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A new, general palladium‐catalyzed oxidative strategy for the cleavage of the C≡C triple bond is presented. By employing PdCl2, CuBr2, TEMPO and air as the catalytic system and H2O as the carbonyl oxygen atom source, a wide range of 2‐alkynyl carbonyl compounds, including 1,3‐disubstituted prop‐2‐yn‐1‐ones, propiolamides and propiolates, lost an alkynyl carbon to access various 1,2‐dicarbonyl compounds, e.g., 1,2‐diones, 2‐keto amides and 2‐keto esters, through Wacker oxidation, intramolecular cyclization and C—C bond cleavage cascades.
Chinese Journal of Chemistry – Wiley
Published: Jun 1, 2020
Keywords: ; ; ; ;
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