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J. Beck, A. Fischer (1995)
SeBr3[AlBr4] und TeI3[AlI4] – zwei weitere Vertreter des SCl3[AlCl4]‐StrukturtypsZeitschrift für anorganische und allgemeine Chemie, 621
J. Passmore, G. Sutherland, P. White (1981)
The synthesis and X-ray crystal structure of triiodotellurium(IV) hexafluoroarsenate(V), TeI3AsF6Canadian Journal of Chemistry, 59
W. Brockner, A. Demiray (1980)
Ramanspektroskopische Untersuchungen des Systems TeCl4SbCl5Zeitschrift für anorganische und allgemeine Chemie, 469
H. Gerding, H. Houtgraaf (1954)
Investigation of the structure of the compounds TeCl4 · AlCl3 and SeCl4 · AlCl3 by means of the Raman effectRecueil des Travaux Chimiques des Pays-Bas, 73
B. Tattershall, N. Kendall (1994)
NMR evidence for new phosphorus halidesPolyhedron, 13
J. Passmore, E. Richardson, T. Whidden, P. White (1980)
The X-ray crystal structures of SeBr3SbF6 and TeBr3AsF6Canadian Journal of Chemistry, 58
H. Gerding, D. Stufkens, H. Gijben (1970)
The vibrational spectra and the ionic structures of the compounds SCl4·SO3, SeCl4· SO3, TeCl4 · SO3 and (CH3)4N · SO3ClRecueil des Travaux Chimiques des Pays-Bas, 89
S. Wolff, T. Ziegler (1998)
Calculation of DFT-GIAO NMR shifts with the inclusion of spin-orbit couplingJournal of Chemical Physics, 109
J. Passmore, P. Boyle, G. Schatte, Todd Way, T. Cameron (1996)
The preparation and characterization of SeCl3SbF6, improved syntheses of MCl3(As/Sb)F6 (M = S, Se), and the X-ray crystal structure determination of SeCl3AsF6 and a new phase of SBr3SbF6Canadian Journal of Chemistry, 74
F. Poulsen, R. Berg (1978)
Addition compounds of sulfur, selenium, or tellurium tetrachloride with niobium or tantalum pentachloride Conductometric and Raman spectroscopic study in the molten and solid stateJournal of Inorganic and Nuclear Chemistry, 40
I. Raabe, K. Wagner, Kristin Guttsche, Mingkui Wang, M. Grätzel, G. Santiso‐Quiñones, I. Krossing (2009)
Tetraalkylammonium salts of weakly coordinating aluminates: ionic liquids, materials for electrochemical applications and useful compounds for anion investigation.Chemistry, 15 8
M. Kaupp, Olga Malkin, V. Malkin (1997)
Interpretation of 13C NMR chemical shifts in halomethyl cations. On the importance of spin-orbit coupling and electron correlationChemical Physics Letters, 265
E. Lenthe, E. Baerends, J. Snijders (1993)
Relativistic regular two‐component HamiltoniansJournal of Chemical Physics, 99
A. Günther, A. Isaeva, A. Baranov, M. Ruck (2011)
Neutral tellurium rings in the coordination polymers [Ru(Te9)](InCl4)2, [Ru(Te8)]Cl2, and [Rh(Te6)]Cl3.Chemistry, 17 23
M. Kaupp (2004)
Relativistic Effects on NMR Chemical ShiftsTheoretical and Computational Chemistry, 14
J. Rautiainen, Todd Way, G. Schatte, J. Passmore, R. Laitinen, R. Suontamo, J. Valkonen (2005)
A computational and experimental study of the structures and Raman and 77Se NMR spectra of SeX3+ and SeX2 (X = Cl, Br, I): FT-Raman spectrum of (SeI3)[AsF6].Inorganic chemistry, 44 6
K. Christe, D. Dixon, Douglas McLemore, W. Wilson, J. Sheehy (2000)
On a Quantitative Scale for Lewis Acidity and Recent Progress in Polynitrogen ChemistryJournal of Fluorine Chemistry, 101
C. Jameson, A. Dios, A. Jameson (1990)
Absolute shielding scale for 31P from gas-phase NMR studiesChemical Physics Letters, 167
Michael Murchie, J. Passmore, P. White (1987)
The characterisation and X-ray crystal structure of pentabromodiselenium hexafluoroarsenate, Se2Br5AsF6; some thermodynamic considerations and the nonexistence of Se2I5AsF6Canadian Journal of Chemistry, 65
A. Reed, L. Curtiss, F. Weinhold (1988)
Intermolecular interactions from a natural bond orbital, donor-acceptor viewpointChemical Reviews, 88
Anna Lehner, Nils Trapp, H. Scherer, I. Krossing (2011)
CCl3(+) and CBr3(+) salts with the [Al(OR(F))4]- and [((F)RO)3Al-F-Al(OR(F))3]- anions (R(F) = C(CF3)3).Dalton transactions, 40 7
