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Synthesis of the new types of N‐substituted aminomethylenebisorganophosphorus acids and their derivatives

Synthesis of the new types of N‐substituted aminomethylenebisorganophosphorus acids and their... The interaction of esters of trivalent organophosphorus acids containing PH and POSiMe3 fragments with various derivatives of formamide is proposed as convenient methods for the synthesis of new N‐substituted aminomethylenebisorganophosphorus acids and their derivatives with three‐, four‐, and five‐coordinated phosphorus. Also the new functionalized derivatives of the new aminomethylenebisphosphinic acids with substituted hydroxymethyl moieties are synthesized, and some properties of the obtained compounds are presented. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:319–324, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20552 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Synthesis of the new types of N‐substituted aminomethylenebisorganophosphorus acids and their derivatives

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References (21)

Publisher
Wiley
Copyright
Copyright © 2009 Wiley Subscription Services
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.20552
Publisher site
See Article on Publisher Site

Abstract

The interaction of esters of trivalent organophosphorus acids containing PH and POSiMe3 fragments with various derivatives of formamide is proposed as convenient methods for the synthesis of new N‐substituted aminomethylenebisorganophosphorus acids and their derivatives with three‐, four‐, and five‐coordinated phosphorus. Also the new functionalized derivatives of the new aminomethylenebisphosphinic acids with substituted hydroxymethyl moieties are synthesized, and some properties of the obtained compounds are presented. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:319–324, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20552

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2009

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