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Palladium‐Catalyzed Cross‐Coupling of Arylboronic Acid and Benzonitriles Using DMSO as the Methylene Source

Palladium‐Catalyzed Cross‐Coupling of Arylboronic Acid and Benzonitriles Using DMSO as the... An interesting strategy on palladium‐catalyzed cross‐coupling of arylboronic acids and benzonitriles has been developed. In this approach, DMSO was utilized as the methylene source and reacted with benzamides (generated in situ from benzonitriles) to form an N‐acyliminium cation, followed by palladium‐catalyzed cross‐coupling with phenylboronic acids to afford the final products. A variety of the desired products were obtained in moderate to excellent yield. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Palladium‐Catalyzed Cross‐Coupling of Arylboronic Acid and Benzonitriles Using DMSO as the Methylene Source

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References (42)

Publisher
Wiley
Copyright
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201800502
Publisher site
See Article on Publisher Site

Abstract

An interesting strategy on palladium‐catalyzed cross‐coupling of arylboronic acids and benzonitriles has been developed. In this approach, DMSO was utilized as the methylene source and reacted with benzamides (generated in situ from benzonitriles) to form an N‐acyliminium cation, followed by palladium‐catalyzed cross‐coupling with phenylboronic acids to afford the final products. A variety of the desired products were obtained in moderate to excellent yield.

Journal

Asian Journal of Organic ChemistryWiley

Published: Oct 1, 2018

Keywords: ; ; ; ;

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