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Shuying Nong, W. Dong, Junwen Yin, Bowei Dong, Yue Lu, Xiaotao Yuan, Xin Wang, Kejun Bu, Mingyang Chen, Shan Jiang, Li‐Min Liu, Manling Sui, Fuqiang Huang (2018)
Well-Dispersed Ruthenium in Mesoporous Crystal TiO2 as an Advanced Electrocatalyst for Hydrogen Evolution Reaction.Journal of the American Chemical Society, 140 17
Yao Zheng, Y. Jiao, M. Jaroniec, S. Qiao (2015)
Advancing the electrochemistry of the hydrogen-evolution reaction through combining experiment and theory.Angewandte Chemie, 54 1
Mark Lukowski, Andrew Daniel, Fei Meng, Audrey Forticaux, Linsen Li, Song Jin (2013)
Enhanced hydrogen evolution catalysis from chemically exfoliated metallic MoS2 nanosheets.Journal of the American Chemical Society, 135 28
J. Greeley, T. Jaramillo, J. Bonde, I. Chorkendorff, J. Nørskov (2006)
Computational high-throughput screening of electrocatalytic materials for hydrogen evolutionNature Materials, 5
R. Levie (1963)
On porous electrodes in electrolyte solutions—IVElectrochimica Acta, 9
Jinxian Feng, Siyuan Tong, Y. Tong, Gao‐Ren Li (2018)
Pt-like Hydrogen Evolution Electrocatalysis on PANI/CoP Hybrid Nanowires by Weakening the Shackles of Hydrogen Ions on the Surfaces of Catalysts.Journal of the American Chemical Society, 140 15
F. Qi, Pingjian Li, Yuanfu Chen, Binjie Zheng, Jingbo Liu, Jinhao Zhou, Jiarui He, X. Hao, Wanli Zhang (2017)
Three-dimensional structure of WS2/graphene/Ni as a binder-free electrocatalytic electrode for highly effective and stable hydrogen evolution reactionInternational Journal of Hydrogen Energy, 42
Libo Gao, W. Ren, Huilong Xu, Li Jin, Zhenxing Wang, Teng Ma, Lai-Peng Ma, Zhiyong Zhang, Q. Fu, Lianmao Peng, X. Bao, Hui‐Ming Cheng (2012)
Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinumNature Communications, 3
D. Voiry, M. Salehi, Rafael Silva, T. Fujita, Mingwei Chen, T. Asefa, V. Shenoy, G. Eda, M. Chhowalla (2013)
Conducting MoS₂ nanosheets as catalysts for hydrogen evolution reaction.Nano letters, 13 12
J. Bonde, P. Moses, T. Jaramillo, J. Nørskov, I. Chorkendorff (2008)
Hydrogen evolution on nano-particulate transition metal sulfides.Faraday discussions, 140
J. Newman, C. Tobias (1962)
Theoretical Analysis of Current Distribution in Porous ElectrodesJournal of The Electrochemical Society, 109
(1990)
20, 677; c) J. Bisquert
Li Zheng, Xinhong Cheng, Peiyi Ye, Lingyan Shen, Qian Wang, Dongliang Zhang, Ziyue Gu, Wen Zhou, Dengpeng Wu, Yuehui Yu (2018)
Low temperature growth of three-dimensional network of graphene for high-performance supercapacitor electrodesMaterials Letters, 218
Haiqing Zhou, Fang Yu, Jingying Sun, R. He, Yumei Wang, C. Guo, Feng Wang, Y. Lan, Z. Ren, Shuo Chen (2016)
Highly active and durable self-standing WS2/graphene hybrid catalysts for the hydrogen evolution reactionJournal of Materials Chemistry, 4
J. Bisquert (2002)
Theory of the Impedance of Electron Diffusion and Recombination in a Thin LayerJournal of Physical Chemistry B, 106
E. Santos, A. Lundin, K. Pötting, P. Quaino, W. Schmickler (2009)
Model for the electrocatalysis of hydrogen evolutionPhysical Review B, 79
Tatsuya Shinagawa, Angel Garcia-Esparza, K. Takanabe (2015)
Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversionScientific Reports, 5
P. Somani, Savita Somani, M. Umeno (2006)
Planer nano-graphenes from camphor by CVDChemical Physics Letters, 430
Liang Cheng, Wenjing Huang, Qiufang Gong, Changhai Liu, Zhuang Liu, Yanguang Li, H. Dai (2014)
