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Levelized Cost and Levelized Avoided Cost of New Generation Resources in the Annual Energy Outlook 2020. https://www.eia.gov/outlooks/aeo/pdf/electricity_generation (accessed: August 2020)
H. Willauer, F. Dimascio, D. Hardy, F. Williams (2014)
Feasibility of CO2 Extraction from Seawater and Simultaneous Hydrogen Gas Generation Using a Novel and Robust Electrolytic Cation Exchange Module Based on Continuous Electrodeionization TechnologyIndustrial & Engineering Chemistry Research, 53
T. Möller, W. Ju, A. Bagger, Xingli Wang, F. Luo, Trung Thanh, A. Varela, J. Rossmeisl, P. Strasser (2019)
Efficient CO2 to CO electrolysis on solid Ni–N–C catalysts at industrial current densitiesEnergy & Environmental Science
Sijie Guo, Siqi Zhao, Xiuqin Wu, Hao Li, Yunjie Zhou, Cheng Zhu, N. Yang, Xin Jiang, Jin Gao, L. Bai, Yang Liu, Y. Lifshitz, Shuitong Lee, Zhenhui Kang (2017)
A Co3O4-CDots-C3N4 three component electrocatalyst design concept for efficient and tunable CO2 reduction to syngasNature Communications, 8
Shan Gao, Yue Lin, Xingchen Jiao, Yongfu Sun, Q. Luo, Wenhua Zhang, Dianqi Li, Jinlong Yang, Yi Xie (2016)
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuelNature, 529
D. Jang, Heesu Ahn, Junghoon Oh, Donggyu Lim, Chulhee Kim, Seungjoo Choi, Young-Hoon Kim, Jinwoo Park, K. Jang, R. Yoo, Tae‐Woo Lee, Jeongho Kim, Y. Lee, Dong Kim, Sungjin Park (2020)
Production of Metal‐Free C, N Alternating Nanoplatelets and Their In Vivo Fluorescence Imaging Performance without LabelingAdvanced Functional Materials, 30
Qun Yi, Wenying Li, Jie Feng, K. Xie (2015)
Carbon cycle in advanced coal chemical engineering.Chemical Society reviews, 44 15
Minghui Zhu, Jiacheng Chen, Libei Huang, Ruquan Ye, Jing Xu, Yi-fan Han (2019)
Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction.Angewandte Chemie, 58 20
Nicolas Dubouis, A. Serva, Roxanne Berthin, Guillaume Jeanmairet, Benjamin Porcheron, Elodie Salager, M. Salanne, A. Grimaud (2020)
Tuning water reduction through controlled nanoconfinement within an organic liquid matrixNature Catalysis, 3
Chade Lv, Yumin Qian, Chunshuang Yan, Yu Ding, Yuanyue Liu, Gang Chen, Guihua Yu (2018)
Defect Engineering Metal-Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions.Angewandte Chemie, 57 32
Levelized (2014)
Levelized Cost and Levelized Avoided Cost of New Generation Resources in the Annual Energy Outlook 2020
Girma Woyessa, Jay-ar Cruz, M. Rameez, C. Hung (2021)
Nanocomposite catalyst of graphitic carbon nitride and Cu/Fe mixed metal oxide for electrochemical CO2 reduction to COApplied Catalysis B-environmental, 291
Chong‐Yong Lee, G. Wallace (2018)
CO2 electrolysis in seawater: calcification effect and a hybrid self-powered conceptJournal of Materials Chemistry, 6
N. Gupta, Bo Peng, G. Haller, E. Ember, J. Lercher (2016)
Nitrogen Modified Carbon Nano-Materials as Stable Catalysts for Phosgene SynthesisACS Catalysis, 6
Le Zhang, Fangxin Mao, L. Zheng, Hai Wang, Xiao Yang, H. Yang (2018)
Tuning Metal Catalyst with Metal–C3N4 Interaction for Efficient CO2 ElectroreductionACS Catalysis
