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Liqun Guo, D. Ellis, B. Hoffman, Y. Ishikawa (1996)
Ligand Substitution Effect on Electronic Structure and Optical Properties of Nickel PorphyrazinesInorganic Chemistry, 35
J. Lin, L. Dudek (1985)
Preparation and characterization of poly(copper 2,3,9,10,16,17,23,24‐octacyanophthalocyanine)Journal of Polymer Science Part A, 23
D. Wöhrle, D. Schlettwein, G. Schnurpfeil, G. Schneider, E. Karmann, Tsukasa Yoshida, M. Kaneko (1995)
Phthalocyanines and related macrocycles for multi-electron transfer in catalysis, photochemistry and photoelectrochemistryPolymers for Advanced Technologies, 6
C. Nostrum, F. Benneker, H. Brussaard, H. Kooijman, N. Veldman, A. Spek, J. Schoonman, M. Feiters, R. Nolte (1996)
Dithiacrown Ether Substituted Porphyrazines: Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions.Inorganic chemistry, 35 4
M. Tsutsui, K. Kasuga (1980)
Some New Developments in Chemistry of Metallophthalocyanines.
O. Schneider, M. Hanack (1982)
Ein neuer Typ eines organischen Leiters: eindimensional polymerisiertes Phthalocyaninatoeisen(II)†Angewandte Chemie, 94
M. Hanack, M. Lang (1994)
Conducting Stacked Metallophthalocyanines and Related CompoundsAdvanced Materials, 6
O. Schneider, M. Hanack (1980)
Phthalocyaninatoeisen mit Pyrazin als zweizähnigem BrückenligandenAngewandte Chemie, 92
C. Nostrum, R. Nolte (1997)
Functional supramolecular materials: self-assembly of phthalocyanines and porphyrazinesChemical Communications, 1996
Mingyi Liao, Kung-Tu Kuo (1993)
Phthalocyanine Polymers II. Synthesis and Characterization of Fused Metal Phthalocyanine PolymersPolymer Journal, 25
E. Hasty, T. Colburn, D. Hendrickson (1973)
Copper(II) and vanadyl complexes of binucleating ligands. Magnetic exchange interactions propagated through an extensive organic systemInorganic Chemistry, 12
E. Ortí, J. Brédas (1988)
Electronic structure of metal‐free phthalocyanine: A valence effective Hamiltonian theoretical studyJournal of Chemical Physics, 89
D. Wöhrle, Ulrich Marose, R. Knoop (1985)
Polymeric phthalocyanines and their precursors, 8. Synthesis and analytical characterization of polymers from 1,2,4,5‐benzenetetracarbonitrileMacromolecular Chemistry and Physics, 186
B. Achar, J. Bhandari (1993)
Magnetic Properties and ESR Studies on Copper PhthalocyaninesSynthesis and Reactivity in Inorganic and Metal-organic Chemistry, 23
Mingyi Liao, Kung-Tu Kuo (1990)
Phthalocyanine polymers. I. Synthesis and characterization of fused copper phthalocyanine polymersJournal of Polymer Science Part A, 28
H. Simmons, D. Blomstrom, R. Vest (1962)
Thiacyanocarbons. II. Chemistry of Disodium DimercaptomaleonitrileJournal of the American Chemical Society, 84
J. Zagal (1992)
Metallophthalocyanines as catalysts in electrochemical reactionsCoordination Chemistry Reviews, 119
Z. Berkovitch-yellin, D. Ellis (1982)
Electronic structure of free-base and transition-metal tetraazaporphyrinsJournal of the American Chemical Society, 103
The title polymer PCuS4P5 was synthesied by reaction of 2,3‐dicyano‐5,6‐dihydro‐1,4‐dithiin, pyromellitic dianhydride and urea with cuprous salt in optimized gentle method. The structure and properties of the PCuS4P5 were characterized by elemental analysis, X‐ray powder diffraction, IR, UV‐Vis, fluorescence and EPR spectra and variable‐temperature magnetic susceptibility. The polymer is black sublimable crystallite and the degree of polymerisation has been found to be n>4. The PCuS4P5 in H2SO4 exhibits intensive absorption bands at 236, 342, 656 and 767 nm and intensive fluorescence band at 410 nm or 464 nm under the excitation of the ultraviolet light of a determined wavelength at room temperature. It has been found that the polymer exhibits a weaker antiferromagnetic interaction (J=−2.1 cm−l, μaff=1.68 B.M.) with an apparent spin S<1/2 in the ground state and its conductivity σ298K is 1.01×10−5 S·cm−1 at 13.73 MPa.
Chinese Journal of Chemistry – Wiley
Published: Jul 1, 1998
Keywords: ; ; ;
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