Ultrathin WS2 nanoflakes as a high-performance electrocatalyst for the hydrogen evolution reaction.Angewandte Chemie, 53 30
K. Novoselov, SUPARNA DUTTASINHA, S. Morozov, D. Jiang, Y. Zhang, S. Dubonos, I. Grigorieva, A. Firsov (2004)
Electric Field Effect in Atomically Thin Carbon FilmsScience, 306
Yung‐Huang Chang, Cheng-Te Lin, Tzu‐Yin Chen, Chang‐Lung Hsu, Yi‐Hsien Lee, Wenjing Zhang, K. Wei, Lain‐Jong Li (2013)
Highly Efficient Electrocatalytic Hydrogen Production by MoSx Grown on Graphene‐Protected 3D Ni FoamsAdvanced Materials, 25
B.Y. Xia, Ya Yan, Xin Wang, X. Lou (2014)
Recent progress on graphene-based hybrid electrocatalystsMaterials horizons, 1
E. Popczun, James McKone, Carlos Read, A. Biacchi, Alex Wiltrout, N. Lewis, R. Schaak (2013)
Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction.Journal of the American Chemical Society, 135 25
K. Kim, Yue Zhao, Houk Jang, Sang Lee, J. Kim, Kwang Kim, Jong-Hyun Ahn, P. Kim, Jae-Young Choi, B. Hong (2009)
Large-scale pattern growth of graphene films for stretchable transparent electrodesNature, 457
K. Emtsev, F. Speck, T. Seyller, L. Ley, J. Riley (2008)
Interaction, growth, and ordering of epitaxial graphene on SiC{0001} surfaces: A comparative photoelectron spectroscopy studyPhysical Review B, 77
H. Monkhorst, J. Pack (1976)
SPECIAL POINTS FOR BRILLOUIN-ZONE INTEGRATIONSPhysical Review B, 13
M. Faber, Song Jin (2014)
Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applicationsEnergy and Environmental Science, 7
Xuesong Li, Weiwei Cai, J. An, Seyoung Kim, J. Nah, Dongxing Yang, R. Piner, A. Velamakanni, I. Jung, E. Tutuc, S. Banerjee, L. Colombo, R. Ruoff (2009)
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper FoilsScience, 324
M. Faber, Mark Lukowski, Qi Ding, N. Kaiser, Song Jin (2014)
Earth-Abundant Metal Pyrites (FeS2, CoS2, NiS2, and Their Alloys) for Highly Efficient Hydrogen Evolution and Polysulfide Reduction ElectrocatalysisThe Journal of Physical Chemistry. C, Nanomaterials and Interfaces, 118
J. Cerdá, F. Soria (2000)
Accurate and transferable extended Huckel-type tight-binding parametersPhysical Review B, 61
Qing Tang, Zhen Zhou, Zhongfang Chen (2015)
Innovation and discovery of graphene‐like materials via density‐functional theory computationsWiley Interdisciplinary Reviews: Computational Molecular Science, 5
Xiehong Cao, Yumeng Shi, Wenhui Shi, Gang Lu, Xiao Huang, Q. Yan, Qichun Zhang, Hua Zhang (2011)
Preparation of novel 3D graphene networks for supercapacitor applications.Small, 7 22
Shengrui Sun, Lian Gao, Yangqiao Liu (2010)
Enhanced dye-sensitized solar cell using graphene-TiO2 photoanode prepared by heterogeneous coagulationApplied Physics Letters, 96
Jiahao Yu, G. Cheng, W. Luo (2017)
Ternary nickel–iron sulfide microflowers as a robust electrocatalyst for bifunctional water splittingJournal of Materials Chemistry, 5
R. Levie (1963)
On porous electrodes in electrolyte solutions: I. Capacitance effects☆Electrochimica Acta, 8
M. Pettes, Hengxing Ji, R. Ruoff, Li Shi (2012)
Thermal transport in three-dimensional foam architectures of few-layer graphene and ultrathin graphite.Nano letters, 12 6
(1963)
8, 751; b) R. de Levie, Electrochim. Acta 1964, 9, 1231; c) R. de Levie
H. Keiser, K. Beccu, M. Gutjahr (1976)
Abschätzung der porenstruktur poröser elektroden aus impedanzmessungenElectrochimica Acta, 21
R. Levie (1965)
The influence of surface roughness of solid electrodes on electrochemical measurementsElectrochimica Acta, 10
