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The stereoselective synthesis of β‐haloenol phosphates—A reinvestigation of the reaction of α‐haloketones with diethyl phosphite

The stereoselective synthesis of β‐haloenol phosphates—A reinvestigation of the reaction of... A new pathway for the reaction involving an α‐haloketone and a dialkyl phosphite has been suggested, It offers a highly stereoselective synthetic procedure leading to β‐haloenol phosphates in one‐pot reactions that take place in good yields. However, normal Pudovik reaction products were formed when the reaction was carried out using a relatively small amount of base. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 55–59, 1999 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

The stereoselective synthesis of β‐haloenol phosphates—A reinvestigation of the reaction of α‐haloketones with diethyl phosphite

Heteroatom Chemistry , Volume 10 (1) – Jan 1, 1999

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References (16)

Publisher
Wiley
Copyright
Copyright © 1999 John Wiley & Sons, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/(SICI)1098-1071(1999)10:1<55::AID-HC10>3.0.CO;2-B
Publisher site
See Article on Publisher Site

Abstract

A new pathway for the reaction involving an α‐haloketone and a dialkyl phosphite has been suggested, It offers a highly stereoselective synthetic procedure leading to β‐haloenol phosphates in one‐pot reactions that take place in good yields. However, normal Pudovik reaction products were formed when the reaction was carried out using a relatively small amount of base. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 55–59, 1999

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1999

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