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- Publisher
- Wiley
- Copyright
- Copyright © 2000 John Wiley & Sons, Inc.
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/(SICI)1098-1071(2000)11:2<144::AID-HC10>3.0.CO;2-Z
- Publisher site
- See Article on Publisher Site
Abstract
The synthesis of new 1,4‐phenylene‐bis‐(N‐alkylaminomethane)‐bis‐phosphonates 3Aa–3Da by the addition of dialkyl or diaryl phosphites to the azomethine bond of 1,4‐phenylene Schiff bases is reported. Some NMR studies on the stereochemistry of dialkyl phosphite addition to terephthalic bis‐imines showing the exclusive formation of the meso‐form are presented. The mechanism and the origin of such a high stereoselectivity are discussed. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:144–151, 2000
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 2000