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Xiaoguang Wang, Wei Li, D. Xiong, D. Petrovykh, Lifeng Liu (2016)
Bifunctional Nickel Phosphide Nanocatalysts Supported on Carbon Fiber Paper for Highly Efficient and Stable Overall Water SplittingAdvanced Functional Materials, 26
A. Ursúa, L. Gandía, P. Sanchis (2012)
Hydrogen Production From Water Electrolysis: Current Status and Future TrendsProceedings of the IEEE, 100
J. Kibsgaard, I. Chorkendorff (2019)
Considerations for the scaling-up of water splitting catalystsNature Energy, 4
Lianyi Shao, Hongming Sun, Licheng Miao, Xiang Chen, Mo Han, Jianchao Sun, Shuang Liu, Lin Li, F. Cheng, Jun Chen (2018)
Facile preparation of NH2-functionalized black phosphorene for the electrocatalytic hydrogen evolution reactionJournal of Materials Chemistry, 6
Yang Wang, Biao Kong, Dongyuan Zhao, Huanting Wang, C. Selomulya (2017)
Strategies for developing transition metal phosphides as heterogeneous electrocatalysts for water splittingNano Today, 15
P. Vesborg, B. Seger, I. Chorkendorff (2015)
Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation.The journal of physical chemistry letters, 6 6
Carlos Morales-Guio, Laurent Liardet, Xile Hu (2016)
Oxidatively Electrodeposited Thin-Film Transition Metal (Oxy)hydroxides as Oxygen Evolution Catalysts.Journal of the American Chemical Society, 138 28
J. Kibsgaard, T. Jaramillo, F. Besenbacher (2014)
Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2- clusters.Nature chemistry, 6 3
Justus Masa, Stefan Barwe, C. Andronescu, I. Sinev, A. Ruff, K. Jayaramulu, K. Elumeeva, Bharathi Konkena, B. Cuenya, W. Schuhmann (2016)
Low Overpotential Water Splitting Using Cobalt–Cobalt Phosphide Nanoparticles Supported on Nickel FoamACS energy letters, 1
Yafei Cheng, Fan Liao, Wen Shen, Liangbin Liu, Binbin Jiang, Yanqing Li, Mingwang Shao (2017)
Carbon cloth supported cobalt phosphide as multifunctional catalysts for efficient overall water splitting and zinc-air batteries.Nanoscale, 9 47
Mater
D. Voiry, M. Chhowalla, Y. Gogotsi, N. Kotov, Yan Li, R. Penner, R. Schaak, P. Weiss (2018)
Best Practices for Reporting Electrocatalytic Performance of Nanomaterials.ACS nano, 12 10
Junyuan Xu, Tianfu Liu, Junjie Li, Bo Li, Yuefeng Liu, Bingsen Zhang, D. Xiong, Isilda Amorim, Wei Li, Lifeng Liu (2018)
Boosting the hydrogen evolution performance of ruthenium clusters through synergistic coupling with cobalt phosphideEnergy and Environmental Science, 11
Rong-Hsiung Chen, Cangjie Yang, Weizheng Cai, Hsin‐Yi Wang, J. Miao, Liping Zhang, Shengli Chen, B. Liu (2017)
Use of Platinum as the Counter Electrode to Study the Activity of Nonprecious Metal Catalysts for the Hydrogen Evolution ReactionACS energy letters, 2
W. Liu, E. Hu, Hong Jiang, Yingjie Xiang, Z. Weng, Min Li, Qi Fan, Xiqian Yu, E. Altman, Hailiang Wang (2016)
A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfideNature Communications, 7
R. Ramachandran, R. Menon (1998)
An overview of industrial uses of hydrogenInternational Journal of Hydrogen Energy, 23
P. Vesborg, T. Jaramillo (2012)
Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energyRSC Advances, 2
S. Anantharaj, S. Kundu (2019)
Do the Evaluation Parameters Reflect Intrinsic Activity of Electrocatalysts in Electrochemical Water Splitting?ACS Energy Letters
