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Angew. Chem. Int. Ed. DOI: 10.1002/anie.201301881 Light-Emitting Diodes E. Pusztai, S. Jang, I. S. Toulokhonova, I. A. Guzei, R. West,* R. Hu, B. Z. Tang Synthesis of Highly Fluorescent Diquinaldinatoalumino Silole Derivatives Two-in-one fluorescent compounds: Blending the strong emitter, diquinaldinato aluminum, and the good electron transporter, tetraphenyl silole, resulted in highly fluorescent compounds that are promising candidates for light-emitting devices without the need of dopants (see figure). Chem. Eur. J. DOI: 10.1002/chem.201300728 Heterometallic Complexes Y.-L. Qin, R.-X. Yao, G.-X. Wu, M.-M. Liu, X.-M. Zhang* Heterometallic Mixed-Valence CopperACHTUNGRE(I,II) Cyanides that were Tuned by Using the Chelate Effect: Discovery of Famous Cairo Pentagonal Tiling and Unprecedented (3,4)-Connected {83}2{86} Topological 3D Net Back of the net: Three heterometallic cyano-bridged mixed-valence CuI/CuII coordination networks show Macmahon-type (5,34) 2D Cairo tiling sheets or a two-fold-interpenetrated (3,4)-connected {83}2{86} 3D topological framework. Their structural difference is due to water molecules on the octahedrally coordinated CuII atom, which are gradually replaced by 1,2-propane diamine chelate groups. Chem. Asian J. DOI: 10.1002/asia.201300143 Vitamins R. S. Dassanayake, D. E. Cabelli,* N. E. Brasch* Pulse Radiolysis Studies on the Reaction of the Reduced Vitamin B12 Complex Cob(II)alamin with Superoxide O2CÃ scavenger: The rate constant for the rapid reaction of
ChemPlusChem – Wiley
Published: Jul 1, 2013
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