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Heterocycles of biological importance. Part 5. The formation of novel biologically active pyrimido[1,2-a]benzimidazoles from allenic nitriles and aminobenzimidazolesJournal of The Chemical Society-perkin Transactions 1
N‐benzimidazol‐2‐yl imidate type 1 reacts with thiourea, carbon disulfide, cyanamide, and hydrazide to give, respectively, (1,2‐a) benzimidazolo‐1,3,5‐triazin‐2‐thione 2, (1,2‐a) benzimidazolo‐1,3,5‐thiadiazin‐2‐thione 3, (1,2‐a) benzimidazolo‐1,3,5‐triazin‐2‐amine 4, and (1,2‐a) benzimidazol‐2‐yl amidrazone 5 with good yields. Structures elucidation of all newly synthesized heterocyclic compounds was based on the data of IR, 1H NMR, 13C NMR, elemental analysis, and MS of some products. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:279–283, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20618
Heteroatom Chemistry – Wiley
Published: Jan 1, 2010
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