H. Becerril, J. Mao, Zunfeng Liu, R. Stoltenberg, Zhenan Bao, Yongsheng Chen (2008)
Evaluation of solution-processed reduced graphene oxide films as transparent conductors.ACS nano, 2 3
T. Jaramillo, K. Jørgensen, J. Bonde, J. Nielsen, S. Horch, I. Chorkendorff (2007)
Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 NanocatalystsScience, 317
X. Geng, Wei Wu, Ning Li, Weiwei Sun, J. Armstrong, A. Al-Hilo, Matthew Brozak, J. Cui, Tar-Pin Chen (2014)
Three‐Dimensional Structures of MoS2 Nanosheets with Ultrahigh Hydrogen Evolution Reaction in Water ReductionAdvanced Functional Materials, 24
J. Thomas (1961)
Kinetics of electrolytic hydrogen evolution and the adsorption of hydrogen by metalsTransactions of The Faraday Society, 57
Subash Sharma, G. Kalita, M. Ayhan, K. Wakita, M. Umeno, M. Tanemura (2013)
Synthesis of hexagonal graphene on polycrystalline Cu foil from solid camphor by atmospheric pressure chemical vapor depositionJournal of Materials Science, 48
Tzu‐Yin Chen, Yung‐Huang Chang, Chang‐Lung Hsu, K. Wei, Chia‐Ying Chiang, Lain‐Jong Li (2013)
Comparative study on MoS2 and WS2 for electrocatalytic water splittingInternational Journal of Hydrogen Energy, 38
M. Zonnevylle, R. Hoffmann, S. Harris (1988)
Thiophene hydrodesulfurization on MoS2; Theoretical aspectsSurface Science, 199
R. Ghosh, S. Mahapatra (2013)
Direct Band-to-Band Tunneling in Reverse Biased $ \hbox{MoS}_{2}$ Nanoribbon p-n JunctionsIEEE Transactions on Electron Devices, 60
Penghui Shao, Jiayu Tian, Xiaoguang Duan, Yi Yang, W. Shi, Xubiao Luo, F. Cui, S. Luo, Shaobin Wang (2019)
Cobalt silicate hydroxide nanosheets in hierarchical hollow architecture with maximized cobalt active site for catalytic oxidationChemical Engineering Journal
A. Nilsson, A. Nilsson, L. Pettersson, B. Hammer, T. Bligaard, C. Christensen, J. Nørskov (2005)
The electronic structure effect in heterogeneous catalysisCatalysis Letters, 100
A. N’Diaye, J. Coraux, Tim Plasa, C. Busse, T. Michely (2008)
Structure of epitaxial graphene on Ir(111)New Journal of Physics, 10
L. Gassa, J. Vilche, M. Ebert, K. Jüttner, W. Lorenz (1990)
Electrochemical impedance spectroscopy on porous electrodesJournal of Applied Electrochemistry, 20
Liming Yang, Zhenglin Chen, Dan Cui, Xubiao Luo, Bin Liang, Lixia Yang, Tianfu Liu, Aijie Wang, S. Luo (2019)
Ultrafine palladium nanoparticles supported on 3D self-supported Ni foam for cathodic dechlorination of florfenicolChemical Engineering Journal
B. Hammer, J. Nørskov (1995)
Why gold is the noblest of all the metalsNature, 376
I. Raistrick (1990)
Impedance studies of porous electrodesElectrochimica Acta, 35
Liting Yan, L. Cao, P. Dai, X. Gu, Dandan Liu, Liangjun Li, Ying Wang, Xuebo Zhao (2017)
Metal‐Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water SplittingAdvanced Functional Materials, 27
S. Cherevko, S. Geiger, O. Kasian, N. Kulyk, Jan-Philipp Grote, A. Savan, B. Shrestha, S. Merzlikin, B. Breitbach, A. Ludwig, K. Mayrhofer (2016)
Oxygen and hydrogen evolution reactions on Ru, RuO2, Ir, and IrO2 thin film electrodes in acidic and alkaline electrolytes: A comparative study on activity and stabilityCatalysis Today, 262
D. Kienle, J. Cerdá, K. Bevan, G. Liang, L. Siddiqui, Avik Ghosh (2006)
Extended Hückel theory for band structure, chemistry, and transport. II. SiliconJournal of Applied Physics, 100
G. Kalita, Matsushima Masahiro, H. Uchida, K. Wakita, M. Umeno (2010)
