalized by a CN group Novel stable carbanions of the generalformula −C(SO2CF3)n(CN)3−n (n = 1,2) were synthesized. The solid‐state structure of cesium cyanobis(trifluoromethylsulfonyl)methanide was determined by single‐crystal X‐ray diffraction. Phenyldiazonium cyanobis(triluoromethylsulfonyl)methanide underwent decomposition to yield theoxo‐sulfonium ylide—trifluoromethyl(phenoxy)oxosulfonium cyano(trifluoromethylsulfonyl)methanide. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9: 565–570, 1998 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Trifluoromethylsulfonylmethanides functionalized by a CN group

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Publisher
Wiley
Copyright
Copyright © 1998 Wiley Subscription Services
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/(SICI)1098-1071(1998)9:6<565::AID-HC7>3.0.CO;2-3
Publisher site
See Article on Publisher Site

Abstract

Novel stable carbanions of the generalformula −C(SO2CF3)n(CN)3−n (n = 1,2) were synthesized. The solid‐state structure of cesium cyanobis(trifluoromethylsulfonyl)methanide was determined by single‐crystal X‐ray diffraction. Phenyldiazonium cyanobis(triluoromethylsulfonyl)methanide underwent decomposition to yield theoxo‐sulfonium ylide—trifluoromethyl(phenoxy)oxosulfonium cyano(trifluoromethylsulfonyl)methanide. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9: 565–570, 1998

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1998

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