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Synthesis and crystal structures of novel (4‐phenylthiazol‐2(3H)‐ylidene) benzamide and ((benzoylimino)‐3‐(9,10‐dioxo‐9,10‐dihydroanthracen‐1‐yl)‐4‐oxothiazolidin‐5‐ylidene)acetate derivatives

Synthesis and crystal structures of novel (4‐phenylthiazol‐2(3H)‐ylidene) benzamide and... A new approach to the synthesis of new heterocyclic compounds with benzoylisothiocyanate, amines, and 2‐bromoacetophenone (phenacyl bromide) fragments in one molecule has been developed. The synthesis method comprises condensation reaction for the preparation of novel (4‐phenylthiazol‐2(3H)‐ylidene) benzamide derivatives. These new compounds were synthesized via one‐pot and multicomponent reaction of 2‐furanmethylamine, 5‐chloro‐2‐phenoxyaniline, and 1‐naphthylamine with phenacyl bromide and substituted benzoylisothiocyanates. Moreover, new series of anthraquinone‐thiazole hybrids have been synthesized. These compounds were prepared from unsymmetrical thiourea containing anthraquinone and dialkyl acetylenedicarboxylate. The nature of the compounds was confirmed by IR, 1HNMR, 13CNMR, mass spectrometry, and CHNS elemental analysis. The structural elucidation was accomplished by single‐crystal X‐ray diffraction methods. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Synthesis and crystal structures of novel (4‐phenylthiazol‐2(3H)‐ylidene) benzamide and ((benzoylimino)‐3‐(9,10‐dioxo‐9,10‐dihydroanthracen‐1‐yl)‐4‐oxothiazolidin‐5‐ylidene)acetate derivatives

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References (25)

Publisher
Wiley
Copyright
Copyright © 2017 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.21409
Publisher site
See Article on Publisher Site

Abstract

A new approach to the synthesis of new heterocyclic compounds with benzoylisothiocyanate, amines, and 2‐bromoacetophenone (phenacyl bromide) fragments in one molecule has been developed. The synthesis method comprises condensation reaction for the preparation of novel (4‐phenylthiazol‐2(3H)‐ylidene) benzamide derivatives. These new compounds were synthesized via one‐pot and multicomponent reaction of 2‐furanmethylamine, 5‐chloro‐2‐phenoxyaniline, and 1‐naphthylamine with phenacyl bromide and substituted benzoylisothiocyanates. Moreover, new series of anthraquinone‐thiazole hybrids have been synthesized. These compounds were prepared from unsymmetrical thiourea containing anthraquinone and dialkyl acetylenedicarboxylate. The nature of the compounds was confirmed by IR, 1HNMR, 13CNMR, mass spectrometry, and CHNS elemental analysis. The structural elucidation was accomplished by single‐crystal X‐ray diffraction methods.

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2017

Keywords: ; ; ; ; ; ;

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