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Synthesis of 15‐hydroxy‐15(14→8)abeo‐5α, (8S)‐cholestane‐3,14‐dione

Synthesis of 15‐hydroxy‐15(14→8)abeo‐5α, (8S)‐cholestane‐3,14‐dione The synthesis of 15α‐hydroxy‐15(14→8)abeo‐5α,(8S)‐cholestanc‐3.14‐dione (1) from cholesterol in ten steps was described. The key step is the intramolecular aldol condensation of 3.14‐dioxo‐14.15‐seco‐5α‐cholestan‐15‐al (3). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

Synthesis of 15‐hydroxy‐15(14→8)abeo‐5α, (8S)‐cholestane‐3,14‐dione

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References (7)

Publisher
Wiley
Copyright
Copyright © 1993 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1001-604X
eISSN
1614-7065
DOI
10.1002/cjoc.19930110310
Publisher site
See Article on Publisher Site

Abstract

The synthesis of 15α‐hydroxy‐15(14→8)abeo‐5α,(8S)‐cholestanc‐3.14‐dione (1) from cholesterol in ten steps was described. The key step is the intramolecular aldol condensation of 3.14‐dioxo‐14.15‐seco‐5α‐cholestan‐15‐al (3).

Journal

Chinese Journal of ChemistryWiley

Published: May 1, 1993

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