Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/the-nature-of-proton-shuttling-in-protic-ionic-liquid-fuel-cells-KHhr2u0UJy
References (37)
-
T. Yasuda, H. Kinoshita, M. Miran, S. Tsuzuki, M. Watanabe (2013)
Comparative Study on Physicochemical Properties of Protic Ionic Liquids Based on Allylammonium and Propylammonium CationsJournal of Chemical & Engineering Data, 58
-
Geoffrey Burrell, I. Burgar, F. Separovic, N. Dunlop (2010)
Preparation of protic ionic liquids with minimal water content and (15)N NMR study of proton transfer.Physical chemistry chemical physics : PCCP, 12 7
-
Qingfeng Li, J. Jensen, R. Savinell, N. Bjerrum (2009)
High temperature proton exchange membranes based on polybenzimidazoles for fuel cellsProgress in Polymer Science, 34
-
D. Macfarlane, Naoki Tachikawa, M. Forsyth, J. Pringle, P. Howlett, G. Elliott, James Davis, M. Watanabe, P. Simon, C. Angell (2014)
Energy applications of ionic liquidsEnergy and Environmental Science, 7
-
Akihiro Noda, M. Susan, K. Kudo, S. Mitsushima, K. Hayamizu, M. Watanabe (2003)
Brønsted acid-base ionic liquids as proton-conducting nonaqueous electrolytesJournal of Physical Chemistry B, 107
-
C. Karlsson, C. Strietzel, Hao Huang, M. Sjödin, P. Jannasch (2018)
Nonstoichiometric Triazolium Protic Ionic Liquids for All-Organic BatteriesACS Applied Energy Materials
-
Seung-Yul Lee, A. Ogawa, Michihiro Kanno, Hirofumi Nakamoto, T. Yasuda, M. Watanabe (2010)
Nonhumidified intermediate temperature fuel cells using protic ionic liquids.Journal of the American Chemical Society, 132 28
-
P. Atkins, J. Paula (2002)
Atkin's Physical Chemistry -
M. Hoque, Morgan Thomas, M. Miran, Mio Akiyama, Mayeesha Marium, K. Ueno, Kaoru Dokko, M. Watanabe (2018)
Protic ionic liquids with primary alkylamine-derived cations: the dominance of hydrogen bonding on observed physicochemical propertiesRSC Advances, 8
-
Moon Park, Ilyoung Choi, Jaewan Hong, O. Kim (2013)
Polymer electrolytes integrated with ionic liquids for future electrochemical devicesJournal of Applied Polymer Science, 129
-
M. Miran, H. Kinoshita, T. Yasuda, M. Susan, M. Watanabe (2012)
Physicochemical properties determined by ΔpKa for protic ionic liquids based on an organic super-strong base with various Brønsted acids.Physical chemistry chemical physics : PCCP, 14 15
-
J. Bautista-Martínez, Lei Tang, Jean-Philippe Bélières, R. Zeller, C. Angell, C. Friesen (2009)
Hydrogen redox in protic ionic liquids and a direct measurement of proton thermodynamicsJournal of Physical Chemistry C, 113
-
L. Johnson, Andinet Ejigu, P. Licence, D. Walsh (2012)
Hydrogen Oxidation and Oxygen Reduction at Platinum in Protic Ionic LiquidsJournal of Physical Chemistry C, 116
-
M. Miran, T. Yasuda, M. Susan, Kaoru Dokko, M. Watanabe (2014)
Binary Protic Ionic Liquid Mixtures as a Proton Conductor: High Fuel Cell Reaction Activity and Facile Proton TransportJournal of Physical Chemistry C, 118
-
J. Thomson, P. Dunn, L. Holmes, Jean-Philippe Bélières, C. Angell, D. Gervasio (2008)
A Flourinated Ionic Liquid as a High-Performance Fuel Cell Electrolyte, 13
-
M. Watanabe, Morgan Thomas, Shiguo Zhang, K. Ueno, T. Yasuda, Kaoru Dokko (2017)
Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices.Chemical reviews, 117 10
-
(2007)
132, 9764; f) H. Puthen Peediyakkal -
Hasna Peediyakkal, Jie Yu, H. Munakata, K. Kanamura (2019)
Highly Durable Non-Platinum Catalyst for Protic Ionic Liquid Based Intermediate Temperature PEFCsElectrochemistry
-
S. Goodwin, Daniel Smith, J. Gibson, Robert Jones, D. Walsh (2017)
Electroanalysis of Neutral Precursors in Protic Ionic Liquids and Synthesis of High-Ionicity Ionic Liquids.Langmuir : the ACS journal of surfaces and colloids, 33 34
-
André Pinkert, K. Ang, K. Marsh, S. Pang (2011)
Density, viscosity and electrical conductivity of protic alkanolammonium ionic liquids.Physical chemistry chemical physics : PCCP, 13 11
-
Hirofumi Nakamoto, M. Watanabe (2007)
