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Synthesis of a new phosphorylated ethylamine, thereon based phosphonamidates and their application as flame retardants

Synthesis of a new phosphorylated ethylamine, thereon based phosphonamidates and their... A new phosphorylated ethylamine salt was synthesized that releases the free amine in situ under water‐free conditions. This storable precursor molecule was used to synthesize a mono‐substituted cyanuric chloride. Further substitutions could not be performed due to the low reactivity of this cyanuric chloride derivative. Also, two novel, bridged phosphonamidates were prepared. Owing to the P‐N synergy, they show enlarged char yields and therefore are promising flame retardants. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Synthesis of a new phosphorylated ethylamine, thereon based phosphonamidates and their application as flame retardants

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References (35)

Publisher
Wiley
Copyright
Copyright © 2017 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.21407
Publisher site
See Article on Publisher Site

Abstract

A new phosphorylated ethylamine salt was synthesized that releases the free amine in situ under water‐free conditions. This storable precursor molecule was used to synthesize a mono‐substituted cyanuric chloride. Further substitutions could not be performed due to the low reactivity of this cyanuric chloride derivative. Also, two novel, bridged phosphonamidates were prepared. Owing to the P‐N synergy, they show enlarged char yields and therefore are promising flame retardants.

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2017

Keywords: ; ; ;

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