Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

The Charge Storage Mechanisms of 2D Cation‐Intercalated Manganese Oxide in Different Electrolytes

The Charge Storage Mechanisms of 2D Cation‐Intercalated Manganese Oxide in Different Electrolytes 2D ion‐intercalated metal oxides are emerging promising new electrodes for supercapacitors because of their unique layered structure as well as distinctive electronic properties. To facilitate their application, fundamental study of the charge storage mechanism is required. Herein, it is demonstrated that the application of in situ Raman spectroscopy and electrochemical quartz crystal microbalance with dissipation monitoring (EQCM‐D), provides a sufficient basis to elucidate the charge storage mechanism in a typical 2D cation‐intercalated manganese oxide (Na0.55Mn2O4·1.5H2O, abbreviated as NMO) in neutral and alkaline aqueous electrolytes. The results reveal that in neutral Na2SO4 electrolytes, NMO mainly displays a surface‐controlled pseudocapacitive behavior in the low potential region (0–0.8 V), but when the potential is higher than 0.8 V, an intercalation pseudocapacitive behavior becomes dominant. By contrast, NMO shows a battery‐like behavior associated with OH− ions in alkaline NaOH electrolyte. This study verifies that the charge storage mechanism of NMO strongly depends on the type of electrolyte, and even in the same electrolyte, different charging behaviors are revealed in different potential ranges which should be carefully taken into account when optimizing the use of the electrode materials in practical energy‐storage devices. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advanced Energy Materials Wiley

The Charge Storage Mechanisms of 2D Cation‐Intercalated Manganese Oxide in Different Electrolytes

Loading next page...
 
/lp/wiley/the-charge-storage-mechanisms-of-2d-cation-intercalated-manganese-2UiVgFdi8Z

References (64)

Publisher
Wiley
Copyright
Copyright © 2019 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1614-6832
eISSN
1614-6840
DOI
10.1002/aenm.201802707
Publisher site
See Article on Publisher Site

Abstract

2D ion‐intercalated metal oxides are emerging promising new electrodes for supercapacitors because of their unique layered structure as well as distinctive electronic properties. To facilitate their application, fundamental study of the charge storage mechanism is required. Herein, it is demonstrated that the application of in situ Raman spectroscopy and electrochemical quartz crystal microbalance with dissipation monitoring (EQCM‐D), provides a sufficient basis to elucidate the charge storage mechanism in a typical 2D cation‐intercalated manganese oxide (Na0.55Mn2O4·1.5H2O, abbreviated as NMO) in neutral and alkaline aqueous electrolytes. The results reveal that in neutral Na2SO4 electrolytes, NMO mainly displays a surface‐controlled pseudocapacitive behavior in the low potential region (0–0.8 V), but when the potential is higher than 0.8 V, an intercalation pseudocapacitive behavior becomes dominant. By contrast, NMO shows a battery‐like behavior associated with OH− ions in alkaline NaOH electrolyte. This study verifies that the charge storage mechanism of NMO strongly depends on the type of electrolyte, and even in the same electrolyte, different charging behaviors are revealed in different potential ranges which should be carefully taken into account when optimizing the use of the electrode materials in practical energy‐storage devices.

Journal

Advanced Energy MaterialsWiley

Published: Jan 1, 2019

Keywords: ; ; ; ;

There are no references for this article.