N. Godino, X. Borrisé, F. Muñoz, F. Campo, R. Compton (2009)
Mass Transport to Nanoelectrode Arrays and Limitations of the Diffusion Domain Approach: Theory and ExperimentJournal of Physical Chemistry C, 113
T. Hellstern, Jesse Benck, J. Kibsgaard, C. Hahn, T. Jaramillo (2016)
Engineering Cobalt Phosphide (CoP) Thin Film Catalysts for Enhanced Hydrogen Evolution Activity on Silicon PhotocathodesAdvanced Energy Materials, 6
Po-Chia Huang, Sanjaya Brahma, Po-Yen Liu, Jow-Lay Huang, Sheng-Chang Wang, S. Weng, M. Shaikh (2018)
Atmospheric Air Plasma Treated SnS Films: An Efficient Electrocatalyst for HERCatalysts
E. Popczun, James McKone, Carlos Read, A. Biacchi, Alex Wiltrout, N. Lewis, R. Schaak (2013)
Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction.Journal of the American Chemical Society, 135 25
N. Cheng, S. Stambula, Da Wang, M. Banis, Jian Liu, Adam Riese, B. Xiao, Ruying Li, T. Sham, Li‐Min Liu, G. Botton, X. Sun (2016)
Platinum single-atom and cluster catalysis of the hydrogen evolution reactionNature Communications, 7
Javeed Mahmood, Feng Li, Sun-Min Jung, Mahmut Okyay, Ishfaq Ahmad, Seok-Jin Kim, N. Park, H. Jeong, Jong‐Beom Baek (2017)
An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction.Nature nanotechnology, 12 5
Shihui Zou, Michaela Burke, M. Kast, Jie Fan, N. Danilovic, S. Boettcher (2015)
Fe (Oxy)hydroxide Oxygen Evolution Reaction Electrocatalysis: Intrinsic Activity and the Roles of Electrical Conductivity, Substrate, and DissolutionChemistry of Materials, 27
Juan Callejas, Joshua McEnaney, Carlos Read, J. Crompton, A. Biacchi, E. Popczun, Thomas Gordon, N. Lewis, R. Schaak (2014)
Electrocatalytic and photocatalytic hydrogen production from acidic and neutral-pH aqueous solutions using iron phosphide nanoparticles.ACS nano, 8 11
Xiao Shang, Zi-Zhang Liu, Shanshan Lu, B. Dong, Jingqi Chi, Jun-feng Qin, Xien Liu, Y. Chai, Chenguang Liu (2018)
Pt-C Interfaces Based on Electronegativity-Functionalized Hollow Carbon Spheres for Highly Efficient Hydrogen Evolution.ACS applied materials & interfaces, 10 50
E. Popczun, Carlos Read, Christopher Roske, N. Lewis, R. Schaak (2014)
Highly active electrocatalysis of the hydrogen evolution reaction by cobalt phosphide nanoparticles.Angewandte Chemie, 53 21
Xiulin Yang, Ang-Yu Lu, Yihan Zhu, M. Hedhili, Shixiong Min, Kuo‐Wei Huang, Yu Han, Lain‐Jong Li (2015)
CoP nanosheet assembly grown on carbon cloth: A highly efficient electrocatalyst for hydrogen generationNano Energy, 15
T. Whitney, P. Searson, J. Jiang, C. Chien (1993)
Fabrication and Magnetic Properties of Arrays of Metallic NanowiresScience, 261
Zhaoyan Luo, Y. Ouyang, Hao Zhang, Meiling Xiao, J. Ge, Zheng Jiang, Jinlan Wang, Daiming Tang, Xinzhong Cao, Changpeng Liu, Wei Xing (2018)
Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolutionNature Communications, 9
Z. Seh, J. Kibsgaard, Colin Dickens, I. Chorkendorff, J. Nørskov, T. Jaramillo (2017)
Combining theory and experiment in electrocatalysis: Insights into materials designScience, 355
Jesse Benck, B. Pinaud, Yelena Gorlin, T. Jaramillo (2014)
Substrate Selection for Fundamental Studies of Electrocatalysts and Photoelectrodes: Inert Potential Windows in Acidic, Neutral, and Basic ElectrolytePLoS ONE, 9
C. Campbell (2012)
