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Physical modification of carbon nanotubes with a dendrimer bearing terminal mercaptoundecahydrododecaborates (Na2B12H11S)

Physical modification of carbon nanotubes with a dendrimer bearing terminal... The thiol‐substituted B12‐cluster mercaptoundecahydro‐closo‐dodecaborate Na2[B12H11SH] (BSH) was successfully attached to a poly(amido)amine (PAMAM) dendrimer, which contains a bis(decyloxy)decane core. The physical modification of single‐walled carbon nanotubes (SWCNTs) with dendrimer(SB12)4 afforded a SWCNT/dendrimer(SB12)4 nanohybrid that exhibited NIR‐I‐to‐NIR‐II fluorescence. Herein, we describe a promising strategy for in vivo imaging of boron clusters that may be widely applicable to boron neutron capture therapy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Physical modification of carbon nanotubes with a dendrimer bearing terminal mercaptoundecahydrododecaborates (Na2B12H11S)

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Publisher
Wiley
Copyright
"Copyright © 2018 Wiley Periodicals, Inc."
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.21467
Publisher site
See Article on Publisher Site

Abstract

The thiol‐substituted B12‐cluster mercaptoundecahydro‐closo‐dodecaborate Na2[B12H11SH] (BSH) was successfully attached to a poly(amido)amine (PAMAM) dendrimer, which contains a bis(decyloxy)decane core. The physical modification of single‐walled carbon nanotubes (SWCNTs) with dendrimer(SB12)4 afforded a SWCNT/dendrimer(SB12)4 nanohybrid that exhibited NIR‐I‐to‐NIR‐II fluorescence. Herein, we describe a promising strategy for in vivo imaging of boron clusters that may be widely applicable to boron neutron capture therapy.

Journal

Heteroatom ChemistryWiley

Published: Dec 1, 2018

Keywords: ; ; ;

References