Access the full text.
Sign up today, get DeepDyve free for 14 days.
F. Jiang, B. Jiang, Yangdan Cao, Xiang‐guang Meng, Xiao‐Qi Yu, Xiancheng Zeng (2005)
Metallomicellar catalysis: Hydrolysis of phosphate monoester by Cu(II), Zn(II), Ni(II) and Co(II) complexes of pyridyl ligands in CTAB micellar solutionColloids and Surfaces A: Physicochemical and Engineering Aspects, 254
R. Jairam, M. Lau, J. Adorante, P. Potvin (2001)
Ester hydrolysis with 2,6-di(pyrazol-3-yl)pyridines and their CoII complexes in homogeneous and micellar media.Journal of inorganic biochemistry, 84 1-2
C. Hartshorn, J. Deschamps, A. Singh, E. Chang (2003)
Metal–chelator polymers as reactive adsorbents for organophosphate hydrolysisReactive & Functional Polymers, 55
K. Ichikawa, Máté Tarnai, M. Uddin, K. Nakata, S. Sato (2002)
Hydrolysis of natural and artificial phosphoesters using zinc model compound with a histidine-containing pseudopeptide.Journal of inorganic biochemistry, 91 3
E. Hegg, J. Burstyn (1998)
Toward the development of metal-based synthetic nucleases and peptidases: a rationale and progress report in applying the principles of coordination chemistryCoordination Chemistry Reviews, 173
P. Scrimin, P. Tecilla, U. Tonellato, C. Bunton (1998)
Nucleophilic catalysis of hydrolyses of phosphate and carboxylate esters by metallomicelles: Facts and misconceptionsColloids and Surfaces A: Physicochemical and Engineering Aspects, 144
U. Baykal, M. Akkaya, E. Akkaya (1999)
Remarkable phosphodiester hydrolysis activity of a novel CeIV complex in neutral aqueous solutionsJournal of Molecular Catalysis A-chemical, 145
Gulnar Rawji, M. Yamada, N. Sadler, R. Milburn (2000)
Cobalt(III)-promoted hydrolysis of 4-nitrophenyl phosphate: the role of dinuclear speciesInorganica Chimica Acta, 303
Jiang Bing-ying, Zang Rong-rong, Xie Jia-qing, D. Juan, Meng Xiangguang, Zeng Xiancheng (2005)
Catalytic Hydrolyses of Carboxylic Acid Esters in the Presence of Gemini SurfactantJournal of Dispersion Science and Technology, 26
W. Cheng, Chihpin Huang, Y. Chien (2000)
Competitive Adsorption of Ferricyanide and Ferrocyanide on γ-Al2O3 Surface, 224
Meng Ying, Jiang Fubin, Hu Wei, Meng Xiangguang, Yu Xiaoqi, Zeng Xiancheng (2006)
Metallomicellar Catalysis: Phosphodiester Hydrolysis Catalyzed by Cu(II), Zn(II), Ni(II), and Co(II) Complexes of Chelating Pyridyl Donor Ligands in CTAB Micellar SolutionJournal of Dispersion Science and Technology, 27
J. You, Xiao‐Qi Yu, Xiao-yu Su, Tao Wang, Qing-xiang Xiang, Meng Yang, R. Xie (2003)
Hydrolytic metalloenzyme models enantioselective hydrolysis of long chain α-amino acid esters by chiral metallomicelles composed of lipophilic L-histidinolJournal of Molecular Catalysis A-chemical, 202
Xingyao Wei, Zhihua Mao, Jianzhang Li, Sheng-ying Qin (2004)
Synthesis of Salicylaldimine Schiff Bases with Benzo‐10‐aza‐15‐crown‐5 PendantSynthetic Communications, 34
Li Jian-zhang, Li Hong-bo, Feng Fa-mei, Xie Jia-qing, Li Shen-xin, Zhou Bo, Qin Sheng-ying (2005)
Hydrolysis of p-Nitrophenyl Picolinate Catalyzed by Mono- and Binuclear Transition Metal Complexes with Polyether Bridged Dihydroxamic AcidChinese Journal of Chemistry, 23
