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Suhaib Ilyas, Rajashekhar Pendyala, N. Marneni (2014)
Preparation, Sedimentation, and Agglomeration of NanofluidsChemical Engineering & Technology, 37
Pengcheng Shi, Linchao Zhang, H. Xiang, Xin Liang, Yi Sun, Wu Xu (2018)
Lithium Difluorophosphate as a Dendrite-Suppressing Additive for Lithium Metal Batteries.ACS applied materials & interfaces, 10 26
Dongdong Wang, Haodong Liu, Mingqian Li, D. Xia, John Holoubek, Z. Deng, Mingyu Yu, Jianhua Tian, Zhongqiang Shan, S. Ong, Ping Liu, Zhengyu Chen (2020)
A long-lasting dual-function electrolyte additive for stable lithium metal batteriesNano Energy, 75
Qianqian Liu, Zerui Chen, Yan Liu, Youran Hong, Weina Wang, Jianghao Wang, Bo Zhao, Yifei Xu, Jiangwei Wang, Xiulin Fan, Linsen Li, Haodong Wu (2021)
Cooperative stabilization of bi-electrodes with robust interphases for high-voltage lithium-metal batteriesEnergy Storage Materials, 37
Lifen Xiao, Ziqi Zeng, Xingwei Liu, Yongjin Fang, Xiaoyu Jiang, Yuyan Shao, Zhuang Lin, X. Ai, Hanxi Yang, Yuliang Cao, Jun Liu (2019)
Stable Li Metal Anode with “Ion–Solvent-Coordinated” Nonflammable Electrolyte for Safe Li Metal BatteriesACS Energy Letters
Chuntian Cao, T. Pollard, O. Borodin, Julian Mars, Yuchi Tsao, M. Lukatskaya, Robert Kasse, M. Schroeder, Kang Xu, M. Toney, Hans‐Georg Steinrück (2021)
Toward Unraveling the Origin of Lithium Fluoride in the Solid Electrolyte InterphaseChemistry of Materials
K. Yan, Jiangyan Wang, Shuoqing Zhao, D. Zhou, Bing Sun, Yi Cui, Guoxiu Wang (2019)
Temperature-dependent Nucleation and Growth of Dendrite-free Lithium Metal Anodes.Angewandte Chemie
Tao Zhang, Huichao Lu, Jun Yang, Zhixin Xu, Jiulin Wang, S. Hirano, Yongsheng Guo, C. Liang (2020)
Stable Lithium Metal Anode Enabled by a Lithiophilic and Electron/Ion-Conductive Framework.ACS nano
A. Naveed, Huijun Yang, Yuyan Shao, Jun Yang, Nuli Yanna, Jun Liu, S. Shi, Liwen Zhang, Anjiang Ye, Bing He, Jiulin Wang (2019)
A Highly Reversible Zn Anode with Intrinsically Safe Organic Electrolyte for Long‐Cycle‐Life BatteriesAdvanced Materials, 31
Dahee Jin, Youngjoon Roh, Taejin Jo, Myung-Hyun Ryou, Hongkyung Lee, Y. Lee (2021)
Robust Cycling of Ultrathin Li Metal Enabled by Nitrate‐Preplanted Li Powder CompositeAdvanced Energy Materials, 11
Ji Chen, Qin Li, T. Pollard, Xiulin Fan, O. Borodin, Chunsheng Wang (2020)
Electrolyte design for Li metal-free Li batteriesMaterials Today
Zhuang Q.‐C. (2005)
1008Chinese battery ind, 10
Woo S.‐G. (2021)
1420Energy Environ. Sci., 14
B. Demri, D. Muster (1995)
XPS study of some calcium compoundsJournal of Materials Processing Technology, 55
Xiao Tang, D. Zhou, Bao-Hua Zhang, Shijian Wang, Peng Li, Hao Liu, Xin Guo, Pauline Jaumaux, Xiaochun Gao, Yongzhu Fu, Chengyin Wang, Chunsheng Wang, Guoxiu Wang (2021)
A universal strategy towards high–energy aqueous multivalent–ion batteriesNature Communications, 12
F. Ding, Wu Xu, G. Graff, Jian Zhang, M. Sushko, Xilin Chen, Yuyan Shao, M. Engelhard, Z. Nie, Jie Xiao, Xingjiang Liu, P. Sushko, Jun Liu, Ji‐Guang Zhang (2013)
Dendrite-free lithium deposition via self-healing electrostatic shield mechanism.Journal of the American Chemical Society, 135 11
Susanne Wilken, M. Treskow, J. Scheers, P. Johansson, P. Jacobsson (2013)
Initial stages of thermal decomposition of LiPF6-based lithium ion battery electrolytes by detailed Raman and NMR spectroscopyRSC Advances, 3
Ziqi Zeng, V. Murugesan, K. Han, Xiaoyu Jiang, Yuliang Cao, Lifen Xiao, X. Ai, Hanxi Yang, Ji‐Guang Zhang, M. Sushko, Jun Liu (2018)
Non-flammable electrolytes with high salt-to-solvent ratios for Li-ion and Li-metal batteriesNature Energy, 3
Dahee Jin, Jeonghun Oh, A. Friesen, Kyuman Kim, Taejin Jo, Y. Lee, Myung-Hyun Ryou (2018)
Self-Healing Wide and Thin Li Metal Anodes Prepared Using Calendared Li Metal Powder for Improving Cycle Life and Rate Capability.ACS applied materials & interfaces, 10 19
