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Treatment of bis(N,N‐dimethylcar‐ bamoylseleno)methanes with SnCl4 afforded β‐1,3,5‐triselenanes in moderate to high yields, and the key intermediates of the reactions, i.e., acylselonium ions and selenoaldehydes, were successfully trapped by using allyltrimethylsilane or 2,3‐dimethyl‐1,3‐butadiene to obtain the allylation products or the cycloadducts, respectively. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:125–135, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20190
Heteroatom Chemistry – Wiley
Published: Jan 1, 2006
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