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Palladium−Hydride‐Catalyzed Regiodivergent Isomerization of 1‐Alkenes

Palladium−Hydride‐Catalyzed Regiodivergent Isomerization of 1‐Alkenes New stable palladium−hydride complexes catalyze the highly regio‐ and stereoselective isomerization of 1‐alkenes at multiple positions. Tuning the ligand and the reaction conditions allowed the position and geometry of the double bonds to be controlled with excellent conversions and selectivities. The catalytic species, a Pd−H complex, was prepared by reacting [LPdCl2] with a silver salt, followed by conversion into Pd−H by using a silyl hydride. The structures of the Pd complexes were determined by using X‐ray crystallography and NMR spectroscopy. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Palladium−Hydride‐Catalyzed Regiodivergent Isomerization of 1‐Alkenes

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References (67)

Publisher
Wiley
Copyright
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201600536
Publisher site
See Article on Publisher Site

Abstract

New stable palladium−hydride complexes catalyze the highly regio‐ and stereoselective isomerization of 1‐alkenes at multiple positions. Tuning the ligand and the reaction conditions allowed the position and geometry of the double bonds to be controlled with excellent conversions and selectivities. The catalytic species, a Pd−H complex, was prepared by reacting [LPdCl2] with a silver salt, followed by conversion into Pd−H by using a silyl hydride. The structures of the Pd complexes were determined by using X‐ray crystallography and NMR spectroscopy.

Journal

Asian Journal of Organic ChemistryWiley

Published: Mar 1, 2017

Keywords: ; ; ; ;

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