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Self‐assembly syntheses and crystal structures of dimeric di‐ n ‐butyltin phosphates containing eight‐membered Sn 2 O 4 P 2 inorganic ring

Self‐assembly syntheses and crystal structures of dimeric di‐ n ‐butyltin phosphates containing... Two organotin (IV) derivatives, (Bu2‐ Sn(HO3PO‐i‐Pr)2)2 (1) and (Bu2Sn(HO3POPh)2)2 (2), have been prepared by reactions of di‐n‐butyltin oxide with the phenylphosphoric acid and isopropylphosphoric acid, respectively. Characterization of the complexes 1 and 2 was achieved using elemental analysis, IR, NMR (1H, 13C, 31P, and 119Sn) spectroscopy, and X‐ray crystallography diffraction analysis. The X‐ray data reveal that complexes 1 and 2 are dimers containing eight‐membered Sn2O4P2 inorganic ring. Interestingly, complexes 1 and 2 are further linked into 2D network through intermolecular O … Sn weak contacts and OH … O weak hydrogen‐bonding interactions. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:298–303, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20610 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Self‐assembly syntheses and crystal structures of dimeric di‐ n ‐butyltin phosphates containing eight‐membered Sn 2 O 4 P 2 inorganic ring

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References (22)

Publisher
Wiley
Copyright
Copyright © 2010 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.20610
Publisher site
See Article on Publisher Site

Abstract

Two organotin (IV) derivatives, (Bu2‐ Sn(HO3PO‐i‐Pr)2)2 (1) and (Bu2Sn(HO3POPh)2)2 (2), have been prepared by reactions of di‐n‐butyltin oxide with the phenylphosphoric acid and isopropylphosphoric acid, respectively. Characterization of the complexes 1 and 2 was achieved using elemental analysis, IR, NMR (1H, 13C, 31P, and 119Sn) spectroscopy, and X‐ray crystallography diffraction analysis. The X‐ray data reveal that complexes 1 and 2 are dimers containing eight‐membered Sn2O4P2 inorganic ring. Interestingly, complexes 1 and 2 are further linked into 2D network through intermolecular O … Sn weak contacts and OH … O weak hydrogen‐bonding interactions. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:298–303, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20610

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2010

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