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Three‐Dimensional Network Structures Based on Pyridyl‐Calix[4]Arene Metal Complexes

Three‐Dimensional Network Structures Based on Pyridyl‐Calix[4]Arene Metal Complexes A new series of supramolecular assemblies is obtained through the interaction of 3‐pyridylmethyl‐calixarenes and copper or zinc ions. The complexes formed are characterized both in solution and in the solid state. The results offer appealing insights into how the steric crowding of the lower rim and different coordination modes of the metal centers have a great impact on the overall architecture of the complexes with the formation of monomeric, dimeric, or oligomeric/polymeric species. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

Three‐Dimensional Network Structures Based on Pyridyl‐Calix[4]Arene Metal Complexes

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References (47)

Publisher
Wiley
Copyright
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201700400
Publisher site
See Article on Publisher Site

Abstract

A new series of supramolecular assemblies is obtained through the interaction of 3‐pyridylmethyl‐calixarenes and copper or zinc ions. The complexes formed are characterized both in solution and in the solid state. The results offer appealing insights into how the steric crowding of the lower rim and different coordination modes of the metal centers have a great impact on the overall architecture of the complexes with the formation of monomeric, dimeric, or oligomeric/polymeric species.

Journal

ChemPlusChemWiley

Published: Jan 1, 2017

Keywords: ; ; ; ;

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