Kuan-Hung Chen, Adrian Sanchez, E. Kazyak, Andrew Davis, N. Dasgupta (2018)
Synergistic Effect of 3D Current Collectors and ALD Surface Modification for High Coulombic Efficiency Lithium Metal AnodesAdvanced Energy Materials, 9
Feilong Qiu, Xiang Li, Han Deng, Di Wang, Xiaowei Mu, P. He, Haoshen Zhou (2018)
A Concentrated Ternary‐Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess LiAdvanced Energy Materials, 9
H. Dai, Kai Xi, Xin Liu, Chao Lai, Shanqing Zhang (2018)
Cationic Surfactant-Based Electrolyte Additives for Uniform Lithium Deposition via Lithiophobic Repulsion Mechanisms.Journal of the American Chemical Society, 140 50
Zhang W. (2020)
2051041Funct. Mater. Lett., 13
Hyeon-Su Bae, I. Phiri, H. Kang, Y. Lee, Myung-Hyun Ryou (2021)
Large-area surface-patterned Li metal anodes fabricated using large, flexible patterning stamps for Li metal secondary batteriesJournal of Power Sources
Feilong Qiu, Siyun Ren, Xueping Zhang, P. He, Haoshen Zhou (2021)
A high efficiency electrolyte enables robust inorganic-organic solid electrolyte interfaces for fast Li metal anode.Science bulletin, 66 9
Kwon B. (2021)
24993J. Mater. Chem. A, 9
Hewei Xu, Ying He, Zibo Zhang, Junli Shi, Pingying Liu, Ziqi Tian, Kan Luo, Xiaozhe Zhang, Suzhe Liang, Zhaoping Liu (2020)
Slurry-like hybrid electrolyte with high lithium-ion transference number for dendrite-free lithium metal anodeJournal of Energy Chemistry
Christopher Campion, Wentao Li, B. Lucht (2005)
Thermal Decomposition of LiPF6-Based Electrolytes for Lithium-Ion BatteriesJournal of The Electrochemical Society, 152
Yufan Zhou, Mao-Feng Su, Xiaofei Yu, Yanyan Zhang, Jungang Wang, Xiaodi Ren, R. Cao, Wu Xu, D. Baer, Yingge Du, O. Borodin, Yanting Wang, Xue-Lin Wang, K. Xu, Zhijie Xu, Chongmin Wang, Zihua Zhu (2020)
Real-time mass spectrometric characterization of the solid–electrolyte interphase of a lithium-ion batteryNature Nanotechnology, 15
Qiankui Zhang, Si Liu, Zeheng Lin, Kang Wang, Min Chen, K. Xu, Weishan Li (2020)
Highly safe and cyclable Li-metal batteries with vinylethylene carbonate electrolyteNano Energy, 74
J. Moulder, W. Stickle, W. Sobol, K. Bomben (1992)
Handbook of X-Ray Photoelectron Spectroscopy
Li S. (2021)
7667J. Mater. Chem. A, 9
Sun H.‐H. (2019)
17782J. Mater. Chem. A, 7
S. Park, Jang‐Yeon Hwang, C. Yoon, Hun‐Gi Jung, Yang‐Kook Sun (2018)
Stabilization of Lithium-Metal Batteries Based on the in Situ Formation of a Stable Solid Electrolyte Interphase Layer.ACS applied materials & interfaces, 10 21
Qianqian Liu, Yifei Xu, Jianghao Wang, Bo Zhao, Zijian Li, H. Wu (2020)
Sustained-Release Nanocapsules Enable Long-Lasting Stabilization of Li Anode for Practical Li-Metal BatteriesNano-Micro Letters, 12
Ming Liu, Zhu Cheng, Kun Qian, T. Verhallen, Chao Wang, M. Wagemaker (2019)
Efficient Li-Metal Plating/Stripping in Carbonate Electrolytes Using a LiNO3-Gel Polymer Electrolyte, Monitored by Operando Neutron Depth ProfilingChemistry of Materials
Pengcheng Shi, Shipeng Zhang, Gongxun Lu, Lifeng Wang, Yu Jiang, Fanfan Liu, Yu Yao, Hai Yang, Mingze Ma, Shufen Ye, X. Tao, Yuezhan Feng, Xiaojun Wu, X. Rui, Yan Yu (2020)
Red Phosphorous‐Derived Protective Layers with High Ionic Conductivity and Mechanical Strength on Dendrite‐Free Sodium and Potassium Metal AnodesAdvanced Energy Materials, 11
Lingjie Zhao, Zhe Hu, Weihong Lai, Y. Tao, Jian Peng, Z. Miao, Yun‐Xiao Wang, S. Chou, Huakun Liu, S. Dou (2020)
Hard Carbon Anodes: Fundamental Understanding and Commercial Perspectives for Na‐Ion Batteries beyond Li‐Ion and K‐Ion CounterpartsAdvanced Energy Materials, 11
Xiang Chen, Xin Shen, Tingzheng Hou, Rui Zhang, Hong‐Jie Peng, Qiang Zhang (2020)
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal BatteriesChem
Xian Wu, Nannan Liu, Zhikun Guo, Maoxu Wang, Y. Qiu, Da Tian, Bin Guan, Lishuang Fan, Naiqing Zhang (2020)
Constructing multi-functional Janus separator toward highly stable lithium batteriesEnergy Storage Materials
