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Solid‐State Solar Thermal Fuels for Heat Release Applications

Solid‐State Solar Thermal Fuels for Heat Release Applications Closed cycle systems offer an opportunity for solar energy harvesting and storage all within the same material. Photon energy is stored within the chemical conformations of molecules and is retrieved by a triggered release in the form of heat. Until now, such solar thermal fuels (STFs) have been largely unavailable in the solid‐state, which would enable them to be utilized for a multitude of applications. A polymer STF storage platform is synthesized employing STFs in the solid‐state. This approach enables uniform films capable of appreciable heat storage of up to 30 Wh kg−1 and that can withstand temperature of up to 180 °C. For the first time a macroscopic energy release is demonstrated using spatial infrared heat maps with up to a 10 °C temperature change. These findings pave the way for developing highly efficient and high energy density STFs for applications in the solid‐state. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advanced Energy Materials Wiley

Solid‐State Solar Thermal Fuels for Heat Release Applications

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References (52)

Publisher
Wiley
Copyright
Copyright © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1614-6832
eISSN
1614-6840
DOI
10.1002/aenm.201502006
Publisher site
See Article on Publisher Site

Abstract

Closed cycle systems offer an opportunity for solar energy harvesting and storage all within the same material. Photon energy is stored within the chemical conformations of molecules and is retrieved by a triggered release in the form of heat. Until now, such solar thermal fuels (STFs) have been largely unavailable in the solid‐state, which would enable them to be utilized for a multitude of applications. A polymer STF storage platform is synthesized employing STFs in the solid‐state. This approach enables uniform films capable of appreciable heat storage of up to 30 Wh kg−1 and that can withstand temperature of up to 180 °C. For the first time a macroscopic energy release is demonstrated using spatial infrared heat maps with up to a 10 °C temperature change. These findings pave the way for developing highly efficient and high energy density STFs for applications in the solid‐state.

Journal

Advanced Energy MaterialsWiley

Published: Mar 1, 2016

Keywords: ; ; ; ;

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