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R. Rauh, K. Abraham, G. Pearson, J. Surprenant, S. Brummer (1979)
A Lithium/Dissolved Sulfur Battery with an Organic ElectrolyteJournal of The Electrochemical Society, 126
Xiulei Ji, Kyu Lee, L. Nazar (2009)
A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries.Nature materials, 8 6
Z. Zhao‐Karger, J. Mueller, Xiangyu Zhao, O. Fuhr, T. Jacob, M. Fichtner (2014)
Novel transmetalation reaction for electrolyte synthesis for rechargeable magnesium batteriesRSC Advances, 4
Z. Zhao‐Karger, Xiangyu Zhao, O. Fuhr, M. Fichtner (2013)
Bisamide based non-nucleophilic electrolytes for rechargeable magnesium batteriesRSC Advances, 3
Yan Diao, Kai Xie, Shizhao Xiong, Xiaobin Hong (2013)
Shuttle phenomenon – The irreversible oxidation mechanism of sulfur active material in Li–S batteryJournal of Power Sources, 235
C. Barchasz, J. Leprêtre, S. Patoux, F. Alloin (2013)
Electrochemical properties of ether-based electrolytes for lithium/sulfur rechargeable batteriesElectrochimica Acta, 89
S. Kim, Yongju Jung, H. Lim (2004)
The effect of solvent component on the discharge performance of Lithium–sulfur cell containing various organic electrolytesElectrochimica Acta, 50
R. Rauh, F. Shuker, J. Marston, S. Brummer (1977)
Formation of lithium polysulfides in aprotic mediaJournal of Inorganic and Nuclear Chemistry, 39
Xiangyu Zhao, Z. Zhao‐Karger, Di Wang, M. Fichtner (2013)
Metal oxychlorides as cathode materials for chloride ion batteries.Angewandte Chemie, 52 51
W. Seidel (1985)
Synthese von Mesitylaluminium‐VerbindungenZeitschrift für anorganische und allgemeine Chemie, 524
Yuriy Mikhaylik, J. Akridge (2004)
Polysulfide Shuttle Study in the Li/S Battery SystemJournal of The Electrochemical Society, 151
Wei-kun Wang, You Wang, Yaqin Huang, Chongjun Huang, Zhongbao Yu, Hao Zhang, An-bang Wang, Keguo Yuan (2010)
The electrochemical performance of lithium–sulfur batteries with LiClO4 DOL/DME electrolyteJournal of Applied Electrochemistry, 40
Sen Xin, L. Gu, N. Zhao, Ya‐Xia Yin, Longjie Zhou, Yu‐Guo Guo, L. Wan (2012)
Smaller sulfur molecules promise better lithium-sulfur batteries.Journal of the American Chemical Society, 134 45
H. Yamin, A. Gorenshtein, J. Penciner, Y. Sternberg, E. Peled (1988)
Lithium Sulfur Battery Oxidation/Reduction Mechanisms of Polysulfides in THF SolutionsJournal of The Electrochemical Society, 135
Jayaprakash Navaneedhakrishnan, Jingguo Shen, Surya Moganty, Alex Corona, L. Archer (2011)
Porous hollow carbon@sulfur composites for high-power lithium-sulfur batteries.Angewandte Chemie, 50 26
A. Kamyshny, J. Gun, D. Rizkov, T. Voitsekovski, O. Lev (2007)
Equilibrium distribution of polysulfide ions in aqueous solutions at different temperatures by rapid single phase derivatization.Environmental science & technology, 41 7
K. Fujita, N. Nakamura, K. Igarashi, M. Samejima, H. Ohno (2009)
Biocatalytic oxidation of cellobiose in an hydrated ionic liquidGreen Chemistry, 11
Jae-Won Choi, G. Cheruvally, Dul-Sun Kim, Jou‐Hyeon Ahn, Ki-won Kim, H. Ahn (2008)
Rechargeable lithium/sulfur battery with liquid electrolytes containing toluene as additiveJournal of Power Sources, 183
N. Manan, L. Aldous, Y. Alias, P. Murray, L. Yellowlees, M. Lagunas, C. Hardacre (2011)
Electrochemistry of sulfur and polysulfides in ionic liquids.The journal of physical chemistry. B, 115 47
P. Bruce, S. Freunberger, L. Hardwick, J. Tarascon (2011)
