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ABSTRACT Two new compounds (1 and 2) containing 2‐sulfydryl‐1,3,4‐thiodiazole have been synthesized and optimized. They both showed wide antibacterial activity for colon bacillus, Staphylococcus aureus, S. albus, dysentery bacillus and inferior activity for Bacillus subtilis. In addition, their binding properties were evaluated for biologically important anions (F–, Cl–, Br–, I–, AcO–, and H2PO4–) by theoretical investigation, UV–vis, fluorescence, and 1H NMR titration experiments, and they displayed strong binding ability for H2PO4– without the interference of other anions tested. Especially the binding ability of compound 2 containing anthracene with H2PO4– was 1000 times stronger than that of compound 1 containing nitrobenzene. Two compounds based on 2‐sulfydryl‐1,3,4‐thiodiazole have both properties of anion recognition and antibacterial activity.
Heteroatom Chemistry – Wiley
Published: Mar 1, 2015
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