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- Publisher
- Wiley
- Copyright
- Copyright © 1995 Wiley Subscription Services
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.520060606
- Publisher site
- See Article on Publisher Site
Abstract
Treatment of tetrakis(triphenylphosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a 1 : 1 mixture of [PtCl2(PPh3)2] and the new compound [Pt(Se2CH2)(PPh3)2], which has been characterized by multinuclear NMR spectroscopy and X‐ray crystallography. Under the same conditions, tetrakis(triphenylphosphine)‐palladium yields only decomposition products. © John Wiley & Sons, Inc.
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 1995