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Synthesis of new organophosphorus‐substituted derivatives of ethanesulfonic acid

Synthesis of new organophosphorus‐substituted derivatives of ethanesulfonic acid Nucleophilic addition of trimethylsilyl esters of hypophosphorus acid to trimethylsilyl ester and diethylamide of vinylsulfonic acid is proposed as convenient methods for the synthesis of new 2‐sulfonylethylphosphonites and their derivatives under mild conditions. Also the new functionalized derivatives of these phosphonites, including aminomethyl fragments as well as certain properties of these compounds as important precursors of new organophosphorus‐substituted derivatives of ethanesulfonic acid, are presented. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:470–473, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20448 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Synthesis of new organophosphorus‐substituted derivatives of ethanesulfonic acid

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References (6)

Publisher
Wiley
Copyright
Copyright © 2008 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.20448
Publisher site
See Article on Publisher Site

Abstract

Nucleophilic addition of trimethylsilyl esters of hypophosphorus acid to trimethylsilyl ester and diethylamide of vinylsulfonic acid is proposed as convenient methods for the synthesis of new 2‐sulfonylethylphosphonites and their derivatives under mild conditions. Also the new functionalized derivatives of these phosphonites, including aminomethyl fragments as well as certain properties of these compounds as important precursors of new organophosphorus‐substituted derivatives of ethanesulfonic acid, are presented. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:470–473, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20448

Journal

Heteroatom ChemistryWiley

Published: Jul 1, 2008

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