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Pyrite Surface after Thiobacillus ferrooxidans Leaching at 30°C

Pyrite Surface after Thiobacillus ferrooxidans Leaching at 30°C Abstract In order to investigate the effect of Thiobacillus ferrooxidans on the oxidation of pyrite, two parallel experiments, which employed H2SO4 solutions and acidic solutions inoculated with Thiobacillus ferrooxidans, were designed and carried out at 30°C. The initial pH of the two solutions was adjusted to 2.5 by dropwise addition of concentrated sulphuric acid. The surfaces of pyrite before exposure to leaching solutions and after exposure to the H2SO4 solutions and acidic solutions inoculated with Thiobacillus ferrooxidans were observed by scanning electron microscopy (SEM). There were a variety of erosion patterns by Thiobacillus ferrooxidans on the bio‐leached pyrite surfaces. A conclusion can be drawn that the oxidation of pyrite might have been caused by erosion of the surfaces. Attachment of the bacteria to pyrite surfaces resulted in erosion pits, leading to the oxidation of pyrite. It is possible that the direct mechanism plays the most important role in the oxidation of pyrite. The changes in iron ion concentrations of both the experimental solutions with time suggest that Thiobacillus ferrooxidans can enhance greatly the oxidation of pyrite. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Geologica Sinica (English Edition) Wiley

Pyrite Surface after Thiobacillus ferrooxidans Leaching at 30°C

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References (41)

Publisher
Wiley
Copyright
2006 Geological Society of China
ISSN
1000-9515
eISSN
1755-6724
DOI
10.1111/j.1755-6724.2006.tb00262.x
Publisher site
See Article on Publisher Site

Abstract

Abstract In order to investigate the effect of Thiobacillus ferrooxidans on the oxidation of pyrite, two parallel experiments, which employed H2SO4 solutions and acidic solutions inoculated with Thiobacillus ferrooxidans, were designed and carried out at 30°C. The initial pH of the two solutions was adjusted to 2.5 by dropwise addition of concentrated sulphuric acid. The surfaces of pyrite before exposure to leaching solutions and after exposure to the H2SO4 solutions and acidic solutions inoculated with Thiobacillus ferrooxidans were observed by scanning electron microscopy (SEM). There were a variety of erosion patterns by Thiobacillus ferrooxidans on the bio‐leached pyrite surfaces. A conclusion can be drawn that the oxidation of pyrite might have been caused by erosion of the surfaces. Attachment of the bacteria to pyrite surfaces resulted in erosion pits, leading to the oxidation of pyrite. It is possible that the direct mechanism plays the most important role in the oxidation of pyrite. The changes in iron ion concentrations of both the experimental solutions with time suggest that Thiobacillus ferrooxidans can enhance greatly the oxidation of pyrite.

Journal

Acta Geologica Sinica (English Edition)Wiley

Published: Jun 1, 2006

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