Catalyst-support interactions: Electronic perturbations.Nature chemistry, 4 8
Maoguo Li, Muping Yu, Xiang Li (2018)
Improving the catalytic activity of amorphous molybdenum sulfide for hydrogen evolution reaction using polydihydroxyphenylalanine modified MWCNTsApplied Surface Science, 439
R. Bose, Suresh Balasingam, Seokhee Shin, Zhenyu Jin, D. Kwon, Yongseok Jun, Yo-Sep Min (2015)
Importance of hydrophilic pretreatment in the hydrothermal growth of amorphous molybdenum sulfide for hydrogen evolution catalysis.Langmuir : the ACS journal of surfaces and colloids, 31 18
Qun Li, Zhicai Xing, Abdullah Asiri, P. Jiang, Xuping Sun (2014)
Cobalt phosphide nanoparticles film growth on carbon cloth: A high-performance cathode for electrochemical hydrogen evolutionInternational Journal of Hydrogen Energy, 39
Yu Zhang, Z. Xie, John Wang (2009)
Supramolecular-templated thick mesoporous titania films for dye-sensitized solar cells: effect of morphology on performance.ACS applied materials & interfaces, 1 12
Jesse Benck, T. Hellstern, J. Kibsgaard, Pongkarn Chakthranont, T. Jaramillo (2014)
Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide NanomaterialsACS Catalysis, 4
J. Kibsgaard, T. Jaramillo (2014)
Molybdenum phosphosulfide: an active, acid-stable, earth-abundant catalyst for the hydrogen evolution reaction.Angewandte Chemie, 53 52
Xiaoxin Zou, Yu Zhang (2015)
Noble metal-free hydrogen evolution catalysts for water splitting.Chemical Society reviews, 44 15
Zhenye Kang, Gaoqiang Yang, Jingke Mo, Yifan Li, Shule Yu, D. Cullen, S. Retterer, T. Toops, G. Bender, B. Pivovar, Johney Green, Feng-Yuan Zhang (2018)
Novel thin/tunable gas diffusion electrodes with ultra-low catalyst loading for hydrogen evolution reactions in proton exchange membrane electrolyzer cellsNano Energy, 47
Irene Hsu, Yannick Kimmel, Xiaoqiang Jiang, B. Willis, Jingguang Chen (2012)
Atomic layer deposition synthesis of platinum-tungsten carbide core-shell catalysts for the hydrogen evolution reaction.Chemical communications, 48 7
J. Cecilia, A. Infantes-Molina, E. Rodriguez-castellon, A. Jiménez-lópez (2009)
Dibenzothiophene hydrodesulfurization over cobalt phosphide catalysts prepared through a new synthetic approach: Effect of the supportApplied Catalysis B-environmental, 92
Jingke Mo, Z. Kang, S. Retterer, D. Cullen, T. Toops, Johney Green, M. Mench, Feng-Yuan Zhang (2016)
Discovery of true electrochemical reactions for ultrahigh catalyst mass activity in water splittingScience Advances, 2
Jia Wang, Yu Zhang, Christopher Capuano, K. Ayers (2015)
Ultralow charge-transfer resistance with ultralow Pt loading for hydrogen evolution and oxidation using Ru@Pt core-shell nanocatalystsScientific Reports, 5
Charles McCrory, Suho Jung, Ivonne Ferrer, S. Chatman, J. Peters, T. Jaramillo (2015)
Benchmarking hydrogen evolving reaction and oxygen evolving reaction electrocatalysts for solar water splitting devices.Journal of the American Chemical Society, 137 13
H. Jhong, F. Brushett, P. Kenis (2013)
The Effects of Catalyst Layer Deposition Methodology on Electrode PerformanceAdvanced Energy Materials, 3
Yuancai Ge, Pei Dong, S. Craig, P. Ajayan, M. Ye, Jianfeng Shen (2018)
Transforming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni2P/Fe2P for Efficient Hydrogen Evolution ReactionAdvanced Energy Materials, 8