I. Krossing, A. Reisinger (2006)
Chemistry with weakly-coordinating fluorinated alkoxyaluminate anions: Gas phase cations in condensed phases?Coordination Chemistry Reviews, 250
I. Krossing, I. Raabe (2004)
Noncoordinating anions--fact or fiction? A survey of likely candidates.Angewandte Chemie, 43 16
M. Kaupp, O. Malkina, V. Malkin, P. Pyykkö (1998)
How Do Spin–Orbit-Induced Heavy-Atom Effects on NMR Chemical Shifts Function? Validation of a Simple Analogy to Spin–Spin Coupling by Density Functional Theory (DFT) Calculations on Some Iodo CompoundsChemistry: A European Journal, 4
A. Edwards, P. Taylor (1973)
Fluoride crystal structures. Part XXI. Trifluorotellurium(IV)µ-fluorobis[pentafluoroantimonate(V)]Journal of The Chemical Society-dalton Transactions
John Slattery, Sharifa Hussein (2012)
How Lewis acidic is your cation? Putting phosphenium ions on the fluoride ion affinity scale.Dalton transactions, 41 6
K. Ooms, K. Feindel, M. Willans, R. Wasylishen, J. Hanna, K. Pike, Mark Smith (2005)
Multiple-magnetic field 139La NMR and density functional theory investigation of the solid lanthanum(III) halides.Solid state nuclear magnetic resonance, 28 2-4
C. Freire-Erdbrügger, D. Jentsch, P. Jones, E. Schwarzmann (1987)
Preparation and Crystal Structure of [TeBr3][AuBr4] · 1/2 Br2, a Compound with “Bromine of Crystallization”Zeitschrift für Naturforschung B, 42
I. Krossing, Angela Bihlmeier, I. Raabe, Nils Trapp (2003)
Structure and characterization of CI3+[Al(OC(CF3)3)4]-; Lewis acidities of CX3+ and BX3.Angewandte Chemie, 42 13
W. Sawodny, K. Dehnicke (1967)
RAMAN‐Spektren und Kraftkonstanten der Hexafluoroarsenate von SCl 3+, SeCl 3+ und TeCl 3+Zeitschrift für anorganische und allgemeine Chemie, 349
W. Brooks, J. Passmore, E. Richardson (1979)
The preparation and Raman spectra of SeBr3AsF6, SeBr3SbF6, TeBr3AsF6, and normal coordinate analyses of the tribromosulphur(IV), tribromoselenium(IV), and tribromotellurium(IV) cationsCanadian Journal of Chemistry, 11
I. Beattie, H. Chudzynska (1967)
The vibrational spectra of some chloro-complexes of sulphur, selenium, and tellurium in the (4+) oxidation stateJournal of The Chemical Society A: Inorganic, Physical, Theoretical
James Johnson, Michael Murchie, J. Passmore, M. Tajik, P. White, C. Wong (1987)
The preparation of SeI3SbF6 and TeI3SbF6; the X-ray crystal structures of SBr3AsF6, SeI3AsF6, SeI3SbF6, and TeI3SbF6; some considerations of the energetics of the formation of SBr3AsF6 and SeI3AsF6.Canadian Journal of Chemistry, 65
Salvador Moncho, J. Autschbach (2010)
Molecular orbital analysis of the inverse halogen dependence of nuclear magnetic shielding in LaX3, X = F, Cl, Br, IMagnetic Resonance in Chemistry, 48
T. Cameron, A. Decken, Isabelle Dionne, Min Fang, I. Krossing, J. Passmore (2002)
Approaching the gas-phase structures of [AgS8]+ and [AgS16]+ in the solid state.Chemistry, 8 15
A. Günther, M. Heise, F. Wagner, M. Ruck (2011)
An iridium-stabilized, formally uncharged Te10 molecule with 3-center-4-electron bonding.Angewandte Chemie, 50 42
I. Brown (1996)
VALENCE: a program for calculating bond valencesJournal of Applied Crystallography, 29
G. Olah, G. Rasul, L. Heiliger, G. Prakash (1996)
Preparation, NMR Spectroscopic, and ab Initio/DFT/GIAO-MP2 Studies of Halomethyl Cations1Journal of the American Chemical Society, 118
I. Krossing, Angela Bihlmeier, Ines Raabe, Nils Trapp (2003)
Struktur und Charakterisierung von CI3+[Al{OC(CF3)3}4]−; Lewis‐Aciditäten von CX3+ und BX3Angewandte Chemie, 115
I. Krossing, Ines Raabe (2004)
Nichtkoordinierende Anionen – Traum oder Wirklichkeit? Eine Übersicht zu möglichen KandidatenAngewandte Chemie, 116
Arnim Hellweg, C. Hättig, S. Höfener, W. Klopper (2007)
Optimized accurate auxiliary basis sets for RI-MP2 and RI-CC2 calculations for the atoms Rb to RnTheoretical Chemistry Accounts, 117
F. Weigend, R. Ahlrichs (2005)
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy.Physical chemistry chemical physics : PCCP, 7 18
