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A catalytic method for the incorporation of an SCF3 group to tryptamine derivatives was developed via a sulfide‐catalyzed cascade trifluoromethylthiolation‐cyclization. A series of C(3)‐CF3S pyrrolidinoindolines were obtained in moderate to good yields under mild conditions. Furthermore, some enantioselectivity was observed when using chiral sulfide thiocineole as a catalyst.
Asian Journal of Organic Chemistry – Wiley
Published: May 1, 2019
Keywords: ; ; ; ;
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