Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Transition‐Metal‐Free C−H Silylation: An Emerging Strategy

Transition‐Metal‐Free C−H Silylation: An Emerging Strategy Silicon‐containing molecules are of great interest with widespread applications in several research areas such as polymer chemistry, materials science, medicinal chemistry, and complex molecule synthesis. Transition‐metal‐free C−H silylation is an essential process because this process is useful in fabricating carbon‐silicon bonds which can be further transformed into a number of other compounds. Since transition‐metal‐catalyzed C−H bond silylation is a developed field, therefore this context only contains transition‐metal‐free pathways for transforming C−H bond to C−Si (Si=SiR3) bond. This review has been further categorized and subcategorized based on intermediates involved and catalysts used during this transformation. This synopsis summarizes recent developments in the area of silicon chemistry with a focus of innovative transition‐metal‐free catalytic silylation using different strategies such as free radical, base promoted, Brønsted acid, Lewis acid, and frustrated Lewis pair. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Transition‐Metal‐Free C−H Silylation: An Emerging Strategy

Loading next page...
 
/lp/wiley/transition-metal-free-c-h-silylation-an-emerging-strategy-zqVKKwGeCL

References (2)

Publisher
Wiley
Copyright
© 2021 Wiley‐VCH GmbH
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.202000584
Publisher site
See Article on Publisher Site

Abstract

Silicon‐containing molecules are of great interest with widespread applications in several research areas such as polymer chemistry, materials science, medicinal chemistry, and complex molecule synthesis. Transition‐metal‐free C−H silylation is an essential process because this process is useful in fabricating carbon‐silicon bonds which can be further transformed into a number of other compounds. Since transition‐metal‐catalyzed C−H bond silylation is a developed field, therefore this context only contains transition‐metal‐free pathways for transforming C−H bond to C−Si (Si=SiR3) bond. This review has been further categorized and subcategorized based on intermediates involved and catalysts used during this transformation. This synopsis summarizes recent developments in the area of silicon chemistry with a focus of innovative transition‐metal‐free catalytic silylation using different strategies such as free radical, base promoted, Brønsted acid, Lewis acid, and frustrated Lewis pair.

Journal

Asian Journal of Organic ChemistryWiley

Published: Feb 1, 2021

Keywords: ; ;

There are no references for this article.