Access the full text.
Sign up today, get DeepDyve free for 14 days.
G. Bazzan, J. Deneault, Tae‐Sik Kang, B. Taylor, M. Durstock (2011)
Nanoparticle/Dye Interface Optimization in Dye‐Sensitized Solar CellsAdvanced Functional Materials, 21
Priti Tiwana, P. Parkinson, M. Johnston, H. Snaith, L. Herz (2010)
Ultrafast terahertz conductivity dynamics in mesoporous TiO2: Influence of dye sensitization and surface treatment in solid-state dye-sensitized solar cellsJournal of Physical Chemistry C, 114
H. Snaith, R. Humphry‐Baker, Peter Chen, I. Cesar, S. Zakeeruddin, M. Grätzel (2008)
Charge collection and pore filling in solid-state dye-sensitized solar cellsNanotechnology, 19
M. Law, Lori Greene, Justin Johnson, R. Saykally, P. Yang (2005)
Nanowire dye-sensitized solar cellsNature Materials, 4
U. Bach, D. Lupo, P. Comte, J. Moser, F. Weissörtel, J. Salbeck, H. Spreitzer, M. Grätzel (1998)
Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficienciesNature, 395
N. Neale, N. Kopidakis, J. Lagemaat, M. Grätzel, A. Frank (2005)
Effect of a coadsorbent on the performance of dye-sensitized TiO2 solar cells: shielding versus band-edge movement.The journal of physical chemistry. B, 109 49
P. Yang, Dongyuan Zhao, D. Margolese, B. Chmelka, G. Stucky (1998)
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworksNature, 396
P. Kumar, S. Badrinarayanan, M. Sastry (2000)
Nanocrystalline TiO2 studied by optical, FTIR and X-ray photoelectron spectroscopy: correlation to presence of surface statesThin Solid Films, 358
B. Morgan, G. Watson (2007)
A DFT+U description of oxygen vacancies at the TiO2 rutile (110) surfaceSurface Science, 601
N. Cai, S. Moon, Lê Cevey-Ha, T. Moehl, R. Humphry‐Baker, Peng Wang, S. Zakeeruddin, M. Grätzel (2011)
An organic D-π-A dye for record efficiency solid-state sensitized heterojunction solar cells.Nano letters, 11 4
Sung Choi, M. Mamak, N. Coombs, N. Chopra, G. Ozin (2004)
Thermally Stable Two‐Dimensional Hexagonal Mesoporous Nanocrystalline Anatase, Meso‐nc‐TiO2: Bulk and Crack‐Free Thin Film MorphologiesAdvanced Functional Materials, 14
B. O'Regan, M. Grätzel (1991)
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 filmsNature, 353
A. Yella, Hsuan‐Wei Lee, H. Tsao, C. Yi, A. Chandiran, Md. Nazeeruddin, E. Diau, C. Yeh, S. Zakeeruddin, M. Grätzel (2011)
Porphyrin-Sensitized Solar Cells with Cobalt (II/III)–Based Redox Electrolyte Exceed 12 Percent EfficiencyScience, 334
Edward Crossland, M. Kamperman, M. Nedelcu, C. Ducati, U. Wiesner, D. Smilgies, G. Toombes, M. Hillmyer, S. Ludwigs, U. Steiner, H. Snaith (2009)
A bicontinuous double gyroid hybrid solar cell.Nano letters, 9 8
E. Crepaldi, Galo Soler-Illia, D. Grosso, F. Cagnol, F. Ribot, C. Sanchez (2003)
Controlled formation of highly organized mesoporous titania thin films: from mesostructured hybrids to mesoporous nanoanatase TiO2.Journal of the American Chemical Society, 125 32
T. Dittrich, E. Lebedev, J. Weidmann (1998)
Electron Drift Mobility in Porous TiO2 (Anatase)Physica Status Solidi (a), 165
C. Tyler, Jian Qin, F. Bates, D. Morse (2007)
SCFT Study of Nonfrustrated ABC Triblock Copolymer MeltsMacromolecules, 40
J. Krüger, R. Plass, M. Grätzel, P. Cameron, L. Peter (2003)
Charge transport and back reaction in solid-state dye-sensitized solar cells: A study using intensity-modulated photovoltage and photocurrent spectroscopyJournal of Physical Chemistry B, 107
F. Fabregat‐Santiago, J. Bisquert, L. Cevey, Peter Chen, Mingkui Wang, S. Zakeeruddin, M. Grätzel (2009)
Electron transport and recombination in solid-state dye solar cell with spiro-OMeTAD as hole conductor.Journal of the American Chemical Society, 131 2
S. Guldin, M. Kolle, M. Stefik, R. Langford, D. Eder, U. Wiesner, U. Steiner (2011)
