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K. Majumdar, S. Chattopadhyay (2011)
Heterocycles in Natural Product Synthesis: MAJUMDAR:HETEROCYCLES O-BK
A Pd‐catalyzed asymmetric aromative [4+3]‐cyclization reaction of amino‐trimethylenemethanes (TMM, 1,3‐dipoles) with fused 1‐azadienes has been developed. This method enables access to the synthetically importance and biologically active benzofuran fused azepines and indeno‐azepines in excellent efficiency and stereoselectivity (up to 95% yield, 99% ee, >19 : 1 dr).
Chinese Journal of Chemistry – Wiley
Published: Feb 1, 2020
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