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The synthesis of 15α‐hydroxy‐15(14→8)abeo‐5α,(8S)‐cholestanc‐3.14‐dione (1) from cholesterol in ten steps was described. The key step is the intramolecular aldol condensation of 3.14‐dioxo‐14.15‐seco‐5α‐cholestan‐15‐al (3).
Chinese Journal of Chemistry – Wiley
Published: May 1, 1993
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