Tunable Mesoporous Bragg Reflectors Based on Block‐Copolymer Self‐AssemblyAdvanced Materials, 23
H. Snaith (2010)
Estimating the Maximum Attainable Efficiency in Dye‐Sensitized Solar CellsAdvanced Functional Materials, 20
Peter Simon, R. Ulrich, H. Spiess, U. Wiesner (2001)
Block Copolymer−Ceramic Hybrid Materials from Organically Modified Ceramic PrecursorsChemistry of Materials, 13
M. Stefik, Surbhi Mahajan, Hiroaki Sai, Thomas Epps, F. Bates, S. Gruner, F. Disalvo, Ulrich Wiesner (2009)
Ordered three- and five-ply nanocomposites from ABC block terpolymer microphase separation with niobia and aluminosilicate sols.Chemistry of materials : a publication of the American Chemical Society, 21 22
B. Smarsly, D. Grosso, T. Brezesinski, N. Pinna, C. Boissière, M. Antonietti, C. Sanchez (2004)
Highly crystalline cubic mesoporous TiO₂ with 10-nm pore diameter made with a new block copolymer templateChemistry of Materials, 16
Wha-Tek Kim, Changdae Kim, Q. Choi (1984)
Sub-band-gap photoresponse of Ti O 2 − x thin-film—electrolyte interfacePhysical Review B, 30
D. Bruggeman (1935)
Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. I. Dielektrizitätskonstanten und Leitfähigkeiten der Mischkörper aus isotropen SubstanzenAnnalen der Physik, 416
J. Kroon, N. Bakker, H. Smit, P. Liska, K. Thampi, Peng Wang, S. Zakeeruddin, M. Grätzel, A. Hinsch, S. Hore, U. Würfel, R. Sastrawan, J. Durrant, E. Palomares, H. Pettersson, T. Gruszecki, Jan Walter, K. Skupień, G. Tulloch (2007)
Nanocrystalline dye‐sensitized solar cells having maximum performanceProgress in Photovoltaics: Research and Applications, 15
J. Bisquert, A. Zaban, Miri Greenshtein, I. Mora‐Seró (2004)
Determination of rate constants for charge transfer and the distribution of semiconductor and electrolyte electronic energy levels in dye-sensitized solar cells by open-circuit photovoltage decay method.Journal of the American Chemical Society, 126 41
Jinwoo Lee, M. Orilall, S. Warren, M. Kamperman, F. Disalvo, U. Wiesner (2008)
Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores.Nature materials, 7 3
M. Stefik, Suntao Wang, R. Hovden, Hiroaki Sai, M. Tate, D. Muller, U. Steiner, S. Gruner, U. Wiesner (2012)
Networked and chiral nanocomposites from ABC triblock terpolymer coassembly with transition metal oxide nanoparticlesJournal of Materials Chemistry, 22
A. Usami (1997)
Theoretical study of application of multiple scattering of light to a dye-sensitized nanocrystalline photoelectrichemical cellChemical Physics Letters, 277
V. Shklover, Y. Ovchinnikov, L. Braginsky, S. Zakeeruddin, M. Graetzel (1998)
Structure of Organic/Inorganic Interface in Assembled Materials Comprising Molecular Components. Crystal Structure of the Sensitizer Bis[(4,4‘-carboxy-2,2‘-bipyridine)(thiocyanato)]ruthenium(II)Chemistry of Materials, 10
H. Snaith, A. Petrozza, S. Ito, H. Miura, M. Grätzel (2009)
Charge Generation and Photovoltaic Operation of Solid‐State Dye‐Sensitized Solar Cells Incorporating a High Extinction Coefficient Indolene‐Based SensitizerAdvanced Functional Materials, 19
M. Nedelcu, S. Guldin, M. Orilall, Jinwoo Lee, S. Hüttner, Edward Crossland, S. Warren, C. Ducati, P. Laity, D. Eder, U. Wiesner, U. Steiner, H. Snaith (2010)
Monolithic route to efficient dye-sensitized solar cells employing diblock copolymers for mesoporous TiO2Journal of Materials Chemistry, 20
S. Hore, C. Vetter, R. Kern, H. Smit, A. Hinsch (2006)
Influence of scattering layers on efficiency of dye-sensitized solar cellsSolar Energy Materials and Solar Cells, 90
Jun‐Ho Yum, E. Baranoff, S. Wenger, Md. Nazeeruddin, M. Grätzel (2011)
Panchromatic engineering for dye-sensitized solar cellsEnergy and Environmental Science, 4
H. Snaith, M. Grätzel (2007)
Electron and Hole Transport through Mesoporous TiO2 Infiltrated with Spiro‐MeOTADAdvanced Materials, 19
