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An interesting strategy on palladium‐catalyzed cross‐coupling of arylboronic acids and benzonitriles has been developed. In this approach, DMSO was utilized as the methylene source and reacted with benzamides (generated in situ from benzonitriles) to form an N‐acyliminium cation, followed by palladium‐catalyzed cross‐coupling with phenylboronic acids to afford the final products. A variety of the desired products were obtained in moderate to excellent yield.
Asian Journal of Organic Chemistry – Wiley
Published: Oct 1, 2018
Keywords: ; ; ; ;
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