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Spotlights on our sister journals: ChemPlusChem 12/2015

Spotlights on our sister journals: ChemPlusChem 12/2015 S SP PO OTTLLIIG GH HTTS S ...... On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Spin-Forbidden Reactions E. S. Akturk, G. P. A. Yap, K. H. Theopold* Dioxygen Activation by Non-Adiabatic OxidativeAddition to a Single MetalCenter Forbidden or allowed? The four-electron oxidative addition of O to TpCr complexes (Tp= tris(pyrazolyl)borate) is spin-forbidden, and yet, it proceeds by anon-adiabatic crossingfrom aquartet to adou- blet potential energy surfaceatthe minimum-energy crossing point, the structure of whichisshown. Angew.Chem. Int. Ed. DOI: 10.1002/anie.201508777 Electron Transfer S. Fukuzumi,* K. Ohkubo, Y.-M. Lee, W. Nam* Lewis Acid-Coupled Electron Transfer of Metal–Oxygen Intermediates Redox-active metal–oxygen species,such as metal–oxo and metal–peroxo complexes, act as key intermediates for the catalytic reduction of dioxygenand the oxidation of water and organic sub- strates. Redox-inactive metal ions and Brønsted acids that function as Lewisacids play pivotalroles in modulating the redox reactivity Chem. Eur.J. of these metal–oxygen intermediates. DOI: 10.1002/chem.201502693 C¢HActivation L.-Y.Jiao, A. V. Ferreira, M. Oestreich* Phosphinic Amide http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

Spotlights on our sister journals: ChemPlusChem 12/2015

ChemPlusChem , Volume 80 (12) – Dec 1, 2015

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Publisher
Wiley
Copyright
© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201581213
Publisher site
See Article on Publisher Site

Abstract

S SP PO OTTLLIIG GH HTTS S ...... On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Spin-Forbidden Reactions E. S. Akturk, G. P. A. Yap, K. H. Theopold* Dioxygen Activation by Non-Adiabatic OxidativeAddition to a Single MetalCenter Forbidden or allowed? The four-electron oxidative addition of O to TpCr complexes (Tp= tris(pyrazolyl)borate) is spin-forbidden, and yet, it proceeds by anon-adiabatic crossingfrom aquartet to adou- blet potential energy surfaceatthe minimum-energy crossing point, the structure of whichisshown. Angew.Chem. Int. Ed. DOI: 10.1002/anie.201508777 Electron Transfer S. Fukuzumi,* K. Ohkubo, Y.-M. Lee, W. Nam* Lewis Acid-Coupled Electron Transfer of Metal–Oxygen Intermediates Redox-active metal–oxygen species,such as metal–oxo and metal–peroxo complexes, act as key intermediates for the catalytic reduction of dioxygenand the oxidation of water and organic sub- strates. Redox-inactive metal ions and Brønsted acids that function as Lewisacids play pivotalroles in modulating the redox reactivity Chem. Eur.J. of these metal–oxygen intermediates. DOI: 10.1002/chem.201502693 C¢HActivation L.-Y.Jiao, A. V. Ferreira, M. Oestreich* Phosphinic Amide

Journal

ChemPlusChemWiley

Published: Dec 1, 2015

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