Fei-Yue Gao, Rui-Cheng Bao, Minrui Gao, Shuhong Yu (2020)
Electrochemical CO2-to-CO conversion: electrocatalysts, electrolytes, and electrolyzersJournal of Materials Chemistry, 8
T. Enokida, R. Hirohashi (1991)
Cobalt phthalocyanine crystal synthesized at low temperatureChemistry of Materials, 3
Junmei Chen, K. Zou, P. Ding, Jun Deng, C. Zha, Yongpan Hu, Xuan Zhao, Jialing Wu, Jian Fan, Yanguang Li (2018)
Conjugated Cobalt Polyphthalocyanine as the Elastic and Reprocessable Catalyst for Flexible Li–CO2 BatteriesAdvanced Materials, 31
Gracita Tomboc, Songa Choi, Taehyun Kwon, Y. Hwang, Kwangyeol Lee (2020)
Potential Link between Cu Surface and Selective CO2 Electroreduction: Perspective on Future Electrocatalyst DesignsAdvanced Materials, 32
Yuchen Hao, Yu Guo, Li-Wei Chen, M. Shu, Xin‐Yu Wang, Tong Bu, Wen-Yan Gao, Nan Zhang, Xin Su, Xiao Feng, Junwen Zhou, Bo Wang, Changwen Hu, Anxiang Yin, R. Si, Ya‐Wen Zhang, Chunhua Yan (2019)
Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in waterNature Catalysis, 2
Wenming Tong, Mark Forster, F. Dionigi, Sören Dresp, Roghayeh Erami, P. Strasser, Alexander Cowan, Pau Farràs (2020)
Electrolysis of low-grade and saline surface waterNature Energy, 5
F. Dionigi, T. Reier, Zarina Pawolek, Manuel Gliech, P. Strasser (2016)
Design Criteria, Operating Conditions, and Nickel-Iron Hydroxide Catalyst Materials for Selective Seawater Electrolysis.ChemSusChem, 9 9
C. Higman, S. Tam (2014)
Advances in coal gasification, hydrogenation, and gas treating for the production of chemicals and fuels.Chemical reviews, 114 3
Min Liu, Y. Pang, Bo Zhang, Bo Zhang, P. Luna, O. Voznyy, Jixian Xu, Xue-Li Zheng, Xue-Li Zheng, C. Dinh, Fengjia Fan, Changhong Cao, F. Arquer, T. Safaei, A. Mepham, A. Klinkova, E. Kumacheva, T. Filleter, D. Sinton, S. Kelley, E. Sargent (2016)
Enhanced electrocatalytic CO2 reduction via field-induced reagent concentrationNature, 537
Jinshui Zhang, Mingwen Zhang, Can Yang, Xinchen Wang (2014)
Nanospherical Carbon Nitride Frameworks with Sharp Edges Accelerating Charge Collection and Separation at a Soft Photocatalytic InterfaceAdvanced Materials, 26
Libo Sun, Vikas Reddu, A. Fisher, Xin Wang (2020)
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalystsEnergy and Environmental Science, 13
E. Nisbet, E. Dlugokencky, P. Bousquet (2014)
Methane on the Rise—AgainScience, 343
Ibadillah Digdaya, Ian Sullivan, Meng Lin, Lihao Han, Wen‐Hui Cheng, H. Atwater, C. Xiang (2020)
A direct coupled electrochemical system for capture and conversion of CO2 from oceanwaterNature Communications, 11
Phil Luna, C. Hahn, Drew Higgins, S. Jaffer, T. Jaramillo, E. Sargent (2019)
What would it take for renewably powered electrosynthesis to displace petrochemical processes?Science, 364
Amit Kumar, K. Phillips, Gregory Thiel, U. Schröder, J. Lienhard (2019)
Direct electrosynthesis of sodium hydroxide and hydrochloric acid from brine streamsNature Catalysis, 2
J. Baran, J. Larsson (2013)
Theoretical Insights into Adsorption of Cobalt Phthalocyanine on Ag(111): A Combination of Chemical and van der Waals BondingJournal of Physical Chemistry C, 117
