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Reactions of iPr2NCP with methylating agents: Formation of the diamino‐2‐phosphaallylic cation ⊕

Reactions of iPr2NCP with methylating agents: Formation of the diamino‐2‐phosphaallylic cation ⊕ The reaction of di(isopropyl)aminophosphaethyne 1 with iodomethane or the methyl ester of trifluormethylsulfonic acid (methyl triflate) yields the ionic 1λ3, 3λ3‐diphosphetene derivatives + X− (2a: X = I; 2b: X = CF3SO3). On the basis of NMR spectroscopic and X‐ray diffraction studies, the cation can be described as a combination of an amino‐2‐phosphaallylic cation and its methylated derivative. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Reactions of iPr2NCP with methylating agents: Formation of the diamino‐2‐phosphaallylic cation ⊕

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References (18)

Publisher
Wiley
Copyright
Copyright © 1994 Wiley Subscription Services
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.520050404
Publisher site
See Article on Publisher Site

Abstract

The reaction of di(isopropyl)aminophosphaethyne 1 with iodomethane or the methyl ester of trifluormethylsulfonic acid (methyl triflate) yields the ionic 1λ3, 3λ3‐diphosphetene derivatives + X− (2a: X = I; 2b: X = CF3SO3). On the basis of NMR spectroscopic and X‐ray diffraction studies, the cation can be described as a combination of an amino‐2‐phosphaallylic cation and its methylated derivative.

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1994

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