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A series of 2‐aryl‐1‐(phenylsulfonyl)‐1H‐pyrrolo[2,3‐b]pyridines 3 were obtained by a palladium‐catalyzed decarboxylative Suzuki coupling of azaindole‐2‐carboxylic acid derivative 1. The synthesis of alkenyl‐1‐(phenylsulfonyl)‐1H‐pyrrolo[2,3‐b]pyridines 9 by a related Heck coupling is also described. Protodecarboxylation operates in the case of azaindole‐3‐carboxylic acids under the reaction conditions.
Asian Journal of Organic Chemistry – Wiley
Published: Feb 1, 2013
Keywords: ; ; ; ;
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