X. Tan, Chang Yu, Yongwen Ren, Song Cui, Wen-bin Li, J. Qiu (2021)
Recent advances in innovative strategies for the CO2 electroreduction reactionEnergy and Environmental Science
Pengfei Xia, M. Antonietti, Bicheng Zhu, T. Heil, Jiaguo Yu, Shaowen Cao (2019)
Designing Defective Crystalline Carbon Nitride to Enable Selective CO2 Photoreduction in the Gas PhaseAdvanced Functional Materials, 29
C. Gabrielli, R. Jaouhari, S. Joiret, G. Maurin, P. Rousseau (2003)
Study of the Electrochemical Deposition of CaCO3 by In Situ Raman Spectroscopy I. Influence of the SubstrateJournal of The Electrochemical Society, 150
Brian Tackett, Elaine Gomez, Jingguang Chen (2019)
Net reduction of CO2 via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processesNature Catalysis, 2
L. Buimaga-Iarinca, C. Morari (2018)
Translation of metal-phthalocyanines adsorbed on Au(111): from van der Waals interaction to strong electronic correlationScientific Reports, 8
Sören Dresp, F. Dionigi, Stefan Loos, Jorge Araújo, C. Spöri, Manuel Gliech, H. Dau, P. Strasser (2018)
Direct Electrolytic Splitting of Seawater: Activity, Selectivity, Degradation, and Recovery Studied from the Molecular Catalyst Structure to the Electrolyzer Cell LevelAdvanced Energy Materials, 8
A. Varela, W. Ju, P. Strasser (2018)
Molecular Nitrogen–Carbon Catalysts, Solid Metal Organic Framework Catalysts, and Solid Metal/Nitrogen‐Doped Carbon (MNC) Catalysts for the Electrochemical CO2 ReductionAdvanced Energy Materials, 8
C. Palmer, D. Upham, S. Smart, Michael Gordon, H. Metiu, Eric McFarland (2020)
Dry reforming of methane catalysed by molten metal alloysNature Catalysis, 3
Jibo Liu, Huijie Shi, Qi Shen, Chenyan Guo, Guohua Zhao (2017)
A biomimetic photoelectrocatalyst of Co–porphyrin combined with a g-C3N4 nanosheet based on π–π supramolecular interaction for high-efficiency CO2 reduction in water mediumGreen Chemistry, 19
Yaping Chen, Qian Zhou, Guoqiang Zhao, Zhenwei Yu, Xiaolin Wang, S. Dou, Wenping Sun (2018)
Electrochemically Inert g‐C3N4 Promotes Water Oxidation CatalysisAdvanced Functional Materials, 28
Shubin Yang, Y. Gong, Jinshui Zhang, L. Zhan, Lulu Ma, Zheyu Fang, R. Vajtai, Xinchen Wang, P. Ajayan (2013)
Exfoliated Graphitic Carbon Nitride Nanosheets as Efficient Catalysts for Hydrogen Evolution Under Visible LightAdvanced Materials, 25
Na Han, Yu Wang, Lu Ma, J. Wen, Jing Li, Hechuang Zheng, Kaiqi Nie, Xinxia Wang, Feipeng Zhao, Yafei Li, Jian Fan, J. Zhong, Tianpin Wu, Dean Miller, Jun Lu, Shui-Tong Lee, Yanguang Li (2017)
Supported Cobalt Polyphthalocyanine for High-Performance Electrocatalytic CO2 ReductionChem, 3
Shiyong Wang, Gang Wang, Tingting Wu, Changping Li, Yuwei Wang, Xinai Pan, Fei Zhan, Yunqi Zhang, Shuaifeng Wang, J. Qiu (2019)
Membrane-Free Hybrid Capacitive Deionization System Based on Redox Reaction for High-Efficiency NaCl Removal.Environmental science & technology, 53 11
In‐Yup Jeon, Yeon-Ran Shin, Gyung-Joo Sohn, Hyun‐Jung Choi, Seo-Yoon Bae, Javeed Mahmood, Sun-Min Jung, Jeong-Min Seo, Minjung Kim, Dong Chang, L. Dai, Jong‐Beom Baek (2012)
