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- Publisher
- Wiley
- Copyright
- Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.201100380
- Publisher site
- See Article on Publisher Site
Abstract
A three‐dimensional porous core‐shell Sn@carbon anode on nickel foam substrate was fabricated by electrostatic spray deposition (ESD) technique followed by high temperature treatment. The carbon shell with a thickness of about 3.2 nm was formed on porous Sn structure at high temperature. 3D porous structure and carbon shell were designed to buffer volume expansion/shrinkage of Sn lattice upon cycling and increase the electrical conductivity. After 315 charge/discharge cycles Sn@carbon anode exhibited high specific capacity of 638 mAh g−1 with the low capacity fade of average 0.11 mAh g−1 per cycle. Sn@carbon based anodes was demonstrated to have promising potential for high performance lithium ion batteries application.
Journal
Advanced Energy Materials – Wiley
Published: Feb 1, 2012