Li-O2 and Li-S batteries with high energy storage.Nature materials, 11 1
M. Lacey, F. Jeschull, K. Edström, D. Brandell (2013)
Why PEO as a binder or polymer coating increases capacity in the Li-S system.Chemical communications, 49 76
Jae-Won Choi, Jin Kim, G. Cheruvally, Jou‐Hyeon Ahn, H. Ahn, Ki-won Kim (2007)
Rechargeable lithium/sulfur battery with suitable mixed liquid electrolytesElectrochimica Acta, 52
Natalia Cañas, D. Fronczek, N. Wagner, A. Latz, K., A. Friedrich (2014)
Experimental and Theoretical Analysis of Products and Reaction Intermediates of Lithium−Sulfur BatteriesJournal of Physical Chemistry C, 118
J. Shim, K. Striebel, E. Cairns (2002)
The Lithium/Sulfur Rechargeable Cell Effects of Electrode Composition and Solvent on Cell PerformanceJournal of The Electrochemical Society, 149
E. Peled, Y. Sternberg, A. Gorenshtein, Y. Lavi (1989)
Lithium‐Sulfur Battery: Evaluation of Dioxolane‐Based ElectrolytesJournal of The Electrochemical Society, 136
T. Gregory, R. Hoffman, R. Winterton (1990)
Nonaqueous Electrochemistry of Magnesium Applications to Energy StorageJournal of The Electrochemical Society, 137
D. Aurbach, Y. Cohen, M. Moshkovich (2001)
The Study of Reversible Magnesium Deposition by In Situ Scanning Tunneling MicroscopyElectrochemical and Solid State Letters, 4
M. Armand, J. Tarascon (2008)
Building better batteriesNature, 451
P. Saha, M. Datta, O. Velikokhatnyi, A. Manivannan, D. Alman, P. Kumta (2014)
Rechargeable Magnesium Battery: Current Status and Key Challenges for the FutureChemInform, 46
Naoki Tachikawa, Kento Yamauchi, E. Takashima, Jun-Woo Park, Kaoru Dokko, M. Watanabe (2011)
Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme-Li salt molten complex electrolytes.Chemical communications, 47 28
Owen Crowther, A. West (2008)
Effect of Electrolyte Composition on Lithium Dendrite GrowthJournal of The Electrochemical Society, 155
Z. Lu, A. Schechter, M. Moshkovich, D. Aurbach (1999)
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutionsJournal of Electroanalytical Chemistry, 466
C. Barchasz, J. Leprêtre, S. Patoux, F. Alloin (2013)
Revisiting TEGDME/DIOX Binary Electrolytes for Lithium/Sulfur Batteries: Importance of Solvation Ability and AdditivesJournal of The Electrochemical Society, 160
J. Tarascon, M. Armand (2001)
Issues and challenges facing rechargeable lithium batteriesNature, 414
D. Aurbach, Ran Elazari, Elad Pollak, G. Salitra, Chariclea Kelley, J. Affinito (2009)
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur BatteriesJournal of The Electrochemical Society, 156
Matthias Schmeisser, P. Illner, R. Puchta, A. Zahl, R. Eldik (2012)
Gutmann donor and acceptor numbers for ionic liquids.Chemistry, 18 35
S. Moon, Y. Jung, W. Jung, Dae Jung, J. Choi, Do Kim (2013)
Encapsulated Monoclinic Sulfur for Stable Cycling of Li–S Rechargeable BatteriesAdvanced Materials, 25
C. Barchasz, J. Leprêtre, F. Alloin, S. Patoux (2012)
New insights into the limiting parameters of the Li/S rechargeable cellJournal of Power Sources, 199
Xiangyu Zhao, S. Ren, M. Bruns, M. Fichtner (2014)
Chloride ion battery: A new member in the rechargeable battery familyJournal of Power Sources, 245
Lina Wang, H. Byon (2013)
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide-based organic electrolyte for high performance lithium–sulfur batteriesJournal of Power Sources, 236
J. Muldoon, Claudiu Bucur, A. Oliver, Tsuyoshi Sugimoto, M. Matsui, H. Kim, G. Allred, J. Zajicek, Yukinari Kotani (2012)