S. Wolff, T. Ziegler, E. Lenthe, E. Baerends (1999)
Density functional calculations of nuclear magnetic shieldings using the zeroth-order regular approximation (ZORA) for relativistic effects: ZORA nuclear magnetic resonanceJournal of Chemical Physics, 110
M. Collins, G. Schrobilgen (1985)
Study of the OTeF5 donor properties of Te(OTeF5)4 by 75As and 125Te NMR spectroscopy: preparation and characterization of the [TeFex(OTeF5)3−x]+ cations, TeFx(OTeF5)4−x, As(OTeF5)5, and [As(OTeF5)6]−1Inorganic Chemistry, 24
B. Christian, M. Collins, R. Gillespie, J. Sawyer (1986)
Preparations, Raman spectra, and crystal structures of (SCl3)(SbCl6), (SeCl3)(SbCl6), (SBr1.2Cl1.8)(SbCl6), (TeCl3)(AlCl4) (triclinic modification), (TeCl3)(SbF6), (TeCl3)(AsF6), and (TeF3)2(SO4)Inorganic Chemistry, 25
J. Beck (1990)
Synthese und Kristallstruktur von Te42+(MoOCl4)22- / Synthesis and Crystal Structure of Te42+(MoOCl4)22-Zeitschrift für Naturforschung B, 45
A. Klamt, G. Schüürmann (1993)
COSMO : a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradientJournal of The Chemical Society-perkin Transactions 1
J. Beck (1991)
Tellurium Cations by Lewis Acid‐Base Reactions: Syntheses and Crystal Structures of (Te24⊕)Zr2Br210⊖ and (TeBr3p⊕)(Zr2Br9⊖)Chemische Berichte, 124
G. Velde, F. Bickelhaupt, E. Baerends, C. Guerra, S. Gisbergen, J. Snijders, T. Ziegler (2001)
Chemistry with ADFJournal of Computational Chemistry, 22
T. Cameron, Isabelle Dionne, I. Krossing, J. Passmore (2002)
Reactions directed towards Sb(OTeF5)−6 salts of new tellurium cations: formation, FT-Raman spectrum and X-ray crystal structure of [Cl3TeFTeCl3][Sb(OTeF5)6] containing the μ-fluoro-bis[trichloro-tellurium(IV)] cationSolid State Sciences, 4
J. Perdew, K. Burke, M. Ernzerhof (1996)
Generalized Gradient Approximation Made Simple.Physical review letters, 77 18
B. Krebs, B. Buss, D. Altena (1971)
Die Kristallstruktur von Trichlorotellur(IV)‐tetrachloroaluminat TeCl 3+AlCl 4−Zeitschrift für anorganische und allgemeine Chemie, 386
Anja Günther, M. Heise, F. Wagner, M. Ruck (2011)
Ein Iridium-stabilisiertes, formal neutrales Te10-Molekül mit Drei-Zentren-vier-Elektronen-BindungAngewandte Chemie, 123
I. Krossing (2001)
The facile preparation of weakly coordinating anions: structure and characterisation of silverpolyfluoroalkoxyaluminates AgAl(ORF)4, calculation of the alkoxide ion affinity.Chemistry, 7 2
E. Lang, U. Abram, J. Strähle, E. López (1998)
Synthesis and Crystal Structures of [TeI3][GaI4] and [TeI3][InI4]Zeitschrift für anorganische und allgemeine Chemie, 624
TeX3(Al(ORF)4) (X=Cl, Br, I; RF=C(CF3)3) were synthesized by the reaction of Ag(Al(ORF)4) and TeX4 or the reaction of AuX, Ag(Al(ORF)4), and elemental tellurium in liquid SO2. The compounds were characterized by 125Te NMR in solution and by X‐ray diffraction, Raman, and IR spectroscopy in the solid state. The vibrational spectra and the crystal structure show very weak secondary interactions, indicating “pseudo gas phase conditions” in the condensed phase. The observed trend of the 125Te NMR chemical shifts along the (TeX3)+ series follows neither the monotonous decrease known as “normal halogen dependence” nor the increase known as “inverse halogen dependence”. By relativistic two‐component calculations based on the ZORA approach, we find that this “abnormal halogen dependence” results from an interplay of relativistic and solvent effects, where non‐negligible scalar relativistic effects and intermediate‐sized spin‐orbit effects compensate to some extent. The reasons for these trends are evaluated in the context of the Te s‐orbital character of the TeX bonds and compared with the halogen dependence(s) within the isoelectronic (SeX3)+ and PX3 series and related trihalomethyl (CX3)+ cations.
ChemPlusChem – Wiley
Published: Aug 1, 2012
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