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R. Pike (2012)
Structure and Bonding in Copper(I) Carbonyl and Cyanide ComplexesOrganometallics, 31
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M. Dembo, Lars Dunaway, James Jones, E. Lepekhina, S. McCullough, Jasprina Ming, Xiaobo Li, François Baril-Robert, H. Patterson, C. Bayse, R. Pike (2010)
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P. Corfield, Emma Cleary, Joseph Michalski (2016)
Crystal structure of poly[N,N-diethyl-2-hydroxyethan-1-aminium [μ3-cyanido-κ3 C:C:N-di-μ-cyanido-κ4 C:N-dicuprate(I)]]Acta Crystallographica Section E: Crystallographic Communications, 72
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B. Toby, R. Dreele (2013)
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T. Tronic, K. Dekrafft, M. Lim, A. Ley, R. Pike (2007)
Copper(I) cyanide networks: synthesis, luminescence behavior and thermal analysis. Part 1. Diimine ligands.Inorganic chemistry, 46 21
Thorsten Pretsch, H. Hartl (2004)
Der strukturdirigierende Einfluß von α, ω‐Alkandiammoniumionen auf die Bildung von Cyanocupraten(I)Zeitschrift für anorganische und allgemeine Chemie, 630
The compound poly[2‐hydroxy‐N‐methylethan‐1‐aminium [μ3‐cyanido‐κ3C:C:N‐di‐μ‐cyanido‐κ4C:N‐dicuprate(I)]], {(C3H10NO)[Cu2(CN)3]}n or [meoenH]Cu2(CN)3, crystallizes in the tetragonal space group P43. The structure consists of a three‐dimensional (3D) anionic CuICN network with noncoordinated protonated N‐methylethanolamine cations providing charge neutrality. Pairs of cuprophilic Cu atoms are bridged by the C atoms of μ3‐cyanide ligands, which link these units into a 43 spiral along the c axis. The spirals are linked together into a 3D anionic network by the two other cyanide groups. The cationic moieties are linked into their own 43 spiral via N—H…O and O—H…O hydrogen bonds, and the cations interact with the 3D network via an unusual pair of N—H…N hydrogen bonds to one of the μ2‐cyanide groups. Thermogravimetric analysis indicates an initial loss of the base cation and one cyanide as HCN at temperatures in the range 130–250 °C to form CuCN. We show how loss of a specific cyanide group from the 3D CuCN structure could form the linear CuCN structure. Further heating leaves a residue of elemental copper, isolated as the oxide.
Acta Crystallographica Section C: Structural Chemistry – Wiley
Published: Jan 1, 2020
Keywords: ; ; ; ; ; ; ;
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