Electrolyte roadblocks to a magnesium rechargeable batteryEnergy and Environmental Science, 5
T. Kakibe, Jun-ya Hishii, N. Yoshimoto, M. Egashira, M. Morita (2012)
Binary ionic liquid electrolytes containing organo-magnesium complex for rechargeable magnesium batteriesJournal of Power Sources, 203
O. Mizrahi, N. Amir, Elad Pollak, O. Chusid, V. Marks, H. Gottlieb, Liraz Larush, E. Zinigrad, D. Aurbach (2008)
Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium BatteriesJournal of The Electrochemical Society, 155
G. Cheek, W. O'grady, S. Abedin, E. Moustafa, F. Endres (2008)
Studies on the Electrodeposition of Magnesium in Ionic LiquidsJournal of The Electrochemical Society, 155
Chenxi Zu, Hong Li (2011)
Thermodynamic analysis on energy densities of batteriesEnergy and Environmental Science, 4
D. Aurbach, Z. Lu, A. Schechter, Y. Gofer, Haim Gizbar, R. Turgeman, Y. Cohen, M. Moshkovich, E. Levi (2000)
Prototype systems for rechargeable magnesium batteriesNature, 407
H. Yoo, I. Shterenberg, Y. Gofer, Gregory Gershinsky, N. Pour, D. Aurbach (2013)
Mg rechargeable batteries: an on-going challengeEnergy and Environmental Science, 6
R. Steudel (2003)
Inorganic Polysulfanes H 2 S n with n > 1ChemInform, 35
R. Mohtadi, M. Matsui, T. Arthur, Son-Jong Hwang (2012)
Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery**Angewandte Chemie (International Ed. in English), 51
L. Lossius, F. Emmenegger (1996)
Plating of magnesium from organic solventsElectrochimica Acta, 41
M. Le, F. Alloin, P. Strobel, J. Leprêtre, L. Cointeaux, C. Valle (2012)
Electrolyte based on fluorinated cyclic quaternary ammonium ionic liquidsIonics, 18
Ye Zhang, Shuangxi Liu, Guochun Li, G. Li, X. Gao (2014)
Sulfur/polyacrylonitrile/carbon multi-composites as cathode materials for lithium/sulfur battery in the concentrated electrolyteJournal of Materials Chemistry, 2
N. Yoshimoto, Mami Matsumoto, Minato Egashia, M. Morita (2010)
Mixed electrolyte consisting of ethylmagnesiumbromide with ionic liquid for rechargeable magnesium electrodeJournal of Power Sources, 195
H. Kim, T. Arthur, G. Allred, J. Zajicek, J. Newman, A. Rodnyansky, A. Oliver, W. Boggess, J. Muldoon (2011)
Structure and compatibility of a magnesium electrolyte with a sulphur cathodeNature Communications, 2
J. Wilkes, M. Zaworotko (1992)
Air and water stable 1-ethyl-3-methylimidazolium based ionic liquidsJournal of The Chemical Society, Chemical Communications
The combination of a magnesium anode with a sulfur cathode is one of the most promising electrochemical couples because of its advantages of good safety, low cost, and a high theoretical energy density. However, magnesium sulfur batteries are still in a very early stage of research and development, and the discovery of suitable electrolytes is the key challenge for further improvement. Here, a new preparation method for non‐nucleophilic electrolyte solutions using a two‐step reaction in one‐pot is presented, which provides a feasible way to optimize the physiochemical properties of the electrolyte for the application in magnesium sulfur batteries. The first use of modified electrolytes in glymes and binary solvents of glyme and ionic liquid shows beneficial effects on the performance of magnesium sulfur batteries. New insights into the reaction mechanism of electrochemical conversion between magnesium and sulfur are also investigated.
Advanced Energy Materials – Wiley
Published: Feb 1, 2015
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