Brian and, F. Lenzmann (2004)
Charge Transport and Recombination in a Nanoscale Interpenetrating Network of n-Type and p-Type Semiconductors: Transient Photocurrent and Photovoltage Studies of TiO2/Dye/CuSCN Photovoltaic CellsJournal of Physical Chemistry B, 108
N. Tétreault, E. Horváth, T. Moehl, J. Brillet, R. Smajda, Stéphane Bungener, N. Cai, Peng Wang, S. Zakeeruddin, L. Forró, A. Magrez, M. Grätzel (2010)
High-efficiency solid-state dye-sensitized solar cells: fast charge extraction through self-assembled 3D fibrous network of crystalline TiO2 nanowires.ACS nano, 4 12
S. Guldin, S. Hüttner, Priti Tiwana, M. Orilall, Burak Ülgüt, M. Stefik, P. Docampo, M. Kolle, G. Divitini, C. Ducati, Simon Redfern, H. Snaith, U. Wiesner, D. Eder, U. Steiner (2011)
Improved conductivity in dye-sensitised solar cells through block-copolymer confined TiO2 crystallisationEnergy and Environmental Science, 4
M. Zukalová, A. Zukal, L. Kavan, M. Nazeeruddin, P. Liska, M. Grätzel (2005)
Organized mesoporous TiO2 films exhibiting greatly enhanced performance in dye-sensitized solar cells.Nano letters, 5 9
V. Henrich, G. Dresselhaus, H. Zeiger (1976)
Observation of two-dimensional phases associated with defect states on the surface of TiO/sub 2/. [Ar ion bombardment]Physical Review Letters, 36
Dongyuan Zhao, Jian-yong Feng, Q. Huo, N. Melosh, G. Fredrickson, B. Chmelka, G. Stucky (1998)
Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom poresScience, 279 5350
P. Docampo, S. Guldin, M. Stefik, Priti Tiwana, M. Orilall, S. Hüttner, Hiroaki Sai, U. Wiesner, U. Steiner, H. Snaith (2010)
Control of Solid‐State Dye‐Sensitized Solar Cell Performance by Block‐Copolymer‐Directed TiO2 SynthesisAdvanced Functional Materials, 20
K. Benkstein, N. Kopidakis, J. Lagemaat, A. Frank (2003)
Influence of the percolation network geometry on electron transport in dye-sensitized titanium dioxide solar cellsJournal of Physical Chemistry B, 107
S. Bagshaw, E. Prouzet, T. Pinnavaia (1995)
Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide SurfactantsScience, 269
H. Snaith, L. Schmidt‐Mende (2007)
Advances in Liquid‐Electrolyte and Solid‐State Dye‐Sensitized Solar CellsAdvanced Materials, 19
M. Templin, A. Franck, A. Chesne, H. Leist, Yuanming Zhang, R. Ulrich, V. Schädler, U. Wiesner (1997)
Organically modified aluminosilicate mesostructures from block copolymer phasesScience, 278 5344
M. Nedelcu, Jinwoo Lee, Edward Crossland, S. Warren, M. Orilall, S. Guldin, S. Hüttner, Catarina Ducati, D. Eder, U. Wiesner, U. Steiner, H. Snaith (2009)
Block copolymer directed synthesis of mesoporous TiO2 for dye-sensitized solar cellsSoft Matter, 5
A new self‐assembly platform for the fast and straightforward synthesis of bicontinuous, mesoporous TiO2 films is presented, based on the triblock terpolymer poly(isoprene‐b‐styrene‐b‐ethylene oxide). This new materials route allows the co‐assembly of the metal oxide as a fully interconnected minority phase, which results in a highly porous photoanode with strong advantages over the state‐of‐the‐art nanoparticle‐based photoanodes employed in solid‐state dye‐sensitized solar cells. Devices fabricated through this triblock terpolymer route exhibit a high availability of sub‐bandgap states distributed in a narrow and low enough energy band, which maximizes photoinduced charge generation from a state‐of‐the‐art organic dye, C220. As a consequence, the co‐assembled mesoporous metal oxide system outperformed the conventional nanoparticle‐based electrodes fabricated and tested under the same conditions, exhibiting solar power‐conversion efficiencies of over 5%.
Advanced Energy Materials – Wiley
Published: Jun 1, 2012
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.