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Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes

Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes 1 and 2 with MeSiCl2H has been investigated. Both steric effects and the presence of an aryl substituent affect the regiochemistry of the hydrosilylation reaction. Hydrosilylation of siloxanetethered bis‐dienes 9 exhibits high regio‐ and diastereoselectivity. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes

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References (10)

Publisher
Wiley
Copyright
Copyright © 1995 Wiley Subscription Services
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.520060106
Publisher site
See Article on Publisher Site

Abstract

Palladium‐catalyzed hydrosilylation of silyl‐substituted butadienes 1 and 2 with MeSiCl2H has been investigated. Both steric effects and the presence of an aryl substituent affect the regiochemistry of the hydrosilylation reaction. Hydrosilylation of siloxanetethered bis‐dienes 9 exhibits high regio‐ and diastereoselectivity.

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1995

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