Kazuhiro Manseki, Osamu Nakamura, Kohei Horikawa, M. Sakamoto, H. Sakiyama, Y. Nishida, Y. Sadaoka, H. Ōkawa (2002)
Synthesis of copper(II)–lanthanum(III) complex of a dinucleating macrocycle and its hydrolytic property for 4-nitrophenylphosphateInorganic Chemistry Communications, 5
Zhisheng Zhang, Xiao-Mei Yu, L. Fong, Lawrence Margerum (2001)
Ligand effects on the phosphoesterase activity of Co(II) Schiff base complexes built on PAMAM dendrimersInorganica Chimica Acta, 317
F. Aka, M. Akkaya, E. Akkaya (2001)
Remarkable cooperative action of two zinc centers in the hydrolysis of plasmid DNAJournal of Molecular Catalysis A-chemical, 165
S. Negi, H. Schneider (2002)
Metal coordination and stacking effects in supramolecular catalysis. Effects of structural variations of copper complexes for the hydrolysis of phosphate estersTetrahedron Letters, 43
Jia‐qing Xie, Siqing Cheng, B. Jiang, J. Du, Changwei Hu, Xiancheng Zeng (2004)
Metallomicelles made of dinuclear copper(II) complexes of oxamido-bridge as symmetric two-center catalysts of the cleavage of carboxylic acid estersColloids and Surfaces A: Physicochemical and Engineering Aspects, 235
Siqing, Xiancheng, Xiangguang, Xiaoqi (2000)
Metallomicellar Catalysis Hydrolysis of p-Nitrophenyl Picolinate Catalyzed by Copper(II), Nickel(II), and Zinc(II) Complexes of Long Alkyl Pyridine Ligands in Micellar Solution.Journal of colloid and interface science, 224 2
Xiang Yan, Jiang Bing-ying, Zeng Xiancheng, Xie Jiaqing (2002)
Metallomicellar catalysis: catalytic cleavage of p-nitrophenyl picolinate by Cu2+ complex of 4-chloride-2,6-bis(N-hydroxyethylaminomethyl)-benzophenol in micellar solution.Journal of colloid and interface science, 247 2
B. Jiang, Yan Xiang, J. Du, Jia‐qing Xie, Changwei Hu, Xiancheng Zeng (2004)
Hydrolysis of p-nitrophenyl picolinate catalyzed by divalent metal ion complexes containing imidazole groups in micellar solutionColloids and Surfaces A: Physicochemical and Engineering Aspects, 235
J. You, Xiao‐Qi Yu, Ke-Chang Liu, Lin Tao, Qing-xiang Xiang, A. Xie (1999)
Synthesis of novel chiral lipophilic pyridyl-containing β-amino alcohol ligands and enantioselective hydrolysis of α-amino acid esters by chiral metallomicellesTetrahedron-asymmetry, 10
Two cobalt(II) complexes of the Schiff base with morpholino or aza‐crown ether pendants, CoL1 and CoL2, as mimic hydrolytic metalloenzyme, were used in catalytic hydrolysis of carboxylic ester (PNPP). The analysis of specific absorption spectra of the hydrolytic reaction systems indicates that key intermediates, made up of PNPP and Co(II) complexes, have been formed in reaction processes of the PNPP catalytic hydrolysis. The mechanism of PNPP catalytic hydrolysis has been proposed based on the analytic result of specific absorption spectrum. A kinetic mathematical model, applied to the calculation of the kinetic parameter of PNPP catalytic hydrolysis, has been established based on the mechanism proposed. The acid effect of buffer solution, structural effect of the complexes, and effect of temperature on the rate of PNPP hydrolysis catalyzed by the complexes have been also discussed.
Chinese Journal of Chemistry – Wiley
Published: Nov 1, 2006
Keywords: ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.