Brønsted acid-base ionic liquids for fuel cell electrolytes.Chemical communications, 24
-
S. Mitsushima, Yoshitsugu Shinohara, K. Matsuzawa, K. Ota (2010)
Mass transportation in diethylmethylammonium trifluoromethanesulfonate for fuel cell applicationsElectrochimica Acta, 55
-
S. Menne, J. Pires, M. Anouti, A. Balducci (2013)
Protic ionic liquids as electrolytes for lithium-ion batteriesElectrochemistry Communications, 31
-
D. Rauber, F. Philippi, J. Zapp, G. Kickelbick, H. Natter, R. Hempelmann (2018)
Transport properties of protic and aprotic guanidinium ionic liquidsRSC Advances, 8
-
J. Asensio, E. Sánchez, P. Gómez‐Romero (2010)
Proton-conducting membranes based on benzimidazole polymers for high-temperature PEM fuel cells. A chemical quest.Chemical Society reviews, 39 8
-
Sa Liu, Li Zhou, Pengjie Wang, Z. Shao, B. Yi (2013)
Nonhumidified high temperature H2/Cl2 fuel cells using protic ionic liquidsJournal of Materials Chemistry, 1
-
Kwan‐Soo Lee, S. Maurya, Y. Kim, C. Kreller, M. Wilson, D. Larsen, S. Elangovan, R. Mukundan (2018)
Intermediate temperature fuel cells via an ion-pair coordinated polymer electrolyteEnergy and Environmental Science, 11
-
Hirofumi Nakamoto, Akihiro Noda, K. Hayamizu, S. Hayashi, H. Hamaguchi, M. Watanabe (2007)
Proton-Conducting Properties of a Brønsted Acid−Base Ionic Liquid and Ionic Melts Consisting of Bis(trifluoromethanesulfonyl)imide and Benzimidazole for Fuel Cell ElectrolytesJournal of Physical Chemistry C, 111
-
Elise Switzer, R. Zeller, Qing Chen, K. Sieradzki, D. Buttry, C. Friesen (2013)
Oxygen Reduction Reaction in Ionic Liquids: The Addition of Protic SpeciesJournal of Physical Chemistry C, 117
-
T. Greaves, C. Drummond (2008)
Protic ionic liquids: properties and applications.Chemical reviews, 108 1
-
M. Miran, M. Hoque, T. Yasuda, S. Tsuzuki, K. Ueno, M. Watanabe (2018)
Key factor governing the physicochemical properties and extent of proton transfer in protic ionic liquids: ΔpKa or chemical structure?Physical chemistry chemical physics : PCCP, 21 1
-
D. Walsh, Andinet Ejigu, Joshua Smith, P. Licence (2013)
Kinetics and mechanism of oxygen reduction in a protic ionic liquid.Physical chemistry chemical physics : PCCP, 15 20
-
F. Barbir (2012)
PEM Fuel Cells: Theory and Practice -
M. Debe (2012)
Electrocatalyst approaches and challenges for automotive fuel cellsNature, 486
-
Sachin Thawarkar, Nageshwar Khupse, Anilesh Kumar (2016)
Comparative Investigation of the Ionicity of Aprotic and Protic Ionic Liquids in Molecular Solvents by using Conductometry and NMR Spectroscopy.Chemphyschem : a European journal of chemical physics and physical chemistry, 17 7
-
Anusorn Kongkanand, M. Mathias (2016)
The Priority and Challenge of High-Power Performance of Low-Platinum Proton-Exchange Membrane Fuel Cells.The journal of physical chemistry letters, 7 7
-
Jelena Stoimenovski, E. Izgorodina, D. Macfarlane (2010)
Ionicity and proton transfer in protic ionic liquids.Physical chemistry chemical physics : PCCP, 12 35
- Publisher
- Wiley
- Copyright
- © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.201900744
- Publisher site
- See Article on Publisher Site
Abstract
It has been proposed previously that protic ionic liquids (PILs) such as diethylmethylammonium triflate could be used as the electrolytes in nonhumidified, intermediate temperature H2 fuel cells, potentially offering the prospect of high conductivity and performance, even under anhydrous conditions. In this contribution, a combination of electroanalytical chemistry and fuel‐cell polarization analyses is used to demonstrate for the first time that the pure PILs cannot support proton shuttling between the electrodes of fuel cells. Only through the inclusion of dissolved acidic or basic proton shuttles can viable protic ionic fuel cells be fabricated, which has major consequences for the use of these neoteric electrolytes in fuel cells.
Journal
Advanced Energy Materials – Wiley
Published: Jun 1, 2019
Keywords: ; ; ;