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- Publisher
- Wiley
- Copyright
- Copyright © 2003 Wiley Periodicals, Inc.
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.10118
- Publisher site
- See Article on Publisher Site
Abstract
A theoretical investigation of both the ortho‐Si(CH3)3 phosphinine and some silacalix(n)phosphinines was performed. The optimized geometries agree well with those reported from X‐ray analysis and other structural studies. The silacalix(n)phosphinine macrocyle is very flexible because of the CSiC bridges. This, in turn, makes possible the formation of strained configurations in solid packed structures. In the silacalix(3)phosphinine, a PP bonding interaction that is presumably responsible for its structural and electronic features seems to exist. The molecular orbital calculations corroborate that both the π‐accepting properties and the σ‐donating capacities of the phosphinine unit may be enhanced by ortho‐Si(CH3)3 substitution. These features satisfy the proposal of the synthesizers as regards the production of macrocyclic phosphorus compounds, with good π‐accepting properties and strong σ‐donating capacities, which are sufficiently flexible as to encapsulate metals with coordination spheres of different geometries. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:160–169, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10118
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 2003