Edge-carboxylated graphene nanosheets via ball millingProceedings of the National Academy of Sciences, 109
Anqi Chen, Bo-Lin Lin (2018)
A Simple Framework for Quantifying Electrochemical CO2 FixationJoule, 2
Ziyang Lu, Qinghua Liang, Bo Wang, Ying Tao, Yufeng Zhao, Wei Lv, Donghai Liu, Chen Zhang, Z. Weng, Jiachen Liang, Huan Li, Quan-hong Yang (2019)
Graphitic Carbon Nitride Induced Micro‐Electric Field for Dendrite‐Free Lithium Metal AnodesAdvanced Energy Materials, 9
Young Sa, C. Lee, Si Lee, Jonggeol Na, Ung Lee, Y. Hwang (2020)
Catalyst-electrolyte interface chemistry for electrochemical CO2 reduction.Chemical Society reviews
I. McCrum, Kathleen Schwarz, M. Janik, M. Koper (2017)
Co-adsorption of cations causes the apparent pH dependence of hydrogen adsorption on a stepped platinum single-crystal electrode
Wenping Liu, Yuxia Hou, H. Pan, Wenbo Liu, Dongdong Qi, Kang Wang, Jianzhuang Jiang, X. Yao (2018)
An ethynyl-linked Fe/Co heterometallic phthalocyanine conjugated polymer for the oxygen reduction reactionJournal of Materials Chemistry, 6
N. Gupta, A. Pashigreva, E. Pidko, E. Hensen, L. Mleczko, S. Roggan, E. Ember, J. Lercher (2016)
Bent Carbon Surface Moieties as Active Sites on Carbon Catalysts for Phosgene Synthesis.Angewandte Chemie, 55 5
Yuan Pan, R. Lin, Yinjuan Chen, Shoujie Liu, Wei Zhu, Xing Cao, Wenxing Chen, Konglin Wu, W. Cheong, Yu Wang, Lirong Zheng, Jun Luo, Yan Lin, Yunqi Liu, Chenguang Liu, Jun Li, Q. Lu, Xin Chen, Dingsheng Wang, Q. Peng, Chen Chen, Yadong Li (2018)
Design of Single-Atom Co-N5 Catalytic Site: A Robust Electrocatalyst for CO2 Reduction with Nearly 100% CO Selectivity and Remarkable Stability.Journal of the American Chemical Society, 140 12
Direct CO2 electrolysis in seawater enables the simultaneous conversion of CO2 into CO and the chlorine ions into Cl2, further meeting downstream industry needs such as phosgene synthesis and also facilitating the net consumption of CO2. As a result, the direct implementation of CO2 electrolysis in seawater is urgently required. Herein, a CoPc molecule‐implanted graphitic carbon nitride nanosheets (CoPc/g‐C3N4) electrocatalyst is prepared via a simple mechanochemistry method. The CoPc/g‐C3N4 with a negatively charged surface and preferential adsorption capability for Na+ can achieve appreciable faradaic efficiency (FE, 89.5%) toward CO with a current density of 16.0 mA cm−2 in natural seawater and also realize long‐term operation for 25 h in simulated seawater. Process monitoring further reveals that the chlorine ions in NaCl electrolyte can modulate the reaction microenvironment around the anode, which in turn has positive effects on the CO2RR in cathode. The CO2RR overall splitting in the simulated seawater exhibits a maximum FE of 98.1% towards CO at cell voltage of 3 V. This work describes the development of a carbon‐coupled CoPc molecular catalyst that can drive the CO2 electrolysis in simulated seawater and provides a promising and energy‐saving coupled reaction system for direct coproduction of CO and Cl2.
Advanced Energy Materials – Wiley
Published: Aug 1, 2021
Keywords: ; ; ;
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