Jingqi Tian, Qian Liu, Abdullah Asiri, Xuping Sun (2014)
Self-supported nanoporous cobalt phosphide nanowire arrays: an efficient 3D hydrogen-evolving cathode over the wide range of pH 0-14.Journal of the American Chemical Society, 136 21
Yanmei Shi, Bin Zhang (2016)
Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction.Chemical Society reviews, 45 6
Xiangheng Niu, Libo Shi, Xin Li, Jianming Pan, Runxin Gu, Hongli Zhao, F. Qiu, Yongsheng Yan, M. Lan (2017)
Simple anodization of home-made screen-printed carbon electrodes makes significant activity enhancement for hydrogen evolution: the synergistic effect of surface functional groups, defect sites, and hydrophilicityElectrochimica Acta, 235
H. Schucht (1891)
On ElectrolysisProceedings of the Edinburgh Mathematical Society, 10
S. Yu, D. Chua (2018)
Toward High-Performance and Low-Cost Hydrogen Evolution Reaction Electrocatalysts: Nanostructuring Cobalt Phosphide (CoP) Particles on Carbon Fiber Paper.ACS applied materials & interfaces, 10 17
A. Laursen, K. Patraju, M. Whitaker, M. Retuerto, T. Sarkar, N. Yao, K. Ramanujachary, M. Greenblatt, G. Dismukes (2015)
Nanocrystalline Ni5P4: A hydrogen evolution electrocatalyst of exceptional efficiency in both alkaline and acidic mediaEnergy and Environmental Science, 8
Juan Callejas, Carlos Read, Christopher Roske, N. Lewis, R. Schaak (2016)
Synthesis, Characterization, and Properties of Metal Phosphide Catalysts for the Hydrogen-Evolution ReactionChemistry of Materials, 28
Zonghua Pu, Ibrahim Amiinu, Zongkui Kou, Wenqiang Li, Shichun Mu (2017)
RuP2 -Based Catalysts with Platinum-like Activity and Higher Durability for the Hydrogen Evolution Reaction at All pH Values.Angewandte Chemie, 56 38
In this work, a methodology is demonstrated to engineer gas diffusion electrodes for nonprecious metal catalysts. Highly active transition metal phosphides are prepared on carbon‐based gas diffusion electrodes with low catalyst loadings by modifying the O/C ratio at the surface of the electrode. These nonprecious metal catalysts yield extraordinary performance as measured by low overpotentials (51 mV at −10 mA cm−2), unprecedented mass activities (>800 A g−1 at 100 mV overpotential), high turnover frequencies (6.96 H2 s−1 at 100 mV overpotential), and high durability for a precious metal‐free catalyst in acidic media. It is found that a high O/C ratio induces a more hydrophilic surface directly impacting the morphology of the CoP catalyst. The improved hydrophilicity, stemming from introduced oxyl groups on the carbon electrode, creates an electrode surface that yields a well‐distributed growth of cobalt electrodeposits and thus a well‐dispersed catalyst layer with high surface area upon phosphidation. This report demonstrates the high‐performance achievable by CoP at low loadings which facilitates further cost reduction, an important part of enabling the large‐scale commercialization of non‐platinum group metal catalysts. The fabrication strategies described herein offer a pathway to lower catalyst loading while achieving high efficiency and promising stability on a 3D electrode.
Advanced Energy Materials – Wiley
Published: Oct 1, 2019
Keywords: ; ; ; ;
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