FEW LAYERS OF GRAPHENE AS TRANSPARENT ELECTRODE FROM BOTANICAL DERIVATIVE CAMPHORMaterials Letters, 64
Zongping Chen, W. Ren, Libo Gao, Bilu Liu, S. Pei, Hui‐Ming Cheng (2011)
Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition.Nature materials, 10 6
Charlie Tsai, F. Abild-Pedersen, J. Nørskov (2014)
Tuning the MoS₂ edge-site activity for hydrogen evolution via support interactions.Nano letters, 14 3
A. Han, Song Jin, Huanling Chen, Hengxing Ji, Zijun Sun, Pingwu Du (2015)
A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14Journal of Materials Chemistry, 3
Zhixiong Cai, Xinhong Song, Yiru Wang, Xi Chen (2015)
Electrodeposition‐Assisted Synthesis of Ni2P Nanosheets on 3D Graphene/Ni Foam Electrode and Its Performance for Electrocatalytic Hydrogen Production, 2
Xiaochen Dong, Xuewan Wang, Lianhui Wang, Hao Song, Hua Zhang, Wei Huang, Peng Chen (2012)
3D graphene foam as a monolithic and macroporous carbon electrode for electrochemical sensing.ACS applied materials & interfaces, 4 6
J. Nørskov, T. Bligaard, Á. Logadóttir, J. Kitchin, Jingguang Chen, S. Pandelov, U. Stimming (2005)
Trends in the exchange current for hydrogen evolutionJournal of The Electrochemical Society, 152
Yanguang Li, Hailiang Wang, Liming Xie, Yongye Liang, Guosong Hong, H. Dai (2011)
MoS2 nanoparticles grown on graphene: an advanced catalyst for the hydrogen evolution reaction.Journal of the American Chemical Society, 133 19
G. Eda, G. Fanchini, M. Chhowalla (2008)
Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material.Nature nanotechnology, 3 5
Wenxin Zhu, Rong-zhu Zhang, Fengli Qu, Abdullah Asiri, Xuping Sun (2017)
Design and Application of Foams for ElectrocatalysisChemCatChem, 9
Yao Zheng, Y. Jiao, Yihan Zhu, Luhua Li, Yu Han, Y. Chen, A. Du, M. Jaroniec, S. Qiao (2014)
Hydrogen evolution by a metal-free electrocatalystNature Communications, 5
J. Turner (2004)
Sustainable Hydrogen ProductionScience, 305
Hong Li, Qing Zhang, C. Yap, B. Tay, Teo Edwin, A. Olivier, D. Baillargeat (2012)
From Bulk to Monolayer MoS2: Evolution of Raman ScatteringAdvanced Functional Materials, 22
Transition metal dichalcogenides (TMDCs), MoS2, and WS2 have emerged as low‐cost and earth‐abundant electrocatalysts for hydrogen evolution reaction (HER). In this work, electrocatalytic HER performance of these TMDCs, supported by few layered graphene and loaded on a 3D framework of Ni foam (Gr/NF), is reported. The graphene in Gr/NF is prepared from inexpensive camphor by atmospheric pressure chemical vapor deposition. The graphene‐supported TMDCs anchored on the Ni foam are demonstrated with a low overpotential for HER below 200 mV at a current density of 10 mA cm−2 which is comparable to their edge terminated counterparts and surpassing that of unsupported bulk or amorphous TMDCs. In addition, their small Tafel slopes (95 and 83 mV dec−1 for MoS2‐ and WS2‐based Gr/NF electrocatalysts, respectively), charge transfer resistance, and long‐term stability make them promising non‐noble electrocatalysts. First principle investigations of the (Mo/W)S2/Gr/NF heterostructure shows that their enhanced electrocatalytic activity can be attributed to the d‐band shift in the transition metals, Mo/W (a larger shift for WS2) by Ni, promoting unoccupied antibonding orbitals which facilitate the hydrogen adsorption–desorption process.
Advanced Sustainable Systems – Wiley
Published: Jul 1, 2019
Keywords: ; ; ; ;
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