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Synthesis and characterization of a new Mo‐Fe‐S cluster compound containing MoO3S3 unit and mixed‐valent Mo atoms [Et4N]2[Mo2Fe(CO)4(S,O‐C6H4‐1,2)3Cl2]

Synthesis and characterization of a new Mo‐Fe‐S cluster compound containing MoO3S3 unit and... Reaction of [Mo3(CO)7(S,O‐C6H4‐1,2)3]2‐ with FeCl2 in MeCN at 60°C affords a new Mo‐Fe‐S cluster complex containing MoO3S3 unit and mixed‐valent Mo atoms, [Et4N]2[Mo2Fe(CO)4(O,S‐C6H4‐1,2)3Cl2] (1). 1 is characterized by elemental analysis, IR, Mössbauer spectra, X‐ray photoelectron spectra and mass spectra. And the structure of 1 is suggested as the structure which contains a [Mo(S,O‐C6H4‐1,2)3] unit of which the two of three sulfur atoms link to a Mo(CO)4‐moiety and the three oxygen atoms are coordinated to a FeCl2 ligand. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

Synthesis and characterization of a new Mo‐Fe‐S cluster compound containing MoO3S3 unit and mixed‐valent Mo atoms [Et4N]2[Mo2Fe(CO)4(S,O‐C6H4‐1,2)3Cl2]

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References (11)

Publisher
Wiley
Copyright
Copyright © 1994 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1001-604X
eISSN
1614-7065
DOI
10.1002/cjoc.19940120603
Publisher site
See Article on Publisher Site

Abstract

Reaction of [Mo3(CO)7(S,O‐C6H4‐1,2)3]2‐ with FeCl2 in MeCN at 60°C affords a new Mo‐Fe‐S cluster complex containing MoO3S3 unit and mixed‐valent Mo atoms, [Et4N]2[Mo2Fe(CO)4(O,S‐C6H4‐1,2)3Cl2] (1). 1 is characterized by elemental analysis, IR, Mössbauer spectra, X‐ray photoelectron spectra and mass spectra. And the structure of 1 is suggested as the structure which contains a [Mo(S,O‐C6H4‐1,2)3] unit of which the two of three sulfur atoms link to a Mo(CO)4‐moiety and the three oxygen atoms are coordinated to a FeCl2 ligand.

Journal

Chinese Journal of ChemistryWiley

Published: Nov 1, 1994

Keywords: ; ; ; ;

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