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Benzo(b)thiophen‐2‐yl‐hydrazonoesters 4 were synthesized by coupling of 2‐diazo‐4,5,6,7‐tetrahydrobenzo(b)thiophene‐3‐carboxamide (1) with either ethyl cyanoacetate or ethyl acetoacetate. The reactivity of 4 toward a variety of nitrogen nucleophiles was investigated to yield pyrazole, isoxazole, pyrimidine, triazine, pyrazolopyridine, and pyrazolopyrimidine derivatives. © 2003 Wiley Periodicals, Inc. 15:15–20, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/.hc10205
Heteroatom Chemistry – Wiley
Published: Jan 1, 2004
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