Yifang Zhang, Y. Zhong, Zishan Wu, Bo Wang, S. Liang, Hailiang Wang (2020)
Solvent Molecule Cooperation Enhancing Lithium Metal Battery Performance on Both Electrodes.Angewandte Chemie
Zhe Peng, X. Cao, Peiyuan Gao, Haiping Jia, Xiaodi Ren, Swadipta Roy, Zhendong Li, Yun Zhu, Weiping Xie, Dianying Liu, Qiuyan Li, Deyu Wang, Wu Xu, Ji‐Guang Zhang (2020)
High‐Power Lithium Metal Batteries Enabled by High‐Concentration Acetonitrile‐Based Electrolytes with Vinylene Carbonate AdditiveAdvanced Functional Materials, 30
Zhenglin Hu, Shu Zhang, Shanmu Dong, Wenjun Li, Hong Li, G. Cui, Liquan Chen (2017)
Poly(ethyl α-cyanoacrylate)-Based Artificial Solid Electrolyte Interphase Layer for Enhanced Interface Stability of Li Metal AnodesChemistry of Materials, 29
Ramin Rojaee, R. Shahbazian‐Yassar (2020)
Two Dimensional Materials to Address the Li-Based Battery Challenges.ACS nano
Jung‐Gu Han, Min-Young Jeong, Koeun Kim, Chanhyung Park, C. Sung, Daegil Bak, Kyung Kim, Kyeong-Min Jeong, N. Choi (2020)
An electrolyte additive capable of scavenging HF and PF5 enables fast charging of lithium-ion batteries in LiPF6-based electrolytesJournal of Power Sources, 446
H. Tsukasaki, Wataru Fukuda, H. Morimoto, T. Arai, S. Mori, A. Hayashi, M. Tatsumisago (2018)
Thermal behavior and microstructures of cathodes for liquid electrolyte-based lithium batteriesScientific Reports, 8
Koeun Kim, Inbok Park, Seonbaek Ha, Yeonkyoung Kim, Myung-Heuio Woo, Myung-Hwan Jeong, Woo-Cheol Shin, M. Ue, Sung Hong, N. Choi (2017)
Understanding the thermal instability of fluoroethylene carbonate in LiPF6-based electrolytes for lithium ion batteriesElectrochimica Acta, 225
K. Kubota, M. Dahbi, Tomooki Hosaka, S. Kumakura, S. Komaba (2018)
Towards K-Ion and Na-Ion Batteries as "Beyond Li-Ion".Chemical record, 18 4
Dul Boriboon, T. Vongsetskul, P. Limthongkul, W. Kobsiriphat, P. Tammawat (2018)
Cellulose ultrafine fibers embedded with titania particles as a high performance and eco-friendly separator for lithium-ion batteries.Carbohydrate polymers, 189
Feng Wu, Kun Zhang, Yiran Liu, Hongcai Gao, Ying Bai, Xinran Wang, Chuan Wu (2020)
Polymer electrolytes and interfaces toward solid-state batteries: Recent advances and prospectsEnergy Storage Materials, 33
Xia Li, X. Sun (2018)
Interface Design and Development of Coating Materials in Lithium–Sulfur BatteriesAdvanced Functional Materials, 28
The capacity attenuation and poor safety caused by lithium dendrite and interface side reactions have hindered the application of lithium–metal batteries (LMBs) for a long time. To solve this problem, some liquid or salt additives have been added to the electrolyte to promote the uniform stripping/plating of lithium, however, the consumption of electrolyte during cycles reduces the concentration of active components, resulting in the gradual failure of additives. Herein, a new solid additive (nano CaCO3) working under the principle of sustained release is proposed: the homo‐dispersed nano CaCO3 particles can continuously absorb the decomposition by‐products generated during the side reaction and release Ca2+, which cannot only inhibit the tip deposition of Li+ through electrostatic shielding effect but also effectively promote the formation of stable F‐rich solid–electrolyte interphase (SEI). As the consequence, a notably optimized electrochemical performance for commercial carbonate electrolyte after adding 3 wt.% nano CaCO3 is observed, and the cycle life of symmetric Li||Li cells is extended from <400 h to over 800 h at 1 mA cm−2. In addition, the modified emulsion‐like electrolyte has lower volatility and its protective effect on the separator is confirmed by ex situ optical observation, reflecting the safety improvement of LMBs.
Advanced Energy Materials – Wiley
Published: May 1, 2022
Keywords: lithium anode protection; lithium–metal batteries; multifunctional additives; nano CaCO 3; sustained‐release effects
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